sodium titanyl phosphate | 110074-73-2

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: sodium titanyl phosphate
• CAS: 110074-73-2
• 化学式: Na*OTi*O₄P
• 分子量: 181.841
• InChiKey: WIAAFJUDXWGYTM-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -5.94
• 重原子数：
  8.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  103.32
• 氢给体数：
  0.0
• 氢受体数：
  5.0

反应信息

• 作为产物：
  描述：

  sodium 、 hydrated titanyl phosphate 在 盐酸 作用下， 以 盐酸 为溶剂， 生成 sodium titanyl phosphate
  参考文献：
  名称：

  摘要：

  DOI：

  10.1023/a:1026169822490

文献信息

• Novel 1.5 V anode materials, ATiOPO₄(A = NH₄, K, Na), for room-temperature sodium-ion batteries
  作者：Linqin Mu、Liubin Ben、Yong-Sheng Hu、Hong Li、Liquan Chen、Xuejie Huang

  DOI：10.1039/c6ta00891g

  日期：——

  Due to the abundance of sodium in nature, sodium-ion batteries (SIBs) have attracted widespread attention.

  由于自然界中钠的丰富，钠离子电池（SIBs）引起了广泛关注。
• Thermodynamics of cationic substitutions on titanyl hydrogen phosphate
  作者：V. I. Ivanenko、E. P. Lokshin、S. V. Aksenova、R. I. Korneikov、V. T. Kalinnikov

  DOI：10.1134/s0036023608040037

  日期：2008.4

  Heterophasic substitution of Group I and Group II metal cations for hydrogen ions of titanyl hydrogen phosphate in aqueous solutions has been studied by a potentiometric method. The thermodynamic parameters of the process have been determined. The exchange constants depend on the degree of cation hydration and increase in the following orders: Li+ < Na+ < K+ < Rb+ < Cs+ and Mg2+ < Ca2+ < Sr2+ < Ba2+. Our results make it possible to determine conditions for the efficient deactivation of high-salt liquid radioactive wastes and for the synthesis of stoichiometric compounds of the KTP family.
• Synthesis of the fibrous materials ρ-Na0.50H0.50TiOPO4 and ρ-K0.67H0.33TiOPO4 by reaction of ρ-Ti2O(PO4)2(H2O)2 with molten alkali nitrates
  作者：Aránzazu Espina、Camino Trobajo、Sergei A Khainakov、José R Garcı́a

  DOI：10.1016/s0025-5408(01)00726-7

  日期：2001.11

  The reaction of rho -TiP with molten MNO3 (M = Na, K) originates the formation of new metal phases, rho -MxH1-xTiOPO4 (x = 0.50, M = Na; x = 0.67, M = K). These compounds maintain the fibrous morphology of their precursors. The processes occur in two differentiated steps with formation of rho -MxH1-xTiOPO4 (x = 0.25, M = Na; x = 0.42, M = K) intermediate phases. An ion-exchange mechanism is proposed for the reaction. Thermal treatment of the novel fibrous alkali metal phosphates produces mixtures of MTiOPO4, MTi2(PO4)(3), and TiO2. (C) 2001 Elsevier Science Ltd. All rights reserved.
• NaTiOPO₄and KTiOPO₄at 110K
  作者：S. Dahaoui、N. K. Hansen、B. Menaert

  DOI：10.1107/s0108270197004265

  日期：1997.9.15

  The title compounds, sodium titanyl phosphate and potassium titanyl phosphate, are isostructural, belonging to a family of compounds with interesting non-linear optical properties. The effect of substitution of K by Na has been analysed by X-ray diffraction at 110 K. The substitution does not modify the geometry of the phosphate groups; however, the Ti-O coordination distances are changed, as well as the relative orientation of the Ti and P polyhedra.
• Nagornyi, P. G.; Kapshuk, A. A.; Stus, N. V., Kristallografiya, 1990, vol. 35, p. 370 - 371
  作者：Nagornyi, P. G.、Kapshuk, A. A.、Stus, N. V.、Slobodyanik, N. S.

  DOI：——

  日期：——