zinc hydroxide nitrate | 395074-43-8

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: zinc hydroxide nitrate
• 英文别名: ZHN；Zinc hydroxide nitrate (1/1/1)；zinc;hydroxide;nitrate
• CAS: 395074-43-8
• 化学式: HO*NO₃*Zn
• 分子量: 144.402
• InChiKey: QAOTYOGEQAZIFQ-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.42
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  zinc hydroxide nitrate 以 neat (no solvent) 为溶剂， 反应 1.0h， 生成 zinc(II) oxide
  参考文献：
  名称：

  A facile template-free route to synthesize porous ZnO nanosheets with high surface area

  摘要：

  Microporous and mesoporous ZnO nanosheets were successfully synthesized by a low-temperature chemical bath deposition and subsequently thermal decomposition at 250 degrees C without any templates. Nanosheet-shaped zinc hydroxide nitrate (Zn-3(OH)(4)(NO3)(2)) was formed as the precursors at 90 degrees C for 6 days by chemical bath deposition in a close system. Microporous and mesoporous ZnO nanosheets were obtained from the removing of OH and NO3 groups from zinc hydroxide nitrate (Zn-3(OH)(4)(NO3)(2)) nanosheet- shaped precursors. The pore sizes were distributed in the region of similar to 1.3-25 nm with a center at similar to 2.4 nm. Such porous and nanosheets structure gave a highest specific surface area of 283.8 m(2)/g. (C) 2013 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2013.06.089
• 作为产物：
  描述：

  zinc(II) nitrate hexahydrate 、 水 在 sodium hydroxide 作用下， 生成 zinc hydroxide nitrate
  参考文献：
  名称：

  Synthesis, controlled release and antibacterial studies of nalidixic acid–zinc hydroxide nitrate nanocomposites

  摘要：

  萘啶酸插层氢氧化锌硝酸盐适用于控释制剂，由此产生的纳米复合材料是一种有效的抗菌剂。

  DOI：

  10.1039/c5nj01737h

文献信息

• Heterogeneous epoxidation of menadione with hydrogen peroxide over the zeolite imidazolate framework ZIF-8
  作者：Irina D. Ivanchikova、Vasilii Yu. Evtushok、Olga V. Zalomaeva、Danil I. Kolokolov、Alexander G. Stepanov、Oxana A. Kholdeeva

  DOI：10.1039/d0dt02658a

  日期：——

  The zeolite imidazolate framework ZIF-8 exhibits superior catalytic performance in the epoxidation of the electron-deficient CC bond in menadione using aqueous hydrogen peroxide as the oxidant. The catalysis has a truly heterogeneous nature and the framework structure remains intact. This is the first example of oxidation catalysis with ZIF-8.

  使用过氧化氢水溶液作为氧化剂，咪唑啉沸石骨架ZIF-8在甲萘醌中缺电子的C C键的环氧化中显示出优异的催化性能。催化具有真正的多相性质，并且框架结构保持完整。这是使用ZIF-8进行氧化催化的第一个例子。
• Preparation of a ZnIn₂S₄–ZnAlO_x nanocomposite for photoreduction of CO₂ to CO
  作者：Yuqing Shao、Xinkui Wang、Zhaolin Dou、Xiaoyu Liang、Xinxin Zhang、Min Pang、Qiang Xu、Min Ji、Min Wang

  DOI：10.1039/d1cy00278c

  日期：——

  The ZnIn₂S₄–ZnAlO_x nanocomposite inhibits the recombination of charge carriers and therefore significantly boosts CO₂ photoreduction efficiency.

  ZnIn2S4-ZnAlOx纳米复合材料抑制了载流子的复合，因此显著提高了CO2光催化还原效率。
• Effects of zinc precursor, basicity and temperature on the aqueous synthesis of ZnO nanocrystals
  作者：Maroua Mrad、Bilel Chouchene、Tahar Ben Chaabane

  DOI：10.17159/0379-4350/2018/v71a13

  日期：——

  whereas zinc oxide was formed in the other, and no lamellar phase of Zn 5 (OH) 8 (NO 3 ) 2 .2H 2 O was obtained. Thermal decomposition of the two lamellar phases was carried out and mainly showed that Zn 5 (OH) 8 (NO 3 ) 2 .2H 2 O was completely decomposed to ZnO when the annealed temperature reached ~250 °C while Zn 5 (OH) 8 Cl 2 ·H 2 O was totally transformed to ZnO at about 400 °C, a higher comparative

  研究了锌盐前体，反应温度和碱比b（b = [OH-] / [Zn 2+]）对ZnO纳米晶体水相合成的影响。取决于锌前体的类型，当在室温（20°C）下获得Zn 5（OH）8 Cl 2·H 2 O或Zn 5（OH）8（NO 3）2 .2H 2 O层状相。碱性比率较低（0.5≤b≤1、6≤pH≤6.4）。当反应温度升至95℃时，在一种情况下获得氢氧化锌一水合物，而在另一情况下形成氧化锌，而未获得Zn 5（OH）8（NO 3）2 .2H 2 O的层状相。 。进行了两个层状相的热分解，主要显示为Zn 5（OH）8（NO 3）2。当退火温度达到〜250°C时2H 2 O完全分解为ZnO，而Zn 5（OH）8 Cl 2·H 2 O在约400°C时完全转化为ZnO，较高的比较温度证实了更好的热氢氧化锌一水合氯化物的稳定性。关键字：氧化物，ZnO，化学合成，X射线衍射，晶体结构，发光