gallium phosphate | 773796-40-0

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属氧阴离子化合物
• 英文名称: gallium phosphate
• 英文别名: gallium(III) phosphate；gallium monophosphate；gallium ortho-phosphate；2,4,5-trioxa-1λ5-phospha-3-gallabicyclo[1.1.1]pentane 1-oxide
• CAS: 773796-40-0
• 化学式: Ga*O₄P
• 分子量: 164.694
• InChiKey: LWFNJDOYCSNXDO-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -3.21
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  gallium phosphate 以 neat (no solvent) 为溶剂， 生成 、
  参考文献：
  名称：

  Lopatin; Semenov; Selevich, Russian Journal of General Chemistry, 1999, vol. 69, # 4, p. 534 - 536

  摘要：

  DOI：
• 作为产物：
  描述：

  2,4,5-Trioxa-1lambda5-phospha-3-gallabicyclo[1.1.1]pentane 1-oxide;hydrate 在 磷酸 作用下， 以 水 为溶剂， 生成 gallium phosphate
  参考文献：
  名称：

  Growth of gallium orthophosphate single crystals in acidic hydrothermal solutions

  摘要：

  The hydrothermal growth of GaPO4 single crystals has been studied in several solutions. Among many solutions, H3PO4, HCl and H2SO4 solutions were found to be effective solvents for the growth of GaPO4 single crystals. Single crystals have been hydrothermally grown at temperatures over the range 210 to 290-degrees-C in these solutions with seed crystals. HCl solution was found to be the most effective solvent in which to grow large single crystals. Morphologies of crystals grown at temperatures below 200-degrees-C tended to be bounded by small major rhombohedral (1 0 1BAR 1) faces. In the temperature range from 210 to 430-degrees-C, the crystals have morphologies bounded by prism (1 0 1BAR 0), small major rhombohedral (1 0 1BAR 1) and minor rhombohedral (0 1 1BAR 1) faces, and grew with well developed basal (0 0 0 1) faces with increase in the growth temperature. Single crystals of GaPO4 with lower dislocation density have been hydrothermally grown at 210 to 290-degrees-C in 3 M H3PO4 solution.

  DOI：

  10.1007/bf02387755

文献信息

• Ionothermal Synthesis and Characterization of a Layered Propylene Diammonium Gallium Phosphate, (C3H12N2)6[Ga12P16O64] · 4.3 H2O
  作者：Sven-Jare Lohmeier、Michael Wiebcke、Peter Behrens

  DOI：10.1002/zaac.200700369

  日期：2008.1

  A new propylene-1,3-diammonium gallium phosphate of composition (C3H12N2)6[Ga12P16O64] · 4.3 H2O (LUH-1) was obtained by ionothermal synthesis using a deep-eutectic solvent (DES) composed of choline chloride and tetrahydro-2-pyrimidione as reaction medium. The structure-directing agent propylene-1,3-diammonium was generated in situ by the thermally induced decomposition of the amide component of the

  使用由氯化胆碱和四氢-2 组成的深共熔溶剂 (DES) 通过离子热合成获得了一种新的丙烯-1,3-磷酸二铵镓 (C3H12N2) 6 [Ga12P16O64] · 4.3 H2O (LUH-1) -嘧啶酮作为反应介质。结构导向剂丙烯-1,3-二铵是通过 DES 酰胺组分的热诱导分解原位生成的。单晶 X 射线结构分析表明，LUH-1 由大阴离子四面体磷酸镓层和层间丙烯-1,3-二铵阳离子层构成，后者表现出双重无序。一维 12 元环通道系统被高度无序的水分子占据。正如热重分析和粉末 X 射线衍射所表明的，水分子可以在大约 10 分钟内从 LUH-1 上解吸。100°C 保留层状无机-有机杂化结构。LUH-1 的晶体数据：三角系，空间群 c1（编号 165），Z = 1，a = 12.905 (4)，c = 18.317 (8) A，T = 297 K。
• Two amino acid-templated metal phosphates: surfactant-thermal synthesis, water stability, and proton conduction
  作者：Lijuan Huang、Lei Wang、Yan Zhao、Ling Huang、Jian Bi、Guohong Zou、Zhien Lin、Daojiang Gao

  DOI：10.1039/d0dt00966k

  日期：——

  structure decorated with homoproline and compound 2 has a three-dimensional zeolite-like structure templated by proline. Notably, compound 2 remains stable in both boiling water and aqueous solutions with a pH range of 2-12. It shows a proton conductivity of 8.89 × 10-4 S cm-1 at 85 °C and 95% relative humidity.

  在表面活性剂-热条件下，制备了两种新的金属磷酸盐，即Zn（HPO4）（C6H11NO2）（1）和（C5H10NO2）Ga4（PO4）4F·3H2O（2）。单晶X射线衍射分析表明，化合物1具有用高脯氨酸修饰的之字形链结构，而化合物2具有由脯氨酸模板化的三维沸石样结构。值得注意的是，化合物2在沸水和pH范围为2-12的水溶液中均保持稳定。它在85°C和95％相对湿度下的质子传导率是8.89×10-4 S cm-1。
• Oxyfluorinated Microporous Compounds. I. Crystal Structure of (NH4)0.93(H3O)0.07GaPO4(OH)0.5F0.5; Reexamination of the Structure of AlPO4-CJ2
  作者：G. Férey、T. Loiseau、P. Lacorre、F. Taulelle

  DOI：10.1006/jssc.1993.1206

  日期：1993.7

  of 1 M2 O3 (M = Ga or Al), 1 P2O5, 2 NH4F, 1 hexamethylenetetramine, and 80 H2O by hydrothermal synthesis at 180°C. Their crystal structure was determined by single-crystal X-ray diffraction. They crystallize in space group P212121, Z = 8, with cell parameters a = 9.593(2) Å, b = 9.742(2) Å, c = 9.981(2) Å and a = 9.416(8) Å, b = 9.563(5) Å, c = 9.933(4) Å, for M = Ga and Al, respectively. It appears

  从1:1的混合物中，制得标题化合物中号2 ö 3（中号=镓或Al），1个P 2 ø 5，2 NH 4 F，1-六亚甲基四，和80h的2在180℃C 0通过水热合成。它们的晶体结构通过单晶X射线衍射确定。它们在空间组P 2 1 2 1 2 1中结晶，Z = 8，单元参数为a = 9.593（2）Å，b = 9.742（2）Å，c = 9.981（2）Å和a = 9.416（8） Å，b对于M = Ga和Al，分别为9.563（5）Å，c = 9.933（4）Å 。看来以前已经制备了铝磷酸盐并称为AlPO 4 -CJ2，但是表征较差。这些化合物的晶体结构可以被描述为PO的三维网络4四面体共享顶点与双三角锥MX 5和八面体MX 6（X = O 2 - ，OH -或F - ）。这些多面体形成八元环并划定通道，其中铵基团占据两种类型的位点。取决于M，氟原子占据一个或两个不同的位置，或者完全占据或统计
• A New Organic‐Inorganic Hybrid Gallophosphate Prepared in the Presence of Glycine
  作者：Mohammed Abdelkrim Hasnaoui、Angélique Simon‐Masseron、Volker Gramlich、Joël Patarin、Abdelkader Bengueddach

  DOI：10.1002/ejic.200400392

  日期：2005.2

  513(3) A and β = 90.67(3)°. The inorganic layer is built up from four-membered rings sharing T−O−T bonds. In addition to the nature of the template, the original properties of this new gallophosphate come from the coordination environment of the Ga which is only pentacoordinated with oxygen atoms and has strong bonds (Ga−O−C) between the organic template and the inorganic sheet. (© Wiley-VCH Verlag GmbH

  使用氨基酸甘氨酸 (H2NCH2CO2H) 作为原始模板，水热合成了一种新的层状镓磷酸盐 Ga4P4O16(C2H5NO2)4，称为 Mu-32。这种模板以前从未用于合成微孔和磷酸盐基材料，例如磷酸镓。通过单晶 X 射线衍射研究确定结构，并通过扫描电子显微镜、元素和热分析以及 13C 和 31P 固态 NMR 光谱进一步表征。该化合物在单斜空间群 P21/c 中结晶，a = 9.177(2), b = 5.1540(10), c = 12.513(3) A 和 β = 90.67(3)°。无机层由共享 T-O-T 键的四元环构成。除了模板的性质，这种新型镓磷酸盐的原始性质来自于 Ga 的配位环境，它仅与氧原子五配位，并且在有机模板和无机片材之间具有强键 (Ga-O-C)。(© Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany
• Some optical properties of aluminum and gallium niobate
  作者：G. Blasse、R.U.E. 't Lam

  DOI：10.1016/0022-4596(78)90045-2

  日期：1978.5

  The vibrational and electronic (diffuse reflection and luminescence) spectra of AlNbO4 and GaNbO4 are reported. They show features which deviate markedly from those observed for other niobates. In the vibrational spectra a very high frequency (≅950 cm−1) band is observed. The reflection spectra show an extended long-wavelength tail. The emission and excitation spectra of the luminescence contain more

  报道了AlNbO 4和GaNbO 4的振动和电子（漫反射和发光）光谱。它们显示出与其他铌酸盐所观察到的特征明显不同的特征。在振动光谱中，非常高的频率（≅950cm -1）波段被观察到。反射光谱显示出延长的长波长尾巴。发光的发射光谱和激发光谱包含一个以上的带。发光的热猝灭温度较低。这些现象与晶体结构的特殊性有关，即，相对较近的NbO距离和最近的电子显微镜所显示的扩展缺陷的存在。根据振动谱，提出了一个中心对称的空间群。