铅(2+)氢氧化物硝酸盐(1:1:1) | 12268-84-7

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属氧阴离子化合物
• 中文名称: 铅(2+)氢氧化物硝酸盐(1:1:1)
• 英文名称: Lead hydroxide nitrate
• 英文别名: lead(2+);hydroxide;nitrate
• CAS: 12268-84-7
• 化学式: 4HO*4NO₃*4Pb
• 分子量: 1144.85
• InChiKey: UITIGCZPKSMPAB-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -0.8
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  lithium hydroxide monohydrate 、 lead(II) nitrate 以 水 为溶剂， 反应 72.0h， 以92%的产率得到铅(2+)氢氧化物硝酸盐(1:1:1)
  参考文献：
  名称：

  A Nitrate Nonlinear Optical Crystal Pb₁₆(OH)₁₆(NO₃)₁₆ with a Large Second-Harmonic Generation Response

  摘要：

  A noncentrosymmetric nitrate, Pb-16(OH)(16)(NO3)(16), has been obtained using a hydrothermal method. It is constructed of [Pb-4(OH)(4)](4+) cubanes and nitrate form the overall three-dimensional structure via weak Pb-O bonds. Powder second-harmonic generation (SHG) using the Kurtz-Perry technique shows that Pb-16(OH)(16)(NO3)(16) is type I phase-matchable, and the measured SHG coefficient was 3.5 times that of KH2PO4. The direction and magnitude of the dipole moments in PbOn polyhedra and [NO3](-) triangles of Pb-16(OH)(16)(NO3)(16) have been quantified using the bond-valence approach, which shows that the large SHG response originates from the cooperation of PbOn polyhedra and [NO3](-) triangles. The band structure and density of states as well as electron density difference are calculated on the basis of density functional theory.

  DOI：

  10.1021/ic402404a

文献信息

• Series of Lead Oxide Hydroxide Nitrates Obtained by Adjusting the pH Values of the Reaction Systems
  作者：Genxiang Wang、Min Luo、Ning Ye、Chensheng Lin、Wendan Cheng

  DOI：10.1021/ic5004116

  日期：2014.5.19

  A series of lead(II) nitrates have been synthesized by a hydrothermal method and adjusting the pH values of the reaction systems. Pb20O6(OH)16(NO3)12 and Pb2O(OH)NO3, crystallize in the centrosymmetric space group P1̅ and Pbca, respectively. The structure of Pb20O6(OH)16(NO3)12 features infinite cationic chains of [Pb20O6(OH)16]∞ running along c axis, and the nitrate groups as the counterions reside

  通过水热法并调节反应体系的pH值，合成了一系列硝酸铅（II）。铅20直径：6（OH）16（NO 3）12和Pb 2 O（OH）NO 3，结晶在中心对称空间群P 1和PBCA分别。Pb 20 O 6（OH）16（NO 3）12的结构特征是[pb 20 O 6（OH）16 ] ∞沿c方向延伸的无限阳离子链Pb 2 O（OH）NO 3的结构可以描述为阳离子[Pb 2 O（OH）] ∞层与阴离子[NO 3 ]的交替堆叠−通过弱Pb–O键沿[001]方向分层，形成具有12个成员环（MR）的1D隧道的3D框架。首次研究了在非中心对称空间群Cc中结晶的[Pb 4（OH）4 ]（NO 3）4作为非线性光学材料。二次谐波生成（SHG）测量表明[Pb]的SHG响应4（OH）4 ]（NO 3）4是KDP的0.7倍。理论计算证实的SHG效率[铅4（OH）4 ]（NO 3）4个从NO的协同效应源自3 -在结构组和铅
• Crystal structure of [Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O
  作者：S. P. Khranenko、N. V. Kuratieva、I. V. Korolkov、S. A. Gromilov

  DOI：10.1134/s0022476616030240

  日期：2016.5

  The structure of [Pb3(OH)4Co(NO2)3](NO3)(NO2)·2H2O is determined by single crystal X-ray diffraction. The crystallographic characteristics are as follows: a = 8.9414(4) Å, b = 14.5330(5) Å, c = 24.9383(9) Å, V = 3240.6(2) Å3, space group Pbca, Z = 8. The Co(III) atoms have a slightly distorted octahedral coordination formed by three nitrogen atoms belonging to nitro groups (Co–Nav is 1.91 Å) and three

  [Pb3(OH)4Co(NO2)3](NO3)( )·2H2O的结构由单晶X射线衍射确定。晶体学特征如下：a = 8.9414(4) Å, b = 14.5330(5) Å, c = 24.9383(9) Å, V = 3240.6(2) Å3, 空间群 Pbca, Z = 8. Co( III) 原子具有轻微扭曲的八面体配位，由三个属于硝基的氮原子（Co-Nav 为 1.91 Å）和三个属于羟基的氧原子（Co-Oav 为 1.93 Å）形成。羟基充当金属原子之间的 μ3 桥。分析几何特征并确定包装图案。