2,6-bis-benzoyloxy-toluene | 90422-08-5

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 2,6-bis-benzoyloxy-toluene
• 英文别名: 2,6-Bis-benzoyloxy-toluol；2.6-Dibenzoyloxy-1-methyl-benzol；3-(Benzoyloxy)-2-methylphenyl benzoate；(3-benzoyloxy-2-methylphenyl) benzoate
• CAS: 90422-08-5
• 化学式: C₂₁H₁₆O₄
• 分子量: 332.356
• InChiKey: AJFVSPMJQTWONR-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.1
• 重原子数：
  25
• 可旋转键数：
  6
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.05
• 拓扑面积：
  52.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  2-hydroxy-4-methoxy-3-methylbenzoic acid 在 氢氧化钾 、 氢碘酸 作用下， 生成 2,6-bis-benzoyloxy-toluene
  参考文献：
  名称：

  Herzig; Wenzel; Haiser, Monatshefte fur Chemie, 1903, vol. 24, p. 908

  摘要：

  DOI：

文献信息

• UV curable abrasion-resistant coatings
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0544465A1

  公开（公告）日：1993-06-02

  UV curable hardcoat compositions are provided which impart improved abrasion resistance to thermoplastic substrates when applied and cured thereon. Enhancement in abrasion and weathering properties has been achieved by the use of certain UV curable branched or carbocyclic monoacrylates, such as isobornyl acrylate.

  本发明提供了紫外线固化硬涂层组合物，当应用于热塑性基材并在其上固化时，可提高其耐磨性。通过使用某些可紫外线固化的支链或碳环单丙烯酸酯，如丙烯酸异冰片酯，可提高耐磨性和耐候性。
• Method of making a UV-curable hardcoat compositions
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0565310A1

  公开（公告）日：1993-10-13

  A method of making a UV curable hardcoat composition uses a strip-free process and produces hardcoats having good scribed tape-pull adhesion, high resistance to scratching and a low delta taber haze after abrading for 500 cycles with a 500 gram weight. UV curable hardcoat compositions are also provided which contain high solids contents and high mole percentages of photoinitiator. Compositions containing methoxypropanol as a water miscible alcohol and methylbenzoylformate as a photoinitiator exhibit high taber hardness and can be made by processes which obviate the need for a time and energy consuming solvent-strip step. The processes are not only shorter, but safer than processes which include a solvent-strip step.

  一种紫外线固化硬涂层组合物的制造方法采用无剥离工艺，生产出的硬涂层具有良好的划线拉带附着力、高抗划伤性以及在以 500 克重量进行 500 次循环研磨后的低 delta taber 雾度。此外，还提供了含有高固体含量和高摩尔百分比光引发剂的紫外线固化硬涂层组合物。含有甲氧基丙醇（作为水溶性醇）和甲基苯甲酰甲酸酯（作为光引发剂）的组合物具有很高的塔伯硬度，并且可以通过免去耗时耗力的溶剂剥离步骤的工艺制成。与包含溶剂剥离步骤的工艺相比，这种工艺不仅时间短，而且更安全。
• Radiation curable hardcoat compositions
  申请人：GENERAL ELECTRIC COMPANY

  公开号：EP0576247A2

  公开（公告）日：1993-12-29

  A radiation (UV or E-beam) curable hardcoat composition formed of a mixture of colloidal silica and hydrolyzed silica acrylate, an acrylic monomer and a photoinitiator it disclosed. Additives including a hindered amine light stabilizer, a fluoroacrylate and alkyl acrylate are employed to improve cure, clarity and hardness. A diphenyl (2,4,6-trimethyl(benzoyl) phosphate oxide UV initiator causes effective out of focus curing.

  本发明公开了一种可辐射（紫外线或电子束）固化的硬涂层组合物，该组合物由胶体二氧化硅和水解丙烯酸二氧化硅、丙烯酸单体和光引发剂的混合物组成。添加剂包括受阻胺光稳定剂、氟丙烯酸酯和丙烯酸烷基酯，用于改善固化、透明度和硬度。一种二苯基（2,4,6-三甲基（苯甲酰基）磷酸酯）氧化物紫外线引发剂可有效地进行非聚焦固化。
• Radiation curable coating compositions
  申请人：General Electric Company

  公开号：US20030045598A1

  公开（公告）日：2003-03-06

  A radiation curable coating composition includes a mixture of an oligomeric acrylate having a crosslinkable acrylate functionality of 1 to 6, at least one of monomeric acrylates and dimeric acrylates, having a crosslinkable acrylate functionality of 1 to 6, an acrylated colloidal silica, and a photoinitiator.

  一种辐射固化涂料组合物包括具有 1-6 可交联丙烯酸酯官能度的低聚丙烯酸酯、至少一种具有 1-6 可交联丙烯酸酯官能度的单体丙烯酸酯和二聚丙烯酸酯、丙烯化胶体二氧化硅和光引发剂的混合物。
• Limited play data storage media and coating formulations thereon
  申请人：Wisnudel Brian Marc

  公开号：US20050051053A1

  公开（公告）日：2005-03-10

  The present invention provides a formulation for a reactive dye layer for a limited-play optical storage medium, the reactive formulation including at least one carrier material or curable acrylate monomer, at least one reactive material disposed within the carrier material or acrylate monomer, and at least one photo-bleaching retarder material disposed within the at least one adhesive material. The at least one photo-bleaching retarder material includes at least one polymeric polyhydroxy compound selected from the group consisting of polyhydroxystyrenes, cellulose, and functionalized cellulose derivatives.

  本发明提供了一种用于有限播放光学存储介质的活性染料层的配方，该活性配方包括至少一种载体材料或可固化丙烯酸酯单体、设置在载体材料或丙烯酸酯单体中的至少一种活性材料，以及设置在至少一种粘合材料中的至少一种光漂白缓释材料。至少一种光漂白缓释材料包括至少一种聚合物聚羟基化合物，该化合物选自由聚羟基苯乙烯、纤维素和官能化纤维素衍生物组成的组。