5,8,11-trioxa-2,14-diazabicyclo[13.2.2]nonadeca-1(17),15(19)-diene-16,18-dione

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 乙烯基酰胺
• 英文名称: 5,8,11-trioxa-2,14-diazabicyclo[13.2.2]nonadeca-1(17),15(19)-diene-16,18-dione
• 化学式: C₁₄H₂₀N₂O₅
• 分子量: 296.323
• InChiKey: CPIHQEGZDBKOKM-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.85
• 重原子数：
  21.0
• 可旋转键数：
  0.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  85.89
• 氢给体数：
  2.0
• 氢受体数：
  7.0

反应信息

• 作为产物：
  描述：

  3,6,9-三氧杂十一烷-1,11-二胺 、 2-(苯硫基)-P-苯醌 以 甲醇 为溶剂， 反应 4.0h， 以34%的产率得到5,8,11-trioxa-2,14-diazabicyclo[13.2.2]nonadeca-1(17),15(19)-diene-16,18-dione
  参考文献：
  名称：

  Reaction of benzoquinones and naphthoquinones with 1,8-diamino-3,6-dioxanonane and with 1,11-diamino-3,6,9-trioxaundecane

  摘要：

  Reaction of 1,4-naphthoquinone or 2,3-dichloro-1,4-naphthoquinone with alpha,omega-diamino-derivatives of poly(alkylenoxides) leads to the formation of alpha,omega-bis(quinonyl) amines. A similar reaction with chloranil, bromanil, dichlorodicyanobenzoquinone, S-phenylbenzoquinone and 1,4-benzoquinone itself, leads to the formation of quinoid crown ethers. (C) 2003 Published by Elsevier Science Ltd.

  DOI：

  10.1016/s0040-4039(03)01263-2

文献信息

• Reaction of benzoquinones and naphthoquinones with 1,8-diamino-3,6-dioxanonane and with 1,11-diamino-3,6,9-trioxaundecane
  作者：Alex K. Machocho、Thida Win、Sarina Grinberg、Shmuel Bittner

  DOI：10.1016/s0040-4039(03)01263-2

  日期：2003.7

  Reaction of 1,4-naphthoquinone or 2,3-dichloro-1,4-naphthoquinone with alpha,omega-diamino-derivatives of poly(alkylenoxides) leads to the formation of alpha,omega-bis(quinonyl) amines. A similar reaction with chloranil, bromanil, dichlorodicyanobenzoquinone, S-phenylbenzoquinone and 1,4-benzoquinone itself, leads to the formation of quinoid crown ethers. (C) 2003 Published by Elsevier Science Ltd.