一氟化汞 | 27575-47-9

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 中文名称: 一氟化汞
• 英文名称: mercury monofluoride
• 英文别名: Mercury(1+);fluoride
• CAS: 27575-47-9
• 化学式: FHg
• 分子量: 219.588
• InChiKey: SCTINZGZNJKWBN-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.42
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为产物：
  描述：

  汞 、 fluorine 生成 一氟化汞
  参考文献：
  名称：

  Photolytic codeposition generation of the HgF radical in an argon matrix at 12 K: An ESR investigation

  摘要：

  The HgF radical has been generated by photolysis during the codeposition reaction of Hg atoms and F2(g) in an argon matrix at 12 K. The magnetic parameters are g(∥) = 1.993(1), g⊥ = 1.961(1); A∥ (19F) = 1344(10) MHz, A⊥ (19F) = 195(5), A∥ (199Hg) = 22 622(10), A⊥(199Hg) = 21 880(8), A∥ (201Hg) = 8055(12), A⊥ (201Hg) = 7760(10). Utilizing the g and A tensor data, the electronic structure of HgF is compared to the other MF radicals studied.

  DOI：

  10.1063/1.441040

文献信息

• Photolytic codeposition generation of the HgF radical in an argon matrix at 12 K: An ESR investigation
  作者：Lon B. Knight、T. A. Fisher、M. B. Wise

  DOI：10.1063/1.441040

  日期：1981.6

  The HgF radical has been generated by photolysis during the codeposition reaction of Hg atoms and F2(g) in an argon matrix at 12 K. The magnetic parameters are g(∥) = 1.993(1), g⊥ = 1.961(1); A∥ (19F) = 1344(10) MHz, A⊥ (19F) = 195(5), A∥ (199Hg) = 22 622(10), A⊥(199Hg) = 21 880(8), A∥ (201Hg) = 8055(12), A⊥ (201Hg) = 7760(10). Utilizing the g and A tensor data, the electronic structure of HgF is compared to the other MF radicals studied.