摘要:
The HgF radical has been generated by photolysis during the codeposition reaction of Hg atoms and F2(g) in an argon matrix at 12 K. The magnetic parameters are g(∥) = 1.993(1), g⊥ = 1.961(1); A∥ (19F) = 1344(10) MHz, A⊥ (19F) = 195(5), A∥ (199Hg) = 22 622(10), A⊥(199Hg) = 21 880(8), A∥ (201Hg) = 8055(12), A⊥ (201Hg) = 7760(10). Utilizing the g and A tensor data, the electronic structure of HgF is compared to the other MF radicals studied.