三(2-甲基-4-二乙基氨基苯基)甲烷 | 4482-70-6

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 中文名称: 三(2-甲基-4-二乙基氨基苯基)甲烷
• 英文名称: Tris(2-methyl-4-diethylaminophenyl)methan
• 英文别名: Benzenamine, 4,4',4''-methylidynetris[N,N-diethyl-3-methyl-；4-[bis[4-(diethylamino)-2-methylphenyl]methyl]-N,N-diethyl-3-methylaniline
• CAS: 4482-70-6
• 化学式: C₃₄H₄₉N₃
• 分子量: 499.783
• InChiKey: OKJSFKIUVDXFMS-UHFFFAOYSA-N

物化性质

• 熔点：
  163-165 °C
• 沸点：
  640.7±55.0 °C(Predicted)
• 密度：
  1.010±0.06 g/cm3(Predicted)
• 稳定性/保质期：
  在常温常压下稳定，应避免与不相容材料接触。它可能与强氧化剂发生反应。

计算性质

• 辛醇/水分配系数(LogP)：
  9
• 重原子数：
  37
• 可旋转键数：
  12
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.47
• 拓扑面积：
  9.7
• 氢给体数：
  0
• 氢受体数：
  3

安全信息

• 危险品标志：
  Xi
• 安全说明：
  S26,S37/39
• 危险类别码：
  R36/37/38
• 海关编码：
  2921590090

SDS

Name:	Tris(2-methyl-4-diethylaminophenyl)methane Material Safety Data Sheet
Synonym:
CAS:	4482-70-6

Section 1 - Chemical Product MSDS Name:Tris(2-methyl-4-diethylaminophenyl)methane Material Safety Data Sheet
Synonym:

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Section 2 - COMPOSITION, INFORMATION ON INGREDIENTS

CAS#	Chemical Name	content	EINECS#
4482-70-6	Tris(2-methyl-4-diethylaminophenyl)met		224-765-7

Hazard Symbols: XI
Risk Phrases: 36/37/38

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Section 3 - HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW
Irritating to eyes, respiratory system and skin.
Potential Health Effects
Eye:
Causes eye irritation.
Skin:
Causes skin irritation. May be harmful if absorbed through the skin.
Ingestion:
May cause irritation of the digestive tract. May be harmful if swallowed.
Inhalation:
Causes respiratory tract irritation. May be harmful if inhaled.
Chronic:
Not available.

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Section 4 - FIRST AID MEASURES
Eyes: Flush eyes with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical aid.
Skin:
Get medical aid. Flush skin with plenty of water for at least 15 minutes while removing contaminated clothing and shoes.
Ingestion:
Get medical aid. Wash mouth out with water.
Inhalation:
Remove from exposure and move to fresh air immediately. If not breathing, give artificial respiration. If breathing is difficult, give oxygen. Get medical aid.
Notes to Physician:
Treat symptomatically and supportively.

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Section 5 - FIRE FIGHTING MEASURES
General Information:
As in any fire, wear a self-contained breathing apparatus in pressure-demand, MSHA/NIOSH (approved or equivalent), and full protective gear.
Extinguishing Media:
Use water spray, dry chemical, carbon dioxide, or chemical foam.

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Section 6 - ACCIDENTAL RELEASE MEASURES
General Information: Use proper personal protective equipment as indicated in Section 8.
Spills/Leaks:
Vacuum or sweep up material and place into a suitable disposal container.

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Section 7 - HANDLING and STORAGE
Handling:
Avoid breathing dust, vapor, mist, or gas. Avoid contact with skin and eyes.
Storage:
Store in a cool, dry place. Store in a tightly closed container.

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Section 8 - EXPOSURE CONTROLS, PERSONAL PROTECTION
Engineering Controls:
Facilities storing or utilizing this material should be equipped with an eyewash facility and a safety shower. Use adequate ventilation to keep airborne concentrations low.
Exposure Limits CAS# 4482-70-6: Personal Protective Equipment Eyes: Not available.
Skin:
Wear appropriate protective gloves to prevent skin exposure.
Clothing:
Wear appropriate protective clothing to prevent skin exposure.
Respirators:
Follow the OSHA respirator regulations found in 29 CFR 1910.134 or European Standard EN 149. Use a NIOSH/MSHA or European Standard EN 149 approved respirator if exposure limits are exceeded or if irritation or other symptoms are experienced.

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Section 9 - PHYSICAL AND CHEMICAL PROPERTIES

Physical State: Solid
Color: off-white
Odor: slight aromatic odor
pH: Not available.
Vapor Pressure: Not available.
Viscosity: Not available.
Boiling Point: Not available.
Freezing/Melting Point: 163 - 165 deg C
Autoignition Temperature: Not available.
Flash Point: Not available.
Explosion Limits, lower: Not available.
Explosion Limits, upper: Not available.
Decomposition Temperature:
Solubility in water: Insoluble.
Specific Gravity/Density:
Molecular Formula: C34H49N3
Molecular Weight: 499.78

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Section 10 - STABILITY AND REACTIVITY
Chemical Stability:
Stable.
Conditions to Avoid:
Incompatible materials.
Incompatibilities with Other Materials:
Strong oxidizing agents.
Hazardous Decomposition Products:
Nitrogen oxides, carbon monoxide, carbon dioxide.
Hazardous Polymerization: Will not occur.

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Section 11 - TOXICOLOGICAL INFORMATION
RTECS#:
CAS# 4482-70-6 unlisted.
LD50/LC50:
Not available.
Carcinogenicity:
Tris(2-methyl-4-diethylaminophenyl)methane - Not listed by ACGIH, IARC, or NTP.

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Section 12 - ECOLOGICAL INFORMATION

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Section 13 - DISPOSAL CONSIDERATIONS
Dispose of in a manner consistent with federal, state, and local regulations.

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Section 14 - TRANSPORT INFORMATION

IATA
Not regulated as a hazardous material.
IMO
Not regulated as a hazardous material.
RID/ADR
Not regulated as a hazardous material.

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Section 15 - REGULATORY INFORMATION

European/International Regulations
European Labeling in Accordance with EC Directives
Hazard Symbols: XI
Risk Phrases:
R 36/37/38 Irritating to eyes, respiratory system
and skin.
Safety Phrases:
S 26 In case of contact with eyes, rinse immediately
with plenty of water and seek medical advice.
S 37/39 Wear suitable gloves and eye/face
protection.
WGK (Water Danger/Protection)
CAS# 4482-70-6: No information available.
Canada
CAS# 4482-70-6 is listed on Canada's DSL List.
CAS# 4482-70-6 is not listed on Canada's Ingredient Disclosure List.
US FEDERAL
TSCA
CAS# 4482-70-6 is listed on the TSCA inventory.

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SECTION 16 - ADDITIONAL INFORMATION
N/A

文献信息

• FLUORESCENT DYE COMPOUND HAVING BENZOTRIAZOLE STRUCTURE AND WAVELENGTH-CONVERTING ENCAPSULANT COMPOSITION USING SAME
  申请人：NITTO DENKO CORPORATION

  公开号：US20170210903A1

  公开（公告）日：2017-07-27

  The present invention relates to fluorescent, benzotriazole-containing dye compounds, which possess a high workability, desirable optical properties, and a good light stability, while suppressing the formation of a precipitate. The invention further relates to a wavelength-converting encapsulant layer, which is formed using the wavelength-converting encapsulant composition comprising said fluorescent, benzotriazole dye compounds. The fluorescent, benzotriazole-containing dye compounds are represented by general formula (I). wherein the variables are defined in the specification.

  本发明涉及含有荧光苯并三唑基染料化合物，具有高可加工性、理想的光学性能和良好的光稳定性，同时抑制沉淀物的形成。本发明还涉及一种波长转换封装层，该封装层是使用含有上述荧光苯并三唑基染料化合物的波长转换封装剂组成形成的。该含有荧光苯并三唑基染料化合物由一般式(I)表示，其中变量在规范中定义。
• FLUORESCENT DYE COMPOUND HAVING BENZOTRIAZOLE STRUCTURE, POLYMER FLUORESCENT DYE COMPOUND AND WAVELENGTH-CONVERTING ENCAPSULANT COMPOSITION USING SAME
  申请人：NITTO DENKO CORPORATION

  公开号：US20170198143A1

  公开（公告）日：2017-07-13

  The present invention relates to fluorescent, benzotriazole-containing dye compounds, which possess high processability, desirable optical characteristics and good photostability, while suppressing the formation of a precipitate, and to dye polymers comprising the same. The present invention further relates to a wavelength-converting encapsulant composition comprising said dye polymer and to a photovoltaic module, which comprises a layer comprising said wavelength-converting encapsulant. The polymer fluorescent benzotriazole-containing dye compound is represented by general formula (I): where the variables are defined in the specification.

  本发明涉及一种含有荧光苯并三唑基染料化合物，该化合物具有高加工性、理想的光学特性和良好的光稳定性，同时抑制沉淀物的形成，以及包含该化合物的染料聚合物。本发明还涉及一种波长转换封装组合物，包括所述染料聚合物，以及包含所述波长转换封装的光伏模块。聚合物荧光苯并三唑基染料化合物由通式（I）表示：其中变量在规范中定义。
• Titanocene based compound, photosensitive composition, photosensitive transfer sheet and pattern forming method
  申请人：Sugiyama Takekatsu

  公开号：US20070212642A1

  公开（公告）日：2007-09-13

  A titanocene compound having a carbonyl group, and a photosensitive composition whose sensitivity has been enhanced by containing this as a photopolymerization initiator, a photosensitive transfer sheet using said photosensitive composition, and a pattern forming method using said photosensitive transfer sheet are provided.

  提供了一种含有羰基的钛环化合物，以及一种光敏组合物，其中包含该钛环化合物作为光聚合引发剂，已增强其敏感度，使用该光敏组合物的光敏转移膜和使用该光敏转移膜的图案形成方法。
• Derivatives of aryl ketones as sensitizers of photopolymerizable compounds for the visible spectral range, and photopolymerizable compositions comprising the said sensitizers
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0039025A1

  公开（公告）日：1981-11-04

  This invention concerns sensitizers of photopolymerizable compounds that absorb in the visible spectral range. The sensitizers are derived from dihydro-ethano(or propano)anthracene, or acetyl-tetrahydronaphthalene, or acetylindane, and dialkylaminoaryl aldehydes. This invention also concerns photopolymerizable compositions comprising said sensitizers.

  本发明涉及可在可见光谱范围内吸收的光聚合化合物的敏化剂。这些敏化剂来自二氢乙烷（或丙烷）蒽、乙酰基四氢萘或乙酰基茚和二烷基氨基芳基醛。本发明还涉及包含上述敏化剂的可光聚合组合物。
• Radiation polymerizable composition for forming heat-resistant relief structures on electrical devices such as semiconductors and capacitors
  申请人：E.I. DU PONT DE NEMOURS AND COMPANY

  公开号：EP0047184A2

  公开（公告）日：1982-03-10

  A polyamide ester resin containing photopolymerizable groups is made more rapidly photopolymerizable and therefore more suitable for forming relief structures on electrical devices (such as capacitors, integrated circuits and semiconductors) by including therein a radiation-sensitive polymerizable polyfunctional acrylate compound and an aromatic biimidazole photopolymerization initiator. On exposure through a pattern of a dried film obtained using a solution of such composition, photopolymerization takes place rapidly and efficiently following which developing can be effected and the photopolymerized material baked to leave a heat- resistant polyimide structure.

  通过在含有可光聚合基团的聚酰胺酯树脂中加入对辐射敏感的可聚合多官能丙烯酸酯化合物和芳香族双咪唑光聚合引发剂，可使该树脂更快地光聚合，从而更适合在电气设备（如电容器、集成电路和半导体）上形成浮雕结构。使用这种组合物溶液制成的干燥薄膜经图案曝光后，可快速有效地发生光聚合反应，然后进行显影，并烘烤光聚合材料，使其形成耐热的聚酰亚胺结构。

表征谱图