bis(dimethyl dithiocarbamato) palladium (II)

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis(dimethyl dithiocarbamato) palladium (II)
• 英文别名: palladium(II) dimethyl dithocarbamate；Pd(dimethyldithiocarbamate)2；dimethyl-dithiocarbamic acid ; palladium(II)-compound；Dimethyl-dithiocarbamidsaeure; Palladium(II)-Verbindung
• 化学式: 2C₃H₆NS₂*Pd
• 分子量: 346.859
• InChiKey: BBKUDJPJGVDONL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  0.38
• 重原子数：
  7.0
• 可旋转键数：
  0.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  3.24
• 氢给体数：
  0.0
• 氢受体数：
  2.0

反应信息

• 作为产物：
  描述：

  palladium dichloride 、 sodium dimethyldithiocarbamate 以 水 为溶剂， 生成 bis(dimethyl dithiocarbamato) palladium (II)
  参考文献：
  名称：

  Malatesta, Gazzetta Chimica Italiana, 1938, vol. 68, p. 196

  摘要：

  DOI：

文献信息

• Metal complexes of sulphur ligands. Part 13. Reaction of dichloro-(η-cyclo-octa-1,5-diene)-palladium and -platinum complexes with some sulphur-containing nucleophiles
  作者：Margaret C. Cornock、T. Anthony Stephenson

  DOI：10.1039/dt9770000683

  日期：——

  M′=[AsPh4]+ or [PPh3(CH2Ph)]+) are formed. Reaction of (1; [S–S]–=[S2CNEt2]–) with Na[S2PMe2]·2H2O gives [Pd(S2CNEt2)(S2PMe2)](4a) which partially disproportionates in solution to [Pd(S2CNEt2)2] and [Pd(S2PMe2)2]. Complex (4a) reacts with PPh3 to give [Pd(PPh3)(S2CNEt2)(S2PMe2)](5a) which possesses bidentate [S2CNEt2]– and unidentate [S2PMe2]– groups. In contrast, reaction of [Pt(C8H12)Cl2] and Na[S2CNEt2]·3H2O

  [Pd（C 8 H 12）Cl 2 ]（C 8 H 12 =环辛-1,5-二烯）与等摩尔量的各种碱金属二硫代酸盐（[S–S – ] = [S 2 NEt 2 ] –，[S 2 COEt] –或[S 2 PMe 2 ] –）给出氯桥联的二聚体[PdCl（S–S）} 2 ]（1）。这些复分解反应得到相应的[PDX（S 2 CNET 2）} 2 ]（X = Br的-或[SPh上] -）。用Lewis碱裂解这些配合物得到[PdCl（S–S）L]（2：L = PPh 3，[S–S – ] = [S 2 CNEt 2 ] –，[S 2 COEt] –，或[S 2 PMe 2 ] –； L = ASPh 3，SbPh 3或C 5 H 5 N，[ SS – ] = [S 2 CNEt 2 ] –），并带有M'Cl–HCl，M' [PdCl 2（S 2 CNEt 2）]（3; M'= [ASPh 4 ]
• Cera, Marta; Cerrada, Elena; Laguna, Mariano, Organometallics, 2002, vol. 21, p. 121 - 126
  作者：Cera, Marta、Cerrada, Elena、Laguna, Mariano、Mata, Jose A.、Teruel, Helena

  DOI：——

  日期：——
• Acetylenes and noble-metal compounds. Part 13. Formation of cyclobutadienepalladium complexes from σ,π-butadienyl complexes in the PdCl₂-induced dimerisation of t-butyl(methyl)acetylene(4,4-dimethylpent-2-yne)
  作者：Elizabeth A. Kelley、Peter M. Maitlis

  DOI：10.1039/dt9790000167

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Pd: MVol.2, 123, page 403 - 405
  作者：

  DOI：——

  日期：——
• Syntheses of carbene and alkenyl derivatives of palladium. Solid-state structures of {(Me2NCS2) Pd(PEt3) [η1−C(N(CH3) C(CH3)3) CH3]}BPh4 and {(Me2NCS2)Pd(PEt3)[η1−C(NHC(CH3)3)CH3]}PF6 · Et2O
  作者：Daniel L. Reger、James E. Collins

  DOI：10.1016/0022-328x(94)05248-a

  日期：1995.4

  The reaction of (t)BuNC and (Me(2)NCS(2))Pd(PEt(3))CH3 yields (Me(2)NCS(2))Pd(PEt(3))[eta(1)-C(NC(CH3)(3)CH3]. Reaction of this amino acyl complex with [(CH3)(3))]BF4 yields, after anion exchange, Me(2)NCS(2))Pd(PEt(3))[eta(1)-C(NHC(CH3)(3)CH3]}BPh(4). An analogous reaction with NH4PF6 yields (Me(2)NCS(2))Pd(PEt(3))[eta(1)-C(NHC(CH3)(3)CH3]}PF6. Both of these carbene complexes have been characterized crystallographically. Crystal data: (Me(2)NCS(2))Pd(PEt(3))[eta(1)-C(N(CH3)C(CH3)(3))CH3]}BPh(4) triclinic, P (1) over bar, a = 12.253(12) Angstrom, b = 14.422(5) Angstrom, c = 11.564(5) Angstrom, alpha = 97.83(3)degrees, beta = 93.04(6)degrees, gamma = 85.21(5)degrees, V = 2018 Angstrom(3), Z = 2, T = 298 K, R(F) = 7.6%; (Me(2)NCS(2))Pd(PEt(3))[eta(1)-C(NHC(CH3)(3))CH3]}PF6 . Et(2)O triclinic, P (1) over bar, a = 12.844(2) Angstrom, b = 15.247(2) Angstrom, c = 8.312(2) Angstrom, alpha = 105.60(1)degrees, beta = 101.67(2)degrees, gamma = 90.20(1)degrees, V = 1533 Angstrom(3), Z = 2, T = 298 K, R(F) = 5.4%. In both complexes, the overall coordination geometry is approximately planar about both the palladium atom and carbene carbon atom, and these two planes are perpendicular. Reaction of (Me(2)NCS(2))Pd(PEt(3))[eta(1)-C(N(CH3)C(CH3)(3))CH3]}BPh(4) with LiCH3 results in deprotonation at the beta-carbon yielding (Me(2)NCS(2))Pd(PEt(3))[eta(1)-C(N(CH3)C(CH3)(3))-CH2], and this reaction is reversed with HBF4 . Et(2)O. The reaction of LiC(OCH2CH3)=CH2 with (Me(2)NCS(2))Pd(PEt(3))Cl yields (Me(2)NCS(2))Pd(PEt(3))[eta(1)-C(OCH2CH3)=CH2]. This alkenyl complex reacts with BH3 in ethanol to yield (Me(2)NCS(2))Pd(PEt(3))[eta(1)-CH(OCH2CH3)CH3]. (Me(2)NCS(2))Pd(PEt(3))[eta(1)-C(OCH2CH3)=CH2] also forms in the reaction of (Me(2)NCS(2))Pd(PEt(3))H and HC=COCH2CH3, along with both geometric isomers of (Me(2)NCS(2))Pd(PEt(3))[eta(1)-CH=CH(OCH2CH3)]. Reaction of phenylacetylene and (Me(2)NCS(2))Pd(PEt(3))H yields mainly (Me(2)NCS(2))Pd(PEt(3))eta(1)-C(Ph)=CH2) with small amounts of one of the other regioisomers present.