bismuth (III) nitrate pentahydrate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属氧阴离子化合物
• 英文名称: bismuth (III) nitrate pentahydrate
• 英文别名: bismuth nitrate pentahydrate；Bi(NO3)35H2O；bismuth nitrate；Bi(NO₃)₃·5H₂O；bismuth (III) nitrate；bismuth nitrate hydrate；Bismuth;nitrate;hydrate
• 化学式: Bi*5H₂O*3NO₃
• 分子量: 485.072
• InChiKey: FADJNIVFPZAURC-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.44
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  bismuth (III) nitrate pentahydrate 在 葡萄糖 、 十六烷基三甲基溴化铵 作用下， 以 甲醇 为溶剂， 反应 28.0h， 生成 bismuth(III) oxide
  参考文献：
  名称：

  A self-templating scheme for the synthesis of NiCo₂Se₄ and BiSe hollow microspheres for high-energy density asymmetric supercapacitors

  摘要：

  电极材料的多孔空心结构可以增大与电解质接触的表面积，加速离子和电子在氧化还原反应过程中的传输，从而增强电极材料的电化学性能。

  DOI：

  10.1039/d1ce01627j
• 作为产物：
  描述：

  氢化铋 、 硝酸 在 H₂O 、 (NH₄)2CO₃ 作用下， 以 硝酸 为溶剂， 以98%的产率得到bismuth (III) nitrate pentahydrate
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Bi: SVol., 153, page 650 - 653

  摘要：

  DOI：
• 作为试剂：
  描述：

  胡椒醇 、 potassium methanolate 在 碲化氢 、 bismuth (III) nitrate pentahydrate 、 5%-palladium/activated carbon 、 氧气 作用下， 以 甲醇 为溶剂， 60.0 ℃ 、101.33 kPa 条件下， 反应 8.0h， 以78%的产率得到甲基 1,3-苯并二恶唑-5-羧酸酯
  参考文献：
  名称：

  Aerobic Oxidation of Diverse Primary Alcohols to Methyl Esters with a Readily Accessible Heterogeneous Pd/Bi/Te Catalyst

  摘要：

  Efficient aerobic oxidative methyl esterification of primary alcohols has been achieved with a heterogeneous catalyst consisting of 1 mol % Pd/charcoal (5 wt %) in combination with bismuth(III) nitrate and tellurium metal. The Bi and Te additives significantly increase the reaction rate, selectivity, and overall product yields. This readily accessible catalyst system exhibits a broad substrate scope and Is effective with both activated (benzylic) and unactivated (aliphatic) alcohols bearing diverse functional groups.

  DOI：

  10.1021/ol402428e

文献信息

• Potent anticancer activity of a new bismuth (III) complex against human lung cancer cells
  作者：Ruizhuo Ouyang、Yang Yang、Xiao Tong、Kai Feng、Yaoqin Yang、Huihong Tao、Xiaoshen Zhang、Tianyu Zong、Penghui Cao、Fei Xiong、Ning Guo、Yuhao Li、Yuqing Miao、Shuang Zhou

  DOI：10.1016/j.jinorgbio.2016.12.006

  日期：2017.3

  The aim of this work is experimental study of an interesting bismuth(III) complex derived from pentadentate 2,6-pyridinedicarboxaldehyde bis(4N-methylthiosemicarbazone), [BiL(NO3)2]NO3 L = 2,6-pyridinedicarboxaldehyde bis(4N-methylthiosemicarbazone)}. A series of in vitro biological studies indicate that the newly prepared [BiL(NO3)2]NO3 greatly suppressed colony formation, migration and significantly

  这项工作的目的是实验研究有趣的从五齿的2,6-吡啶二甲醛甲醛双（4 N-甲基硫代半脲），[BiL（NO 3）2 ] NO 3 L = 2,6-吡啶二甲醛bis（4 N-甲基硫代半碳酮）}。一系列的体外生物学研究表明，新制备的[BiL（NO 3）2 ] NO 3大大抑制了人类肺癌细胞A549和H460的集落形成，迁移并明显诱导了其凋亡，但并未明显降低非癌性人类肺成纤维细胞（HLF）细胞系的细胞活力，显示出比其母体配体更高的抗癌活性，特别是最大抑制浓度（IC 50）的一半<3.5μM。此外，体内研究提供了足够的证据表明[BiL（NO 3）2 ] NO 3的治疗有效抑制了荷瘤小鼠（10 mg kg − 1，与对照组相比，肿瘤体积减少了97.92％，肿瘤重量减少了94.44％，并且没有显示出对小鼠体重和肝脏的有害影响。这些结果表明，游离配体与Bi（III）的配位可能是发现新的抗癌药物候选者的有趣且有效的策略。
• Structural insights into the polymorphism of bismuth(III) di-n-butyldithiocarbamate by X-ray diffraction, solid-state (13C/15N) CP-MAS NMR and DFT calculations
  作者：Vasantha Gowda、Bipul Sarma、Risto S. Laitinen、Anna-Carin Larsson、Alexander V. Ivanov、Dinu Iuga、Perttu Lantto、Oleg N. Antzutkin

  DOI：10.1016/j.poly.2017.03.018

  日期：2017.6

  polymorphs of a binuclear tris(di-n-butyldithiocarbamato)bismuth(III) complex, I and II, with an empirical formula of [BiS2CN(n-C4H9)2}3] were synthesised and characterised by X-ray diffraction (XRD), solid-state NMR and density functional theory (DFT) calculations. At the supramolecular level, these mononuclear molecular units interact in pairs via secondary Bi⋯S bonds, yielding binuclear formations of

  摘要合成了经验式为[Bi S2CN（n-C4H9）2} 3]的双核三（二-正丁基二硫代氨基甲酸酯）铋（III）晶体多晶型物I和II，并用X-进行了表征射线衍射（XRD），固态NMR和密度泛函理论（DFT）计算。在超分子水平上，这些单核分子单元通过次级Bi⋯S键成对相互作用，产生[Bi2 S2CN（n-C4H9）2} 6]的双核形成。多晶型物I（P 1）包含[Bi2 S2CN（n-C4H9）2} 6]的两个异构非中心对称双核分子，它们以构象体形式相互关联，因此具有四个结构不等价的铋原子和十二个不等价的铋原子二硫代氨基甲酸酯配体。相比之下，结构上较简单的多晶型物II（P 2 1 / n）以相应的中心对称双核形式的单分子形式存在，包括两个结构上等效的铋原子和三个结构上不同的二硫代氨基甲酸酯基团。通过在重结晶过程中改变溶剂体系，发现多晶型物I和II可相互转化。Sun等。（2012）报道了标题
• Photocatalytic aerobic oxidation of amines to imines on BiVO₄ under visible light irradiation
  作者：Bo Yuan、Ruifeng Chong、Bao Zhang、Jun Li、Yan Liu、Can Li

  DOI：10.1039/c4cc07097f

  日期：——

  BiVO4 was found to be an efficient photocatalyst under visible light irradiation for selective oxidation of amines to imines with high activity (99% conversion) and selectivity (up to 99%) using oxygen as an oxidant.

  发现BiVO 4是可见光照射下的一种有效的光催化剂，用于使用氧气作为氧化剂将胺选择性氧化为亚胺，具有高活性（99％转化率）和选择性（最高99％）。
• Perovskite-type ferromagnetic BiFeO3 nanopowder: a new magnetically recoverable heterogeneous nanocatalyst for efficient and selective transfer hydrogenation of aromatic nitro compounds into aromatic amines under microwave heating
  作者：S. Farhadi、N. Rashidi

  DOI：10.1007/s13738-012-0149-5

  日期：2012.12

  Perovskite-type ferromagnetic BiFeO3 nanopowder was readily synthesized via thermal decomposition of Bi[Fe(CN)6]·5H2O complex and characterized using thermal analysis (TGA/DSC), X-ray diffraction (XRD), Fourier-transformed infrared spectroscopy (FT–IR), scanning electron microscopy (SEM), transmission electron microscopy (TEM), energy-dispersive X-ray spectroscopy (EDX), magnetic measurement and Brunauer–Emmett–Teller (BET) specific surface area measurements. The magnetic measurements show a ferromagnetic behavior for the BiFeO3 nanoparticles at room temperature. This nanosized ferromagnetic oxide with an average particle size of approximately 20 nm and a specific surface area of 48.5 m2/g was used as a new magnetically recoverable heterogeneous nanocatalyst for the highly efficient and selective reduction of aromatic nitro compounds into their corresponding amines by using propan-2-ol as the hydrogen donor under microwave irradiation. This method is regio- and chemoselective, clean, inexpensive and compatible with the substrates having hydrogenlyzable or reducible functional groups. As compared with conventional heating, this method is very fast and suitable for the large-scale preparation of different substituted anilines as well as other arylamines. The catalyst can also be reused without loss of activity.

  钙钛矿型铁磁性BiFeO3纳米粉末通过Bi[Fe(CN)6]·5H2O配合物的热分解容易地合成，并使用热分析（TGA/DSC）、X射线衍射（XRD）、傅里叶变换红外光谱（FT-IR）、扫描电子显微镜（SEM）、透射电子显微镜（TEM）、能量色散X射线谱（EDX）、磁性测量及BET比表面积测量进行表征。磁性测量显示，BiFeO3纳米颗粒在室温下表现出铁磁性行为。这种具有约20 nm平均粒径和48.5 m²/g比表面积的纳米级铁磁性氧化物被用作一种新的磁性可回收异质纳米催化剂，用于在微波辐射下使用丙-2-醇作为氢供体，对芳香硝基化合物进行高效且选择性的还原为相应的胺。该方法具有区域和化学选择性，干净、成本低廉，并与具有可氢化或可还原官能团底物相兼容。与常规加热相比，这种方法非常快速，适合大规模制备不同取代的苯胺以及其他芳香胺。催化剂也可重复使用而不会损失活性。
• Synthesis of g-Bi2MoO6 by Co-precipitation Method and Evaluation for Photocatalytic Degradation of Rhodamine B, Crystal Violet and Orange II Dyes Under Visible Light Irradiation
  作者：Lavakusa Banavatu、D. Srinivasa Rao、K. Basavaiah

  DOI：10.14233/ajchem.2018.20917

  日期：——

  g-Bismuth molybdate (g-Bi2MoO6) catalyst has been successfully synthesized by co-precipitation method and followed by calcination using stoichiometry ratio of bismuth nitrate, nitric acid, ammonium molybdate as precursor materials. The synthesized g-Bi2MoO6 nanoparticles characterized by X-ray diffraction for identifying crystalline phases and particle size, Raman spectroscopy identifies active species during the reaction, Fourier transform infrared spectroscopy is to identify adsorbed species and to study the way in which these species are chemisorbed at the surface of the catalyst, UV-visible diffuse reflectance spectroscopy (UV-DRS) revealed for band energy of semiconductors, Field emission scanning electron microscopy (FE-SEM) is to determine morphology and shape of supported particles and Energy dispersive X-ray analysis (EDX) is for elemental analysis of synthesized nanoparticles. The photocatalytic activity of g−Bi2MoO6 catalyst evaluated using the degradation of Rhodamine-B, Crystal Violet and Orange II dyes under visible light irradiation at room temperature.

  采用共沉淀法并结合使用铋硝酸盐、硝酸和钼酸铵作为前驱体材料，按照化学计量比煅烧，成功合成了g-Bi2MoO6催化剂。通过X射线衍射表征合成的g-Bi2MoO6纳米颗粒的晶相和粒径，拉曼光谱用于鉴定反应中的活性物种，傅里叶变换红外光谱用于鉴定吸附物种并研究这些物种在催化剂表面的化学吸附方式，紫外-可见漫反射光谱揭示了半导体带隙能量，场发射扫描电子显微镜用于确定支撑颗粒的形态和形状，能量色散X射线分析用于合成纳米颗粒的元素分析。利用降解罗丹明-B、结晶紫和橙II染料在室温下可见光照射下评价g-Bi2MoO6催化剂的光催化活性。