aluminum(III) nitrate nonahydrate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 后过渡金属氧阴离子化合物
• 英文名称: aluminum(III) nitrate nonahydrate
• 英文别名: aluminum nitrate nonahydrate；aluminium nitrate nonahydrate；aluminium(III) nitrate nonahydrate；Al(NO₃)₃*9H₂O；aluminum nitrate nanohydrate；aluminium nitrate nanohydrate；aluminum nitrate；Aluminum;nitrate;hydrate
• 化学式: Al*9H₂O*3NO₃
• 分子量: 375.134
• InChiKey: RZBBQIWPPHHPJX-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -1.44
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  63.9
• 氢给体数：
  1
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  aluminum(III) nitrate nonahydrate 以 水 为溶剂， 生成 aluminium trinitrate
  参考文献：
  名称：

  Synthesis and characterization of nanocrystalline Nd3+-doped gadolinium scandium aluminum garnet powders by a gel-combustion method

  摘要：

  Nd3+-doped gadolinium scandium aluminum garnet (Nd:GSAG) precursor was synthesized by a gel combustion method using metal nitrates and citric acid as raw materials. The structure and morphology of the precursor and the sintered powders were studied by means of X-ray diffraction (XRD), infrared spectroscopy (IR) and transmission electron microscopy (TEM). The results showed that the precursor transformed into pure GSAG polycrystalline phase at about 800 degrees C, and the powders sintered at 800-1000 degrees C were well-dispersed with average particle sizes in the range of 30-80 nm. Optical properties of Nd:GSAG nano-powders were characterized by using photoluminescence spectroscopy. The highest photoluminescence intensity was achieved for the powder sintered at 900 degrees C. (C) 2012 Elsevier Ltd. All rights reserved.

  DOI：

  10.1016/j.materresbull.2012.03.039
• 作为产物：
  描述：

  aluminium trinitrate 在 amyl alcohol 作用下， 以 硝酸 为溶剂， 生成 aluminum(III) nitrate nonahydrate
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Al: MVol.B1, 4.5, page 149 - 156

  摘要：

  DOI：
• 作为试剂：
  描述：

  苯甲醛 在 aluminum(III) nitrate nonahydrate 作用下， 反应 0.5h， 生成 6-甲基-4-苯基-2-硫代-1,2,3,4-四氢嘧啶-5-羧酸乙酯
  参考文献：
  名称：

  硝酸铝九水合物（Al（NO3）3⋅9H2O）：一种由苄醇一锅法合成Biginelli化合物的高效氧化剂

  摘要：

  据报道，在存在铝的情况下，可以从伯芳基醇，β-酮酸酯，尿素或硫脲合成3,4-二氢嘧啶-2（1 H）-一或硫酮衍生物的清洁，高效的串联氧化环缩合工艺。 （NO 3）3 ⋅9ħ 2 O作为氧化剂催化剂（方案，表5）。

  DOI：

  10.1002/hlca.201100242

文献信息

• Nickel Schiff-base complexes immobilized on boehmite nanoparticles and their application in the oxidation of sulfides and oxidative coupling of thiols as novel and reusable nano organometal catalysts
  作者：Arash Ghorbani-Choghamarani、Bahman Tahmasbi、Fatemeh Arghand、Sara Faryadi

  DOI：10.1039/c5ra14974f

  日期：——

  Ni-complex-boehmite was prepared in water at room temperature using commercially available materials and applied as an efficient nanocatalyst in the oxidation of sulfides and thiols.

  Ni-复合物氢氧化铝在室温下使用商业可获得的材料制备，并应用为高效的纳米催化剂在硫醚和硫醇的氧化反应中。
• Structure Lattice-Dimensionality and Spectroscopic Property Correlations in Novel Binary and Ternary Materials of Group 13 Elements with α-Hydroxycarboxylic Benzilic Acid and Phenanthroline
  作者：E. Halevas、A. Hatzidimitriou、M. Bertmer、A. A. Vangelis、A. Antzara、C. Mateescu、A. Salifoglou

  DOI：10.1021/cg500638z

  日期：2014.8.6

  To probe and understand the structural and coordinative flexibility of Group 13 ions with α-hydroxycarboxylic acids, leading to crystalline inorganic–organic hybrid materials with distinct lattice architecture, dimensionality, and spectroscopic properties, the systematic synthesis and physicochemical properties of binary and ternary B(III), Al(III), Ga(III), In(III), and Tl(I)-benzilic acid-(phenanthroline)

  为了探查和理解第13族离子与α-羟基羧酸的结构和配位灵活性，从而导致具有独特的晶格结构，尺寸和光谱性质的结晶无机-有机杂化材料，对二元和三元B（系统地合成和理化性质）进行了研究。 III），Al（III），Ga（III），In（III）和Tl（I）-苯甲酸-（菲咯啉）体系在水-醇混合物中进行了研究。第13组离子与苯甲酸和菲咯啉（phen）的化学计量反应提供了新材料[B（C 14 H 10 O 3）2 ]（C 3 H 5 N 2）·H 2 O（1），[Al（C 14 H 11 O 3）3 ]·0.5C 2 H 5 OH·4.5H 2 O（2），[Ga（C 14 H 11 O 3）3 ]·CH 3 OH·3H 2 O （3），[In（C 14 H 11 O 3）4 ]·C 3 H 5 N 2 ·C 2 H 5 OH·H 2 O（4），[Tl（C 14 H 11O 3）] n（5），[Tl 2（C
• Metal–Organic Framework with Dual Active Sites in Engineered Mesopores for Bioinspired Synergistic Catalysis
  作者：Yangjian Quan、Yang Song、Wenjie Shi、Ziwan Xu、Justin S. Chen、Xiaomin Jiang、Cheng Wang、Wenbin Lin

  DOI：10.1021/jacs.0c02966

  日期：2020.5.13

  strong Lewis acid and photoredox sites in engineered mesopores. Al-MOF (1) with mixed 2,2'-bipyridyl-5,5-dicarboxylate (dcbpy) and 1,4-benzenediacrylate ligands was oxidized with ozone and then tiflated to generate strongly Lewis acidic Al-OTf sites in the mesopores, followed by the installation of [Ir(ppy)2(dcbpy)]+ (ppy = 2-phenylpyridine) sites to afford 1-OTf-Ir with both Lewis acid and photoredox

  在这里，我们通过在工程介孔中安装强路易斯酸和光氧化还原位点来报告模拟酶的金属有机框架 (MOF) 1-OTf-Ir 的设计。具有混合 2,2'-联吡啶-5,5-二羧酸酯 (dcbpy) 和 1,4-苯二丙烯酸酯配体的 Al-MOF (1) 用臭氧氧化，然后 tiflated 以在介孔中生成强路易斯酸性 Al-OTf 位点，然后安装 [Ir(ppy)2(dcbpy)]+ (ppy = 2-苯基吡啶) 位点以提供具有路易斯酸和光氧化还原位点的 1-OTf-Ir。1-OTf-Ir 有效地催化 N-羟基邻苯二甲酰亚胺酯或芳基溴甲基酮与乙烯基或炔基氮杂芳烃的还原交叉偶联，以提供新的氮杂芳烃衍生物。1-OTf-Ir 能够催化合成抗胆碱能药物苯那敏和氯苯那敏。
• First report of the direct supporting of palladium-arginine complex on boehmite nanoparticles and application in the synthesis of 5-substituted tetrazoles
  作者：Bahman Tahmasbi、Arash Ghorbani-Choghamarani

  DOI：10.1002/aoc.3644

  日期：2017.7

  Boehmite nanoparticles are aluminium oxide hydroxide (γ‐AlOOH) particles, which were prepared using a simple and inexpensive procedure in water at room temperature and further modified using arginine. Subsequently palladium particles were immobilized on their surface to prepare Pd‐Arg@boehmite. This novel nanostructured compound was fully characterized using thermogravimetric analysis, X‐ray diffraction

  勃姆石纳米颗粒是氢氧化铝（γ-AlOOH）颗粒，使用简单且廉价的方法在室温下于水中制备，然后使用精氨酸进一步改性。随后，将钯颗粒固定在其表面上以制备Pd-Arg @ boehmite。通过热重分析，X射线衍射，电感耦合等离子体光学发射（ICP-OES）和能量色散X射线光谱学以及扫描和透射电子显微镜学对这种新型纳米结构化合物进行了全面表征。最后，该催化剂被用作湿气和空气稳定的非均相材料，用于合成5取代的1 H–四唑衍生物。使用热过滤和ICP-OES研究了钯的浸出和催化剂的非均质性。该催化剂显示出显着的可回收性。这项工作的新颖之处在于，它是首次将氨基酸接枝到勃姆石纳米颗粒上。
• Palladium fabricated on boehmite as an organic–inorganic hybrid nanocatalyst for C–C cross coupling and homoselective cycloaddition reactions
  作者：Bahman Tahmasbi、Arash Ghorbani-Choghamarani、Parisa Moradi

  DOI：10.1039/c9nj06129k

  日期：——

  Pd-adenine@boehmite has been prepared and characterized by FT-IR, BET, SEM, EDS, WDX, TGA, XRD and AAS techniques and further was used as catalyst in organic reactions. The reused catalyst was characterized by TEM, EDS, WDX, AAS and FT-IR techniques.

  Pd-腺嘌呤@铝石英已通过FT-IR、BET、SEM、EDS、WDX、TGA、XRD和AAS技术制备和表征，并进一步用作有机反应中的催化剂。再生催化剂通过TEM、EDS、WDX、AAS和FT-IR技术进行表征。