ZnCl₂*H₂O

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: ZnCl₂*H₂O
• 英文别名: ZINC;chloride;hydrate
• 化学式: 2Cl*H₂O*Zn
• 分子量: 154.311
• InChiKey: VOSQOLXQDQZVCL-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  -3.82
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  ZnCl₂*H₂O 以 melt 为溶剂， 生成 zinc(II) chloride
  参考文献：
  名称：

  Head-on versus Side-on [5−5]Bitrovacenes Featuring Benzene and Naphthalene Units as Spacers:  How π-Stacking Affects Exchange Coupling and Redox Splitting

  摘要：

  The biradicals 1,8-di([5]trovacenyl)naphthalene (6), 1,5-di((5]trovacenyl)naphthalene (7), and 1,3-di([5]trovacenyl)benzene (8) and the monoradical 1-[51trovacenylnaphthalene (9) have been prepared and studied by means of single-crystal X-ray diffraction 6, 8, 9), cyclic voltammetry, EPR spectroscopy, and magnetic susceptometry. Comparison of the, magnetic properties of 6-9 reveals that pi-stacking, as encountered in 6, largely enhances exchange interaction between the two singly occupied V(3d(z)(2)) orbitals. The effect of pi-stacking on the electrochemical properties, as manifested in the redox splitting between consecutive electron transfer steps, is less pronounced. Redox splittings deltaE(1/2) for consecutive reductions exceed those for oxidations of binuclear trovacenes, deltaE(1/2)(2+/+, +/0) being apparent for pi-stacked 6 only, Because of the orthogonality of the metal-centered redox orbitals V1(d(z)(2)) and V2(d(z)(2)) and the eta(5)-cyclopentadienyl pi-orbitals, electro- and magnetocommunication are indirect processes. Electrocommunication rests on changes of the donor/acceptor properties of V1,V2 caused by oxidation or reduction which govern metal-ligand charge distribution; the latter changes are transmitted via the spacer. Magnetocommunication takes the form of antiferromagnetic coupling, which can be traced to spin polarization of filled pi-orbitals of the bridge by orthogonal singly occupied vanadium 3d(z)(2)orbitals.

  DOI：

  10.1021/om020520y

文献信息

• Synthesis, crystal structure and investigation of the catalytic and spectroscopic properties of a Zn(II) complex with coumarin-hydrazone ligand
  作者：Sanam Aslkhademi、Nader Noshiranzadeh、Mirabdullah Seyed Sadjadi、Kheirollah Mehrani、Nazanin Farhadyar

  DOI：10.1016/j.poly.2018.12.023

  日期：2019.3

  Single crystal X-ray analysis indicated that the Zn(II) ion in complex 1 has a distorted square pyramidal environment and the coumarin-hydrazone ligand is coordinated as a mononegative tridentate ONO-donor ligand, (HL)−. The photoluminescent studies indicated that complex 1 has emission at about 470 nm. The catalytic potential of complex 1 was investigated for preparing tetrazole based compounds from the

  摘要由等摩尔量的ZnCl2·4H2O与（1）的反应制得了具有香豆素-配体[ZnCl（HL）（CH3OH）0.76（H2O）0.24]·0.24（CH3OH）（1）的Zn（II）配合物。 E）在甲醇溶剂中的2-羟基-N'-（1-（2-氧代-2H-铬-3-基）亚乙基）苯甲酰肼（H2L）。通过元素分析，光谱法和单晶X射线衍射研究对复合物进行了表征。单晶X射线分析表明，配合物1中的Zn（II）离子具有扭曲的方形锥体环境，香豆素marin配体被配制成单负三齿ONO供体配体（HL）-。光致发光研究表明，配合物1在约470nm处具有发射。为了从叠氮化物-腈的环加成反应制备基于四唑的化合物，研究了配合物1的催化潜力。催化反应在作为绿色溶剂的水中进行。结果表明，配合物1是用于制备四唑化合物的活性催化剂。还考虑了温度和与腈基连接的取代基的电子性质对该催化体系活性的影响。
• 一种可见光下催化降解有机染料的锌金属有机 骨架材料
  申请人：东北师范大学

  公开号：CN104402914B

  公开（公告）日：2016-02-24

  本发明的用于可见光催化降解有机染料的新型金属有机骨架材料及其制备方法属于无机化学、有机化学、材料化学交叉领域。本发明以9,10-二（乙炔基吡啶）蒽作为配体，与六水合硝酸锌/三水合氯化锌和1,4-对苯二酸在有机溶剂中发生溶剂热反应，经过洗涤干燥，得到一种新型的锌金属有机骨架晶体材料，采用该方法制备的金属有机骨架化合物具有规则的骨架结构和可调控的粒子尺寸，本发明方法操作简便，节约成本，在可见光下催化降解有机染料技术领域具有重要意义。
• Transition metal chelates of novel ligand bearing Isatin moiety: Synthesis, Structural characterization, Voltammetric analysis of heavy metals, Molecular docking and Biological evaluation
  作者：Lubna Afroz、M.H. Moinuddin Khan、H.M. Vagdevi、Malathesh Pari、R. Mohammed Shafeeulla、Anees Fathima

  DOI：10.1016/j.molstruc.2023.136200

  日期：2023.12

  anticancer properties of ligand HBH and its 3d-metal complexes. The results from the biological screening exposed the fact that the coordinated compounds demonstrated significantly higher pharmacological activities than their ligand. Additionally, molecular docking study was undertaken for antimicrobial and anticancer receptors to determine binding modes of ligand and its metal chelates.

  本研究支持将带有靛红部分的新型配体 (E)-2-羟基-N'-(2-氧吲哚啉-3-亚基)苯甲酰肼 (HBH) 的 3d-金属螯合物（Co(II)、Ni(II)、Cu(II) 和 Zn(II)）的实验和药理学研究相结合。采用一系列物理和光谱方法来表征合成的配体及其 3d 金属配合物。根据光谱方法，所有金属配位化合物均表现出三齿配位和八面体几何形状。此外，具有多壁碳纳米管的改性钴（II）金属络合物碳电极用作传感器来识别三种最有害的重金属离子（Pb 2+、Hg 2+、Cd 2+）单独并同时使用 CV 和 LSV 方法。一般来说，所提出的传感器可靠、可重复且具有高灵敏度，确保其在实际样品中的实际实施并获得令人满意的结果。此外，本研究的一个重要方面是探索配体 HBH 及其 3d 金属配合物的抗菌、抗氧化、抗肥胖和抗癌特性。生物筛选的结果揭示了配位化合物比其配体表现出显着更高的药理活性的事实。此外，还对
• Parihar, D. S.; Nagar, P. N., Synthesis and Reactivity in Inorganic and Metal-Organic Chemistry, 1995, vol. 25, p. 625 - 638
  作者：Parihar, D. S.、Nagar, P. N.

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