copper sodium phosphate

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属氧阴离子化合物
• 英文名称: copper sodium phosphate
• 英文别名: Copper;sodium;phosphate
• 化学式: Cu*Na*O₄P
• 分子量: 181.507
• InChiKey: MNPICTSLNPAQOZ-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -5.82
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  86.2
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  sodium pyrophosphate 、 copper(II) oxide 以 neat (no solvent) 为溶剂， 生成 copper sodium phosphate
  参考文献：
  名称：

  Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B3, 16, page 1007 - 1009

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Cu: MVol.B3, 16, page 1007 - 1009
  作者：

  DOI：——

  日期：——
• Synthesis, structure, and magnetic properties of two quasi-low-dimensional antiferromagnets, NaMnAsO4 and β-NaCuPO4
  作者：Mutlu Ulutagay-Kartin、Kristen M.S.G. Etheredge、George L. Schimek、Shiou-Jyh Hwu

  DOI：10.1016/s0925-8388(02)00242-6

  日期：2002.5

  Crystals of NaMnAsO4 (1) and beta-NaCuPO4 (2) were grown by conventional high-temperature, solid-state methods in molten salt media. The compounds were characterized by single crystal X-ray diffraction and magnetic susceptibility measurements. Compound 1 crystallizes in an orthorhombic lattice with a=10.853(3) Angstrom, b=6.383(2) Angstrom, c=5.157(2) Angstrom, and V=357.2(2) Angstrom(3); Pnma (No. 62); Z=4, while 2 crystallizes in a monoclinic lattice with a=6.943(1) Angstrom, b=8.848(1) Angstrom, c=5.013(1) Angstrom. beta=97.25(1)degrees and V=305.53(9) Angstrom(3); P2(1)/n (No. 14); Z=4. The new sodium manganese(II) arsenate is isostructural with LiMnAsO4, which contains single layers of (100) perovskite sheet made of distorted MnO6 octahedra. Sodium copper(II) phosphate adopts a known beta-form that possesses linear chains of edge-shared CuO6 octahedra depicting a [4+2] Jahn-Teller distortion. These structurally isolated magnetic layers and chains are incorporated into a three-dimensional lattice via the linkage by closed-shell, non-magnetic oxy anions. Magnetic susceptibility measurements reveal that the title compounds are antiferromagnetic with the negative Weiss constants theta=-76.99 K (1) and -33.85 K (2). At low-temperatures, magnetic susceptibility data feature a field-induced antiferromagnetic-to-ferromagnetic transition. The field dependence studies further indicate that these phenomena could be attributed to metamagnetism and a spin-flop transition, respectively. The current work in the exploratory synthesis of quasi-low-dimensional TM-based oxy compounds gives a new perspective to the continued investigation of experimental and theoretical developments of magnetic models. (C) 2002 Elsevier Science B.V. All rights reserved.
• High-Temperature Synthesis of an Open-Framework Compound, Na2Cs2Cu3(P2O7)2Cl2 (CU-4), by Molten-Salt Methods
  作者：Qun Huang、Shiou-Jyh Hwu、Xunhua Mo

  DOI：10.1002/1521-3773(20010504)40:9<1690::aid-anie16900>3.0.co;2-e

  日期：2001.5.4
• Kawahara, A.; Kageyama, T.; Watanabe, I., Acta Crystallographica, Section C: Crystal Structure Communications, <hi>1993</hi>, vol. 49, p. 1275 - 1277
  作者：Kawahara, A.、Kageyama, T.、Watanabe, I.、Yamakawa, J.

  DOI：——

  日期：——
• Quarton, M.; Kolsi, A. W., Acta Crystallographica, Section C: Crystal Structure Communications, <hi>1983</hi>, vol. 39, p. 664 - 667
  作者：Quarton, M.、Kolsi, A. W.

  DOI：——

  日期：——