Synthesis, Structure, and Characterization of the Hydrogen-Substituted Imido Complex TiCl2(NH)(OPPh3)2
摘要:
The first hydrogen-substituted imido complex of the group 4 metals has been synthesized. Its crystal structure shows the titanium atom in square pyramidal geometry with a very short titanium-nitrogen bond length. This complex represents a structural model for species that have been frequently proposed as intermediates in chemical vapor deposition processes.