1,2-bis[(isopropylideneaminooxy)dimethylsilyl]ethylene

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1,2-bis[(isopropylideneaminooxy)dimethylsilyl]ethylene
• 英文别名: N-[2-[dimethyl-(propan-2-ylideneamino)oxysilyl]ethenyl-dimethylsilyl]oxypropan-2-imine
• 化学式: C₁₂H₂₆N₂O₂Si₂
• 分子量: 286.522
• InChiKey: RSACTSMQAROYFB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.86
• 重原子数：
  18.0
• 可旋转键数：
  6.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.67
• 拓扑面积：
  43.18
• 氢给体数：
  0.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  1,2-双氯二甲基硅基化乙烯 、 丙酮肟 以 甲苯 为溶剂， 反应 2.0h， 以73%的产率得到1,2-bis[(isopropylideneaminooxy)dimethylsilyl]ethylene
  参考文献：
  名称：

  摘要：

  Reactions of a series of 1,2-bis(methylchlorosilyl)ethylenes and -acetylenes Me(n)Cl(3-n)SiZ-SiCl3-nMen (Z = CH=CH, Cequivalent toC; n=0-2) with ethanol and acetoxime were studied. Novel alkoxy- and isopropylideneaminooxysilanes were obtained and characterized. A relation was found between the activity of Si-Cl bonds in the reactions studied and the structure of the carbon-carbon bridge.

  DOI：

  10.1023/a:1013225112569

文献信息

• ——
  作者：V. G. Lakhtin、V. M. Nosova、A. V. Kisin、P. V. Ivanov、E. A. Chernyshev

  DOI：10.1023/a:1013225112569

  日期：——

  Reactions of a series of 1,2-bis(methylchlorosilyl)ethylenes and -acetylenes Me(n)Cl(3-n)SiZ-SiCl3-nMen (Z = CH=CH, Cequivalent toC; n=0-2) with ethanol and acetoxime were studied. Novel alkoxy- and isopropylideneaminooxysilanes were obtained and characterized. A relation was found between the activity of Si-Cl bonds in the reactions studied and the structure of the carbon-carbon bridge.