sodium octadecylate

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: sodium octadecylate
• 英文别名: sodium salt of 1-octadecanol；sodium;octadecan-1-olate
• 化学式: C₁₈H₃₇O*Na
• 分子量: 292.481
• InChiKey: SBEDULGUSDGGHS-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.61
• 重原子数：
  20
• 可旋转键数：
  16
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  23.1
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  sodium octadecylate 在 四氯化锡 作用下， 以 六甲基磷酰三胺 为溶剂， 生成 1-[((Z)-Octadec-9-enyl)oxy]-3-octadecyloxy-propan-2-ol
  参考文献：
  名称：

  Synthesis of glycerol deuterated ether phospholipids

  摘要：

  1,3-Dialkyl glycerophosphocholines deuterated on the glycerol moiety were synthesized starting either from propiolic acid to yield a pentadeuterated compound, or from epibromohydrin to give a monodeuterated substance. Copyright (C) 1996 Elsevier Science Ltd

  DOI：

  10.1016/0040-4039(96)01218-x
• 作为产物：
  描述：

  硬脂醇 生成 sodium octadecylate
  参考文献：
  名称：

  RAO, SAMALA JAGADISHWAR;BHALERAO, UDAY T.;TILAK, BAL DATTATREYA, INDIAN J. CHEM. B., 27,(1988) N 3, C. 277-278

  摘要：

  DOI：

文献信息

• Phospha-S-triazines. IX. Chloro-substituted monophospha-S-triazines and derivatives
  作者：K.J.L. Paciorek、J.H. Nakahara、M.E. Smythe、D.H. Harris、R.H. Kratzer

  DOI：10.1016/s0022-1139(00)81134-3

  日期：1985.7

  tetrachlorophenylphosphorane instead of phosphorus pentachloride; phenoxy and stearyloxy derivatives were formed without difficulty. All the compounds, with the exception of 1-stearyloxy(phenyl)phospha-3,5-bis(perfluoro- n-heptyl)-2,4,6-triazine, exhibited the characteristic mass spectral fragmentation patterns associated with the monophospha- s-triazine ring system.

  通过五氯化磷与各自的亚氨基y啶的相互作用，合成了1-二氯磷基-3,5-双（全氟-正庚基）-2,4,6-三嗪及其一种全氟烷基醚类似物。随后，用叠氮基团取代氯基很容易。用四氯苯基磷烷代替五氯化磷通过平行方法制得1-氯（苯基）-膦-3，5-双（全氟正庚基）-2，4，6-三嗪。毫不费力地形成苯氧基和硬脂氧基衍生物。除1-硬脂基氧基（苯基）膦-3,5-双（全氟-正庚基）-2,4,6-三嗪外，所有化合物均表现出与单磷-三嗪相关的特征性质谱碎裂模式。铃声系统。
• Cambi, L., Atti della Reale Accademia dei Lincei. Serie 5: Rendiconti Classe di scienze fisiche, matematiche e naturali., 1964, vol. 23 I, p. 244 - 252
  作者：Cambi, L.

  DOI：——

  日期：——
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: B: B-Verb.8, 8.2, page 109 - 115
  作者：

  DOI：——

  日期：——
• Mayer,B.; Asselineau,J., Chimica Therapeutica, 1968, vol. 3, p. 325 - 332
  作者：Mayer,B.、Asselineau,J.

  DOI：——

  日期：——
• Homochiral Supramolecular Polymerization of an “<i>S</i>”-Shaped Chiral Monomer:  Translation of Optical Purity into Molecular Weight Distribution
  作者：Yasuhiro Ishida、Takuzo Aida

  DOI：10.1021/ja028403h

  日期：2002.11.1

  An "S"-shaped chiral motif of a p-xylylene-bridged bis(cyclic dipeptide) (1), having four hydrogen-bonding amide functionalities, formed a homochiral supramolecular polymer in solution. X-ray crystallography of a slightly modified version of 1 for an enhanced crystallinity showed one-dimensional columnar assemblies via four double hydrogen-bonding interactions. Model studies with half-protected analogues of 1 indicated a nearly perfect enantioselectivity in hydrogen-bonding dimerization. When 1 was not racemic but enriched in either of the enantiomers, a supramolecular polymer with a bimodal molecular weight distribution resulted, due to the formation of two homochiral polymers with different molecular weights. By taking advantage of this, separation of optically pure 1 from an enantiomerically unbalanced mixture was possible by means of size-exclusion chromatography.