双(2,2-二甲基丙基)膦 | 57620-76-5

• 分子结构分类: 有机化合物 - 有机磷化合物
• 中文名称: 双(2,2-二甲基丙基)膦
• 英文名称: Bis-neopentylphosphin
• 英文别名: Bis(2,2-dimethylpropyl)phosphane
• CAS: 57620-76-5
• 化学式: C₁₀H₂₃P
• 分子量: 174.266
• InChiKey: LGJHKAMPHVQRLU-UHFFFAOYSA-N

物化性质

• 沸点：
  208.7±9.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  3.4
• 重原子数：
  11
• 可旋转键数：
  4
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  双(2,2-二甲基丙基)膦 在 potassium tert-butylate 、 sodium 作用下， 生成
  参考文献：
  名称：

  Poly(tertiary phosphines and arsines). XIII. Neopentyl poly(tertiary phosphines)

  摘要：

  DOI：

  10.1021/jo00868a016
• 作为产物：
  描述：

  氯化新戊烷基镁 在 lithium aluminium tetrahydride 、 三氯化磷 作用下， 生成 双(2,2-二甲基丙基)膦
  参考文献：
  名称：

  Poly(tertiary phosphines and arsines). XIII. Neopentyl poly(tertiary phosphines)

  摘要：

  DOI：

  10.1021/jo00868a016

文献信息

• CARBOXYLATE METAL COMPLEX AND CATALYST FOR OLEFIN POLYMERIZATION
  申请人：Ito Shingo

  公开号：US20130158223A1

  公开（公告）日：2013-06-20

  The present invention provides a metal complex of group 10 elements of the periodic table having a carboxylate structure represented by formula (C2); a catalyst for polymerization of olefin mainly comprising the metal complex; and a method for producing polymers by homopolymerizing olefin represented by formula (1), polymerizing two or more kinds of the above olefin, or copolymerizing olefin represented by formula (1) with polar group-containing olefin represented by formula (2) (the meaning of the symbols are as set forth in the description) using the catalyst. A metal complex of group 10 elements of the periodic table, in which all of the coordinating atoms to the metal are a hetero atom is stable and useful as a catalyst component for olefin polymerization, and can be used for a long time in homopolymerization of olefin or copolymerization of two or more kinds of olefin.

  本发明提供了一种具有由式（C2）表示的羧酸盐结构的周期表第10族元素的金属配合物；主要包括所述金属配合物的烯烃聚合催化剂；以及通过使用所述催化剂，通过将由式（1）表示的烯烃进行均聚合，聚合两种或更多种上述烯烃，或将由式（1）表示的烯烃与由式（2）表示的含极性基团的烯烃进行共聚合来生产聚合物的方法。周期表第10族元素的金属配合物，其中与金属配位的所有原子均为杂原子，稳定且可用作烯烃聚合的催化剂组分，并可在烯烃的均聚合或两种或更多种烯烃的共聚合中长时间使用。
• PRODUCTION METHOD OF COPOLYMER OF ALLYL MONOMER CONTAINING POLAR GROUP
  申请人：The University of Tokyo

  公开号：EP2470575B1

  公开（公告）日：2013-10-09
• PREPARATION OF FUNCTIONAL POLYMERS USING PHOSPHIDE INITIATORS
  申请人：Bridgestone Corporation

  公开号：EP2831128B1

  公开（公告）日：2016-11-30
• CATALYST FOR SYNTHESIZING POLYOLEFINS
  申请人：The University Of Tokyo

  公开号：EP3190120B1

  公开（公告）日：2021-11-17
• METHOD FOR PRODUCING POLAR GROUP-CONTAINING OLEFIN COPOLYMERS
  申请人：Okumura Yoshikuni

  公开号：US20130165607A1

  公开（公告）日：2013-06-27

  The present invention relates to a method of producing a polymer in the method for producing a copolymer of olefin and a polar group-containing monomer represented by formula (1): C(R 1 ) 2 ═C(R 1 )(C(R 1 ) 2 ) n R 2 (1) (in the formula, the symbols have the same meanings as described in the description), the method comprising using a complex of a metal in Group 10 of the periodic table as a catalyst; and supplying a catalyst solution separated from a polymer after the polymerization reaction to a polymerization reaction system to recycle and re-use the catalyst. The production method of the present invention can dramatically reduce the catalyst cost.