Tribromonickel

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: Tribromonickel
• 化学式: Br₃Ni
• 分子量: 298.402
• InChiKey: UDJLTPRXSDTXLT-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  -8.99
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  镍 、 氢化铋 以 neat (no solvent) 为溶剂， 生成 Tribromonickel
  参考文献：
  名称：

  Superconducting and Normal State Properties of NiBi ₃

  摘要：

  The electrical resistivity, heat capacity, superconducting upper critical magnetic field and magnetic susceptibility of NiBi3 have been measured for the polycrystal and needle crystal. The temperature dependence of the resistivity rho(T) above the superconducting transition temperature can be explained by the parallel resistor formula. From rho(T), using the sum of two Gruneisen-Bloch functions, we have obtained that the lower main value of the Debye temperature is 70K and the higher one is 300K. This is compatible with omega(E) drop 30.6K and omega(D) drop 141K obtained from the heat capacity using the hybrid Einstein-Debye model. We have compared the angular dependence of the critical magnetic field with that of the effective mass model and found an anisotropic mass ratio m parallel to(b)/m(perpendicular to b) approximate to 0.17 for the needle (parallel to b-axis) crystal. Almost the same value of 0.14 is also obtained from the analysis of rho(T).

  DOI：

  10.1143/jpsj.69.3017

文献信息

• Reactions of N,N′-ethylenebis(salicylideneiminato)metal(II) complexes with electrons, halide ions and halogen radicals in gaseous plasmas
  作者：G.W. Dillow、I.K. Gregor

  DOI：10.1016/s0020-1693(00)90414-6

  日期：1989.1

  Abstract Results of the gas phase reactions between a series of N , N′ -ethylenebis(salicylideneiminato)metal(II) complexes (metal = Co, Ni, Cu, Zn) and electrons, radicals and negative ions contained in plasmas of the halogenated reagent gases NF 3 , CF 2 Cl 2 and CF 3 Br are presented. Resonance electron capture and nucleophilic addition of a halide ion to the metal complexes compete as the two primary

  摘要一系列N，N'-乙撑双（水杨酰亚胺亚胺基）金属（II）配合物（金属= Co，Ni，Cu，Zn）与卤化试剂血浆中所含的电子，自由基和负离子之间的气相反应结果提出了气体NF 3，CF 2 Cl 2和CF 3 Br。共振电子捕获和卤化物离子向金属络合物的亲核加成，是气态等离子体中两个主要电离过程的竞争。由这些过程产生的离子的相对丰度分别根据还原的难易程度和配合物的路易斯酸度来解释。氟离子还通过质子提取诱导负离子形成。在电离过程中，
• Superconducting and Normal State Properties of NiBi_{<b> 3</b>}
  作者：Yasunobu Fujimori、Shin-ichi Kan、Bunjyu Shinozaki、Takasi Kawaguti

  DOI：10.1143/jpsj.69.3017

  日期：2000.9

  The electrical resistivity, heat capacity, superconducting upper critical magnetic field and magnetic susceptibility of NiBi3 have been measured for the polycrystal and needle crystal. The temperature dependence of the resistivity rho(T) above the superconducting transition temperature can be explained by the parallel resistor formula. From rho(T), using the sum of two Gruneisen-Bloch functions, we have obtained that the lower main value of the Debye temperature is 70K and the higher one is 300K. This is compatible with omega(E) drop 30.6K and omega(D) drop 141K obtained from the heat capacity using the hybrid Einstein-Debye model. We have compared the angular dependence of the critical magnetic field with that of the effective mass model and found an anisotropic mass ratio m parallel to(b)/m(perpendicular to b) approximate to 0.17 for the needle (parallel to b-axis) crystal. Almost the same value of 0.14 is also obtained from the analysis of rho(T).