bis(diethylamido)zinc

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: bis(diethylamido)zinc
• 化学式: C₈H₂₀N₂Zn
• 分子量: 209.65
• InChiKey: XUTHXGGERJGLFK-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.4
• 重原子数：
  6.0
• 可旋转键数：
  2.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  14.1
• 氢给体数：
  0.0
• 氢受体数：
  0.0

反应信息

• 作为产物：
  描述：

  lithium diethylamide 、 zinc(II) chloride 以 乙醚 为溶剂， 以89%的产率得到bis(diethylamido)zinc
  参考文献：
  名称：

  The properties of some volatile alkyl (di-alkylamido) zinc (11) and bis(di-alkylamido) zinc compounds: potential zinc precursors in MOCVD

  摘要：

  A series of compounds with the general formula Zn(NR2)(2) where R = Et, 'Pr, 'Bu; or RZnNR'(2) where R = Me, Et; R' = Et,'Pr,'Bu, SiMe3; and R = Np or 'Bu; R' = Et, 'Pr, 'Bu; have been synthesized and characterised. Vapour pressure measurements have been carried out to assess the potential suitability of such compounds as zinc precursors. Vapour pressures of alkyl(di-alkylamido)zinc(II) appear to be ca 5 Torr at 0 degrees C which makes then suitable zinc precursors for MOCVD (Molecular Organic Chemical Vapour Deposition) whereas bis(di-alkylamido)zinc(II) are viscous liquids with low volatility. (C) 1997 Elsevier Science Ltd.

  DOI：

  10.1016/s0277-5387(97)00116-2

文献信息

• Reactions of allylic and propargylic amines and ethers with Zn[Co(CO)4]2
  作者：P.H.M. Budzelaar、H.J. Alberts-Jansen、J. Boersma、G.J.M. van de Kerk

  DOI：10.1016/s0277-5387(00)81616-2

  日期：1982.1