N-methyl-N-[methyl(diethoxy)silylmethyl]amine

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: N-methyl-N-[methyl(diethoxy)silylmethyl]amine
• 英文别名: 1-[diethoxy(methyl)silyl]-N-methylmethanamine
• 化学式: C₇H₁₉NO₂Si
• 分子量: 177.319
• InChiKey: FGLGEKSVYNGSGA-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.89
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  30.5
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为反应物：
  描述：

  2-氯-5-氯甲基噻吩 、 N-methyl-N-[methyl(diethoxy)silylmethyl]amine 在 三乙胺 作用下， 以45%的产率得到1-(5-chlorothiophen-2-yl)-N-[[diethoxy(methyl)silyl]methyl]-N-methylmethanamine
  参考文献：
  名称：

  N-(2-Thenyl)derivatives of aminoalkyltriethoxysilanes,-silatranes and 2,2-dimethyl-1,3-dioxa-6-aza-silacyclooctane

  摘要：

  The reactions of aminoalkylethoxysilanes and 2,2-dimethyl-1,3-dioxa-6-aza-2-silacyclooctane with 2-(chlormethyl)thiophene and its 5-chloroderivative lead to the corresponding N-(2-thenyl) derivatives. The N-methyl-N-(2-thenyl)aminomethyltriethoxysilane and 5-chlorothyenyl derivative formed are converted by triethanolamine into silatranes.

  DOI：

  10.1007/bf00702157

文献信息

• (N-methyl-N-alkoxymethylaminomethyl)dialkoxysilanes and bis[N-methyl-N-(dialkoxysilylmethyl)amino]methanes
  作者：N. F. Lazareva、V. P. Baryshok、M. G. Voronkov

  DOI：10.1007/bf00702156

  日期：1995.2

  Abstract(N-methyl-N-alkoxymethylaminomethyl)-dialkoxysilanes and bis[N-methyl-N-(dialkoxymethyl)amino]methanes were first obtained by the interaction of (N-methylaminomethyl) dialkoxy-R-silanes with chloromethyl alkyl ethers in yields of 40–67% and 10–25 %, respectively.

  摘要 (N​​-甲基-N-烷氧基甲基氨基甲基)-二烷氧基硅烷和双[N-甲基-N-(二烷氧基甲基)氨基]甲烷是首先通过(N-甲基氨基甲基)二烷氧基-R-硅烷与氯甲基烷基醚的相互作用获得的。分别为 40-67% 和 10-25%。
• Lasarewa N. F., Baryshok W. P., Woronkow M. G., Isw. AN. Ser. khim, (1995) N 2, S 382-383
  作者：Lasarewa N. F., Baryshok W. P., Woronkow M. G.

  DOI：——

  日期：——
• Woronkow M. G., Lasarewa N. F., Efremowa G. G., Baryshok W. P., Isw. AN. Ser. khim, (1995) N 2, S 384-386
  作者：Woronkow M. G., Lasarewa N. F., Efremowa G. G., Baryshok W. P.

  DOI：——

  日期：——
• N-(2-Thenyl)derivatives of aminoalkyltriethoxysilanes,-silatranes and 2,2-dimethyl-1,3-dioxa-6-aza-silacyclooctane
  作者：M. G. Voronkov、N. F. Lazareva、G. G. Efremova、V. P. Baryshok

  DOI：10.1007/bf00702157

  日期：1995.2

  The reactions of aminoalkylethoxysilanes and 2,2-dimethyl-1,3-dioxa-6-aza-2-silacyclooctane with 2-(chlormethyl)thiophene and its 5-chloroderivative lead to the corresponding N-(2-thenyl) derivatives. The N-methyl-N-(2-thenyl)aminomethyltriethoxysilane and 5-chlorothyenyl derivative formed are converted by triethanolamine into silatranes.