3,3'-dichloro-4,4'-azobenzenedicarboxylic acid

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 3,3'-dichloro-4,4'-azobenzenedicarboxylic acid
• 化学式: C₁₄H₈Cl₂N₂O₄
• 分子量: 339.135
• InChiKey: WQWVCZLDVCFVFX-ISLYRVAYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  4.81
• 重原子数：
  22.0
• 可旋转键数：
  4.0
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  99.32
• 氢给体数：
  2.0
• 氢受体数：
  4.0

反应信息

• 作为产物：
  描述：

  葡萄糖 、 2-氯苯甲酸 在 盐酸 作用下， 以 水 为溶剂， 生成 3,3'-dichloro-4,4'-azobenzenedicarboxylic acid
  参考文献：
  名称：

  USE OF A POROUS CRYSTALLINE HYBRID SOLID AS A NITROGEN OXIDE REDUCTION CATALYST AND DEVICES

  摘要：

  本发明涉及将由金属有机骨架（MOF）组成且具有以下式（I）的单元的固体用作氮氧化物催化剂。本发明还涉及用于实现所述用途的设备。所涉氮氧化物是一氧化氮和二氧化氮，统称为NOx。本发明的MOF固体有利地能够从液体或气态流出物中去除氮氧化物，例如从水中、从车辆、工厂、车间、实验室、储存产品、城市排气口等的废气中，无需还原剂且在低温下。脱氮催化是我们社会的一个重要问题。本发明可用于减少甚至避免由人类活动产生的有毒NOx气体对公共健康的影响。

  公开号：

  US20120129684A1

文献信息

• ORGANIC/INORGANIC HYBRID NANOPARTICULATES MADE FROM IRON CARBOXYLATES
  申请人：Horcajada-Cortes Patricia

  公开号：US20100209354A1

  公开（公告）日：2010-08-19

  The invention relates to nanoparticles made from organometallic hybrid materials made from iron carboxylates, used for example as contrast agents. The particles can also be used for the encapsulation and vectoring of molecules of interest such as active3 pharmaceutical agents, cosmetically interesting compounds and markers. Apart from the intrinsic properties thereof for imaging, said nanoparticles give good results in terms of capacity for loading with medicaments and in biocompatibility.

  该发明涉及由铁羧酸盐制成的有机金属混合材料制成的纳米颗粒，例如用作对比剂。这些颗粒还可用于封装和导向感兴趣的分子，如活性药物、具有化妆品特性的化合物和标记物。除了其成像的固有特性外，这些纳米颗粒在药物载荷能力和生物相容性方面也表现出良好的结果。
• REDUCIBLE POROUS CRYSTALLINE HYBRID SOLID FOR THE SEPARATION OF MIXTURES OF MOLECULES HAVING DIFFERENT DEGREES AND/OR A DIFFERENT NUMBER OF UNSATURATIONS
  申请人：Serre Christian

  公开号：US20110172412A1

  公开（公告）日：2011-07-14

  The present invention relates to reducible porous crystalline solids, constituted of a metal-organic framework (MOF), for the separation of mixtures of molecules having different unsaturation degrees and/or a different number of unsaturations with a selectivity that can be adjusted by controlling the reduction of the MOF. The MOF solids of the present invention, after reduction, have a strong affinity for molecules containing at least one unsaturation. They can be used in various separation processes, especially those relating to hydrocarbons.

  本发明涉及可还原的多孔晶体固体，由金属有机框架（MOF）构成，用于分离具有不同不饱和度和/或不同不饱和度数量的分子混合物，并且可以通过控制MOF的还原来调节选择性。本发明的MOF固体在还原后对至少含有一个不饱和度的分子具有很强的亲和力。它们可以用于各种分离过程，特别是与烃有关的过程。
• SOLID INORGANIC/ORGANIC HYBRID WITH MODIFIED SURFACE
  申请人：Horcajada-Cortes Patricia

  公开号：US20100226991A1

  公开（公告）日：2010-09-09

  The invention relates to solid organometallic hybrids with modified surface. Said solid may be used for example for the encapsulation and vectoring of molecules of interest such as active pharmaceutical agents, compounds of interest in cosmetics and markers, for example, contrast agents. Said solids show good results in terms of loading capacity in medicament agents and in biocompatibility.

  该发明涉及具有改性表面的固体有机金属杂化物。所述固体可以用于例如封装和载体化感兴趣的分子，如活性药物剂、化妆品中感兴趣的化合物和标记物，例如对比剂。所述固体在药物剂的装载能力和生物相容性方面表现出良好的结果。
• POROUS CRYSTALLINE HYBRID SOLID FOR ADSORBING AND RELEASING GAS OF BIOLOGICAL INTEREST
  申请人：Morris Russel

  公开号：US20110052650A1

  公开（公告）日：2011-03-03

  The invention relates to solids made of a porous crystalline metal-organic framework (MOF) loaded with at least one gas of biological interest, and to a method for preparing the same. The MOF solids of the present invention are capable of adsorbing and releasing in a controlled manner gases having a biological interest. They can be used in the pharmaceutical field and/or for applications in the cosmetic field. They can also be used in the food industry.

  该发明涉及由多孔结晶金属有机框架（MOF）制成的固体，该固体载有至少一种具有生物学兴趣的气体，并涉及制备该固体的方法。本发明的MOF固体能够以受控方式吸附和释放具有生物学兴趣的气体。它们可以在制药领域和/或化妆品领域应用。它们也可以在食品工业中使用。
• ORGANIC-INORGANIC HYBRID SOLID HAVING A MODIFIED OUTER SURFACE
  申请人：CENTRE NATIONAL DE LA RECHERCHE SCIENTIFIQUE-CNRS

  公开号：US20150150981A1

  公开（公告）日：2015-06-04

  The present invention concerns metal-organic hybrid solids having a modified outer surface. These solids can be used, for example, for the storage and vectoring of molecules of interest such as pharmaceutically active ingredients, compounds of interest in cosmetics and markers, for example contrast agents. These solids have good results in terms of active drug loading capacities, biocompatibility, stability and controlling the release of the active ingredients encapsulated.

  本发明涉及具有改性外表面的金属-有机混合固体。这些固体可以用于存储和载体化感兴趣的分子，例如药用活性成分、化妆品中感兴趣的化合物和标记物，例如对比剂。这些固体在活性药物装载能力、生物相容性、稳定性和控制封装的活性成分释放方面取得了良好的结果。