四丁基溴化锑(V) | 45212-19-9

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 四丁基溴化锑(V)
• 英文名称: tetra-n-butylantimony bromide
• 英文别名: Tetrabutylstibanium;bromide；tetrabutylstibanium;bromide
• CAS: 45212-19-9
• 化学式: C₁₆H₃₆BrSb
• 分子量: 430.116
• InChiKey: JVFNASPYONXEIE-UHFFFAOYSA-M

物化性质

• 密度：
  1.34 g/mL at 25 °C(lit.)
• 闪点：
  110 °C
• 稳定性/保质期：
  遵照规定使用和储存，则不会分解。

计算性质

• 辛醇/水分配系数(LogP)：
  7.48
• 重原子数：
  18
• 可旋转键数：
  12
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

安全信息

• 危险品标志：
  Xn,N
• 安全说明：
  S61
• 危险类别码：
  R20/22,R51/53
• 危险品运输编号：
  UN 3077 9/PG 3
• 海关编码：
  2931900090

反应信息

• 作为反应物：
  描述：

  铋试剂II 、 四丁基溴化锑(V) 以 苯 为溶剂， 以83%的产率得到[(n-Bu)4Sb(2,5-dimercapto-4-phenyl-1,3,4-thiodiazole(-1H))]
  参考文献：
  名称：

  Syntheses, characterizations and crystal structures of new organoantimony(V) complexes with heterocyclic (S,N) ligand

  摘要：

  Eight new organoantimony(V) complexes with 1-phenyl-H-1-tetrazole-5-thiol [(LH)-H-1] and 2,5-dimercapto-4-phenyl-1,3,4-thiodiazole [(LH)-H-2] of the type RnSbL5-n(L=L-1: n=4, R=n-Bu 1, Ph 2, n=3, R=Me 3, Ph 4; L=L-2: n=4, R=n-Bu 5, Ph 6, n=3, R=Me 7, Ph 8) have been synthesized. All the complexes 1-8 have been characterized by elemental, FT-IR, H-1 and C-13 NMR analyses. Among them complexes 2, 6 and 8 have also been confirmed by X-ray crystallography. The structure analyses show that the antimony atoms in complexes 2 and 6 display a trigonal bipyramid geometry, while it displays a distorted capped trigonal prism in complex 8 with two intramolecular Sb...N weak interactions. Furthermore, the supramolecular structure of 2 has been found to consist of one-dimensional linear molecular chain built up by intermolecular C-H...N weak-hydrogen bonds, while a macrocyclic dimer has been found in complex 6 linked by intermolecular C-H...S weak hydrogen bonds with head-to-tail arrangement. Interestingly, one-dimensional helical chain is recognized in complex 8, which is connected by intermolecular C-H...S weak hydrogen bonds. (c) 2006 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2006.01.049

文献信息

• Syntheses, characterizations and crystal structures of new organoantimony(V) complexes with heterocyclic (S,N) ligand
  作者：Chunlin Ma、Qingfu Zhang、Jiafeng Sun、Rufen Zhang

  DOI：10.1016/j.jorganchem.2006.01.049

  日期：2006.5

  Eight new organoantimony(V) complexes with 1-phenyl-H-1-tetrazole-5-thiol [(LH)-H-1] and 2,5-dimercapto-4-phenyl-1,3,4-thiodiazole [(LH)-H-2] of the type RnSbL5-n(L=L-1: n=4, R=n-Bu 1, Ph 2, n=3, R=Me 3, Ph 4; L=L-2: n=4, R=n-Bu 5, Ph 6, n=3, R=Me 7, Ph 8) have been synthesized. All the complexes 1-8 have been characterized by elemental, FT-IR, H-1 and C-13 NMR analyses. Among them complexes 2, 6 and 8 have also been confirmed by X-ray crystallography. The structure analyses show that the antimony atoms in complexes 2 and 6 display a trigonal bipyramid geometry, while it displays a distorted capped trigonal prism in complex 8 with two intramolecular Sb...N weak interactions. Furthermore, the supramolecular structure of 2 has been found to consist of one-dimensional linear molecular chain built up by intermolecular C-H...N weak-hydrogen bonds, while a macrocyclic dimer has been found in complex 6 linked by intermolecular C-H...S weak hydrogen bonds with head-to-tail arrangement. Interestingly, one-dimensional helical chain is recognized in complex 8, which is connected by intermolecular C-H...S weak hydrogen bonds. (c) 2006 Elsevier B.V. All rights reserved.