Amino-tri(tert.-butyl)phosphonium

• 分子结构分类: 有机化合物 - 有机磷化合物
• 英文名称: Amino-tri(tert.-butyl)phosphonium
• 英文别名: Amino(tritert-butyl)phosphanium;chloride
• 化学式: C₁₂H₂₉NP*Cl
• 分子量: 253.796
• InChiKey: XESYSKJARUWZEV-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  1.28
• 重原子数：
  15
• 可旋转键数：
  3
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  26
• 氢给体数：
  1
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  Amino-tri(tert.-butyl)phosphonium 在 potassium amide 作用下， 以 氨 为溶剂， 生成 tri-tert-butylphosphoranimine
  参考文献：
  名称：

  Ross,B.; Reetz,K.-P., Chemische Berichte, 1979, vol. 112, p. 1756 - 1762

  摘要：

  DOI：
• 作为产物：
  描述：

  三叔丁基膦 以 乙醚 为溶剂， 生成 Amino-tri(tert.-butyl)phosphonium
  参考文献：
  名称：

  Ross,B.; Reetz,K.-P., Chemische Berichte, 1979, vol. 112, p. 1756 - 1762

  摘要：

  DOI：

文献信息

• Process For The Preparation Of A Metal-Organic Compound Comprising At Least One Imine Ligand
  申请人：Ijpeij Edwin

  公开号：US20070219376A1

  公开（公告）日：2007-09-20

  The invention relates to a process for the preparation of a metal-organic compound, comprising at least one imine ligand, characterized in that an imine ligand according to formula I or the HA adduct thereof, wherein HA represents an acid, of which H represents its proton and A its conjugate base, is contacted with a metal-organic reagent of formula 2 In the presence of at least 1, respectively at least 2 equivalents of a base, with Y═N—R   as formula 1, wherein Y is selected from a substituted carbon, nitrogen, or phosphorous atom and R represents a substituent, and with M V (L 1 ) k (L 2 ) l (L 3 ) m (L 4 ) n X   as formula 2, wherein: M represents a group 4 or group 5 metal ion V represents the valency of the metal ion, being 3, 4 or 5 L 1 , L 2 , L 3 , and L 4 represent a ligand or a group 17 halogen atom on M and may be equal or different X represents a group 17 halogen atom, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+1=V. The invention further relates to a process for the preparation of a polyolefin in the presence of the compound prepared according to the process of the invention.

  本发明涉及一种制备至少含有一种亚胺配体的金属有机化合物的方法，其特征在于将式I或其HA加合物中的亚胺配体与式2的金属有机试剂接触，在至少1个或2个当量的碱存在下进行，其中HA代表酸，其中H代表其质子，A代表其共轭碱基，式1中，Y═N—R，其中Y选自取代的碳、氮或磷原子，R代表取代基，式2中，MV（L1）k（L2）l（L3）m（L4）nX，其中：M代表4族或5族金属离子，V代表金属离子的价态为3、4或5，L1、L2、L3和L4代表M上的配体或17族卤素原子，可以相同也可以不同，X代表17族卤素原子，k、l、m、n=0、1、2、3、4，其中k+l+m+n+1=V。本发明还涉及一种在本发明方法制备的化合物存在下制备聚烯烃的方法。
• Process for the Preparation of a Metal-Organic Compound Comprising at Least One Imine Ligand
  申请人：Ijpeij Edwin

  公开号：US20080045719A1

  公开（公告）日：2008-02-21

  The invention relates to a process for the preparation of a metal-organic compound, comprising at least one phosphinimine ligand, characterized in that the HA adduct of a phosphinimine ligand according to formula (1) is contacted with a metal-organic reagent of formula (2) in the presence of at least 2 equivalents of a base, wherein HA represents an acid, of which H represents its proton and A its conjugate base, with Y═N—H as formula (1), and M v (L 1 ) k (L 2 ) 1 (L 3 ) m (L 4 ) n X as formula (2), and wherein Y is a substituted phosphorous atom, and M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5 L 1 , L 2 , L 3 , and L 4 represent a ligand or a group 17 halogen atom on M and may be equal or different, k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+l=V, and X represents a group 17 halogen atom. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.

  本发明涉及一种制备至少含有一个膦亚胺配体的金属有机化合物的方法，其特征在于将公式（1）的膦亚胺配体的HA加合物与公式（2）的金属有机试剂在至少2当量的碱存在下接触，其中HA代表一种酸，H代表其质子，A代表其共轭碱基，Y═N—H为公式（1），Mv(L1)k(L2)1(L3)m(L4)nX为公式（2)，其中Y为取代的磷原子，M代表4族或5族金属离子，V代表金属离子的价，为3、4或5，L1、L2、L3和L4代表M上的配体或17族卤素原子，可以相同或不同，k、l、m、n=0、1、2、3、4，其中k+l+m+n+l=V，X代表17族卤素原子。本发明还涉及一种通过制备本发明方法的金属有机化合物来制备聚烯烃的方法，其中碱是与烯烃聚合兼容的碱，所述金属有机化合物在聚合反应器内或之前的任何地方被活化。
• Process for the preparation of a metalloorganic compound comprising at least one imine ligand
  申请人：DSM IP Assets B.V.

  公开号：EP1506974A1

  公开（公告）日：2005-02-16

  The invention relates to a process for the preparation of a metal-organic compound, comprising at least one imine ligand, characterized in that an imine ligand according to formula 1 or the HA adduct thereof, wherein HA represents an acid, of which H represents its proton and A its conjugate base, is contacted with a metal-organic reagent of formula 2 in the presence of at least 1, respectively at least 2 equivalents of a base, with         Y=N-R     as formula 1, wherein Y is selected from a substituted carbon, nitrogen, or phosphorous atom and R represents a substituent, and with         Mv(L1)k(L2)I(L3)m(L4)nX     as formula 2, wherein: M represents a group 4 or group 5 metal ion V represents the valency of the metal ion, being 3, 4 or 5 L1, L2, L3, and L4 represent a ligand or a group 17 halogen atom on M and may be equal or different X represents a group 17 halogen atom, k, l, m, n = 0, 1, 2, 3, 4 with k+l+m+n+1=V. The invention further relates to a process for the preparation of a polyolefin in the presence of the compound prepared according to the process of the invention.

  本发明涉及一种包含至少一种亚胺配体的金属有机化合物的制备方法，其特征在于：在至少 1 个（分别为至少 2 个当量）碱的存在下，将根据式 1 的亚胺配体或其 HA 加合物（其中 HA 代表酸，H 代表其质子，A 代表其共轭碱）与式 2 的金属有机试剂接触，条件为 Y=N-R 如式 1、 其中 Y 选自取代的碳原子、氮原子或磷原子，R 代表取代基，以及 Mv(L1)k(L2)I(L3)m(L4)nX 如式 2、 其中 M 代表 4 族或 5 族金属离子 V 代表 3、4 或 5 族金属离子的化合价 L1、L2、L3 和 L4 代表 M 上的配体或第 17 族卤原子，可以相同或不同 X 代表第 17 族卤原子、 k、l、m、n = 0、1、2、3、4，k+l+m+n+1=V。 本发明还涉及一种在根据本发明工艺制备的化合物存在下制备聚烯烃的工艺。
• Improved method of preparing a hydrocarbylated metal-organic compound
  申请人：DSM IP Assets B.V.

  公开号：EP1535936A1

  公开（公告）日：2005-06-01

  The invention relates to a process for the preparation of a hydrocarbylated metal organic compound, comprising a hydrocarbyl group, a spectator ligand and optionally a ligand, by contacting a metal-organic reagent with a spectator ligand in the presence of at least 2 equivalents of a hydrocarbylating agent. The invention further relates to a hydrocarbylated metal organic compound according to the following formula containing a spectator ligand S equal to (Ar-Z-)sY(-Z-DR'n)q, wherein Y represents the an anionic moiety of S bonded to M of the metal-organic compound, Z an optional bridging group between the Y moiety and the DR'n and/or Ar group, D an electron-donating hetero atom chosen from group 15 or 16, R' an optional substituent, Ar an electron-donating aryl group, n the number of R' groups bonded to D, q and s integers with q + s ≥ 1, wherein Y is an imine radical, or wherein the electron donating hetero atom containing group DR'-n is a ketimide, phosphinimide, guanidine, or iminoimidazoline, or a combination thereof.

  本发明涉及一种制备烃基化金属有机化合物的工艺，该化合物包括一个烃基、一个旁配体和任选的一个配体，制备方法是在至少2当量烃基化剂存在下，将金属有机试剂与旁配体接触。本发明还涉及一种符合下式的烃基化金属有机化合物 其中 Y 代表与金属有机化合物 M 键合的 S 的阴离子基团，Z 代表 Y 基团与 DR'n 和/或 Ar 基团之间任选的桥基，D 代表选自 15 或 16 族的电子捐赠杂原子，R' 代表任选的取代基、Ar 一个电子捐赠芳基，n 与 D 键合的 R'基团数，q 和 s 是 q + s ≥ 1 的整数，其中 Y 是亚胺基，或其中含有电子捐赠杂原子的基团 DR'-n 是酮亚胺、膦亚胺、胍或亚胺咪唑啉，或它们的组合。
• Process for the preparation of a metal-organic compound comprising at least one imine ligand
  申请人：Ijpeij Gerard Edwin

  公开号：US20060247438A1

  公开（公告）日：2006-11-02

  The invention relates to a process for the preparation of a metalorganic compound, comprising at least one imine ligand, characterized in that an imine ligand according to formula 1, or the HA adduct thereof, wherein HA represents an acid, of which H represents its proton and A its conjugate base, is contacted with a metal-organic reagent of formula 2 in the presence of at least 1, respectively 2 equivalents of an inorganic or metal-organic base, wherein Y═N—R (formula 1), Y is selected from a substituted carbon, nitrogen or phosphorous atom, R represents a proton, a protic or an aprotic substituent, and the metal organic compound is: M V (L 1 )k(L 2 )l(L 3 ) m (L 4 ) n X (formula 2) wherein: M represents a group 4 or group 5 metal ion, V represents the valency of the metal ion, being 3, 4 or 5, L 1 , L 2 , L 3 , and L 4 represent ligands on M and may be equal or different, X represents a group 17 halogen atom, and k, l, m, n=0, 1, 2, 3, 4 with k+l+m+n+l=V. The invention further relates to a process for the preparation of a polyolefin by making a metal-organic compound according to the process of the invention, wherein the base is an olefin polymerisation compatible base, which metal-organic compound is activated anywhere in, or before a polymerisation reactor.

  本发明涉及一种制备金属有机化合物的工艺，该化合物包含至少一种亚胺配体，其特征在于，根据式 1 的亚胺配体或其 HA 加合物，其中 HA 代表一种酸，其中 H 代表其质子，A 代表其共轭碱、在至少 1 个或 2 个当量的无机碱或金属有机碱存在下，与式 2 的金属有机试剂接触，其中 Y═N-R (式 1)，Y 选自取代的碳原子、氮原子或磷原子，R 代表质子、质子或烷基取代基，金属有机化合物为：M V (L 1 ）k（L 2 )l(L 3 ) m (L 4 ) n X（式 2） 其中M 代表第 4 组或第 5 组金属离子，V 代表金属离子的化合价（3、4 或 5），L 1 , L 2 , L 3 和 L 4 代表 M 上的配位体，可以相同或不同，X 代表 17 族卤原子，k、l、m、n=0、1、2、3、4，k+l+m+n+l=V。本发明进一步涉及一种根据本发明工艺制备金属有机化合物制备聚烯烃的工艺，其中碱为烯烃聚合相容碱，该金属有机化合物在聚合反应器内或聚合反应器前的任何地方活化。