1-乙基-3-甲基-1H-咪唑-3-鎓二丁基磷酸酯 | 869858-84-4

• 物质功能分类: 医药中间体 - 原料药中间体
• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 中文名称: 1-乙基-3-甲基-1H-咪唑-3-鎓二丁基磷酸酯
• 中文别名: 1-乙基-3-甲基咪唑二丁基磷酸盐
• 英文名称: 1-ethyl-3-methylimidazolium dibutyl phosphate
• 英文别名: dibutyl phosphate;1-ethyl-3-methylimidazol-3-ium
• CAS: 869858-84-4
• 化学式: C₆H₁₁N₂*C₈H₁₈O₄P
• 分子量: 320.369
• InChiKey: IDXRTKFKTIRDST-UHFFFAOYSA-M

计算性质

• 辛醇/水分配系数(LogP)：
  2.42
• 重原子数：
  21
• 可旋转键数：
  9
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.79
• 拓扑面积：
  67.4
• 氢给体数：
  0
• 氢受体数：
  4

安全信息

• 危险品标志：
  Xi
• 危险类别码：
  R36/37/38
• WGK Germany：
  3
• 安全说明：
  S26

反应信息

• 作为反应物：
  描述：

  uranyl nirate hexahydrate 、 1-乙基-3-甲基-1H-咪唑-3-鎓二丁基磷酸酯 以 水 为溶剂， 生成
  参考文献：
  名称：

  探索有机官能团在磷酸双氧铀材料离子热合成中的作用

  摘要：

  在使用离子液体 1-ethyl-3-methylimidazolium 二甲基磷酸盐和 1-ethyl-3-methylimidazolium 二丁基磷酸盐通过离子热合成生长单晶后，对四种新的杂化有机-无机磷酸双氧铀化合物进行了结构表征。这里介绍的三种新晶体结构将磷酸二甲酯或单甲基磷酸酯配体结合到结构单元中，形成一个链基化合物和两个片基化合物。其中一个结构利用磷酸二丁酯形成先前报道的铀酰化合物，这是一种在空间群P 2 1 / c中结晶的结构多晶型物，与先前报道的P-1 结构。将结构和拓扑关系与磷酸双氧铀矿物以及先前报道的有机磷酸盐化合物的结构和拓扑关系进行了比较。讨论了有机物对磷酸盐阴离子影响铀酰配位和稳定晶体结构的作用。

  DOI：

  10.1002/zaac.202200162

文献信息

• [EN] ESLICARBAZEPINE ACETATE AND ITS POLYMORPHS<br/>[FR] ACÉTATE D'ESLICARBAZÉPINE ET SES POLYMORPHES
  申请人：REDDYS LAB LTD DR

  公开号：WO2011091131A2

  公开（公告）日：2011-07-28

  Processes for the preparation of eslicarbazepine acetate and intermediates thereof. Also provided are polymorphic forms of eslicarbazepine acetate and methods for their preparation.

  制备艾司卡巴嗪乙酸酯及其中间体的过程。还提供了艾司卡巴嗪乙酸酯的多态形式及其制备方法。
• SYNTHETIC LUBRICANT
  申请人：Honda You

  公开号：US20130053287A1

  公开（公告）日：2013-02-28

  Provided is a lubricating oil additive which is able to impart friction adjusting performance and rust preventing performance which are essential for practical use of a lubricant composed of an ionic liquid, and is dissolved or dispersed in the ionic liquid even when blended with the ionic liquid, and thus, does not inhibit performances as a base oil of the ionic liquid. The present invention relates to a synthetic lubricant including a fluorine atom-containing ionic liquid (A) as a main component, wherein the synthetic lubricant contains an imidazolium phosphate ester salt (B).

  提供了一种润滑油添加剂，能够赋予离子液体润滑剂所必需的摩擦调节性能和防锈性能，并且即使与离子液体混合，也能够溶解或分散在离子液体中，因此不会影响离子液体作为基础油的性能。本发明涉及一种合成润滑剂，包括一种含氟原子的离子液体(A)作为主要成分，其中合成润滑剂包含一种咪唑磷酸酯盐(B)。
• SILICONE ADHESIVE COMPOSITION AND ADHESIVE TAPE
  申请人：Shin-Etsu Chemical Co., Ltd.

  公开号：EP3290489A1

  公开（公告）日：2018-03-07

  One of the purposes of the present invention is to provide a silicone adhesive composition which provides an adhesive layer having an excellent antistatic property and which has an excellent bond strength to a tape substrate and, therefore, when an adhesive tape or film having the adhesive layer is peeled from a tape-stuck body, less residual adhesive occurs on the tape-stuck body. The other purpose of the present invention is to provide a silicone adhesive composition which cures well by heating for a short time, particularly for less than 5 minutes, to provide an adhesive layer having an excellent antistatic property. The present invention first provides a silicone adhesive composition comprising (A) an addition reaction-curable silicone, (B1) a compound having at least two unsaturated hydrocarbon groups and two (poly)oxyalkylene residues in one molecule, and (C) an ionic liquid containing no lithium. The present invention secondly provides a silicone adhesive composition comprising (A) an addition reaction-curable silicone, (B) a compound having at least one unsaturated hydrocarbon group and at least one (poly) oxyalkylene residue in one molecule, (C) an ionic liquid containg no lithium and (e) a platinum group metal catalyst which is not a complex with a compound having an unsaturated hydrocarbon bond.

  本发明的目的之一是提供一种硅酮粘合剂组合物，该组合物提供的粘合剂层具有极佳的抗静电性能，并且与胶带基材具有极佳的粘合强度，因此，当具有该粘合剂层的胶带或薄膜从胶带粘贴体上剥离时，胶带粘贴体上的残留粘合剂较少。本发明的另一个目的是提供一种硅酮粘合剂组合物，该组合物通过短时间，特别是少于 5 分钟的加热就能很好地固化，从而提供具有优异抗静电性能的粘合层。本发明首先提供了一种有机硅粘合剂组合物，该组合物包括（A）加成反应固化的有机硅，（B1）在一个分子中具有至少两个不饱和烃基和两个（聚）氧烷基残基的化合物，以及（C）不含锂的离子液体。本发明其次提供了一种有机硅粘合剂组合物，该组合物包含 (A) 加成反应固化有机硅，(B) 在一个分子中具有至少一个不饱和烃基和至少一个（聚）氧烷基残基的化合物，(C) 不含锂的离子液体，以及 (e) 不与具有不饱和烃键的化合物形成络合物的铂族金属催化剂。
• Composition for the immediate stopping of a free-radical polymerization
  申请人：BASF SE

  公开号：US10221255B2

  公开（公告）日：2019-03-05

  A composition for the immediate stopping of a free-radical polymerization comprises a) an inhibitor for the free-radical polymerization selected from among phenothiazines, b) an aprotic solvent and c) an ionic liquid. It serves to stabilize free-radically polymerizable monomers against free-radical polymerization. For the immediate stopping of free-radical polymerizations, the composition is added to a free-radically polymerizing system.

  一种可立即阻止自由基聚合的组合物包括 a) 一种吩噻嗪类自由基聚合抑制剂；b) 一种烷基溶剂；c) 一种离子液体。其作用是稳定可自由基聚合的单体，防止自由基聚合。为了立即停止自由基聚合，可将该组合物加入自由基聚合体系中。
• Silicone adhesive composition and an adhesive tape
  申请人：SHIN-ETSU CHEMICAL CO., LTD.

  公开号：US10696881B2

  公开（公告）日：2020-06-30

  One of the purposes of the present invention is to provide a silicone adhesive composition which provides an adhesive layer having an excellent antistatic property and which has an excellent strength of bond to a tape substrate and, therefore, when an adhesive tape or film having the adhesive layer is peeled from a tape-stuck body, less residual adhesive occurs on the tape-stuck body. The other purpose of the present invention is to provide a silicone adhesive composition which cures well by heating for a short time, particularly for less than 5 minutes, to provide an adhesive layer having an excellent antistatic property. The present invention first provides a silicone adhesive composition comprising (A) an addition reaction-curable silicone, (B1) a compound having at least two unsaturated hydrocarbon groups and two (poly)oxyalkylene residues in one molecule, and (C) an ionic liquid containing no lithium. The present invention secondly provides a silicone adhesive composition comprising (A) an addition reaction-curable silicone, (B) a compound having at least one unsaturated hydrocarbon group and at least one (poly)oxyalkylene residue in one molecule, (C) an ionic liquid containing no lithium and (e) a platinum group metal catalyst which is not a complex with a compound having an unsaturated hydrocarbon bond.

  本发明的目的之一是提供一种硅酮粘合剂组合物，该组合物提供的粘合剂层具有极佳的抗静电性能，并且与胶带基材具有极佳的粘合强度，因此，当具有该粘合剂层的胶带或薄膜从胶带粘合体上剥离时，胶带粘合体上的残留粘合剂较少。本发明的另一个目的是提供一种硅酮粘合剂组合物，该组合物通过短时间，特别是少于 5 分钟的加热就能很好地固化，从而提供具有优异抗静电性能的粘合层。本发明首先提供了一种有机硅粘合剂组合物，该组合物包括（A）加成反应固化的有机硅，（B1）在一个分子中具有至少两个不饱和烃基和两个（聚）氧烷基残基的化合物，以及（C）不含锂的离子液体。本发明其次提供了一种有机硅粘合剂组合物，该组合物包含 (A) 加成反应固化有机硅，(B) 在一个分子中具有至少一个不饱和烃基和至少一个（聚）氧烷基残基的化合物，(C) 不含锂的离子液体，以及 (e) 不是与具有不饱和烃键的化合物的络合物的铂族金属催化剂。