氯甲基二甲基己基硅烷 | 73013-40-8

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 中文名称: 氯甲基二甲基己基硅烷
• 英文名称: chloromethyldimethylhexylsilane
• 英文别名: Dimethyl-chlormethyl-hexylsilan；Chloromethyl-hexyl-dimethylsilane；chloromethyl-hexyl-dimethylsilane
• CAS: 73013-40-8
• 化学式: C₉H₂₁ClSi
• 分子量: 192.804
• InChiKey: CKSRYOVEFQHASJ-UHFFFAOYSA-N

物化性质

• 沸点：
  213.6±13.0 °C(predicted)
• 密度：
  0.859±0.06 g/cm3(Temp: 20 °C; Press: 760 Torr)(predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  4.05
• 重原子数：
  11
• 可旋转键数：
  6
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  氯甲基二甲基己基硅烷 在 氢氧化钾 作用下， 生成 3-(Hexyl-dimethyl-silanyl)-propionic acid
  参考文献：
  名称：

  Synthesis and investigation of the dipole moments of ?-(n-alkyldimethylsilyl)propionic acids

  摘要：

  DOI：

  10.1007/bf00947552
• 作为产物：
  描述：

  氯甲基二甲基氯硅烷 、 magnesium,hexane,chloride 以 乙醚 为溶剂， 生成 氯甲基二甲基己基硅烷
  参考文献：
  名称：

  Synthesis and investigation of the dipole moments of ?-(n-alkyldimethylsilyl)propionic acids

  摘要：

  DOI：

  10.1007/bf00947552

文献信息

• Regioselective Synthesis of 1,4-Di(organo)[60]fullerenes through DMF-assisted Monoaddition of Silylmethyl Grignard Reagents and Subsequent Alkylation Reaction
  作者：Yutaka Matsuo、Akihiko Iwashita、Yoko Abe、Chang-Zhi Li、Keiko Matsuo、Masahiko Hashiguchi、Eiichi Nakamura

  DOI：10.1021/ja8041299

  日期：2008.11.19

  Monoaddition of Grignard reagents, in particular tri(organo)silylmethyl magnesium chlorides, to [60]fullerene took place smoothly in the presence of dimethylformamideto produce (organo)(hydro)[60]fullerenes, (C60RH)-H-1, in good yield (up to 93% isolated yield). The hydrofullerene was then deprotonated to generate the corresponding anion, C60R-, which was then alkylated to obtain 58 pi-electron di(organo)[60]fullerenes, (C60RR2)-R-1, in good to high yield (up to 93% overall yield). The two-step methodology provides a wide variety of 1,4-di(organo)[60] fullerenes bearing the same or different organic addends on the [60] fullerene core. By changing the addends, one can control the chemical and physical properties of the compounds at the molecular and bulk levels.
• Synthesis and investigation of the dipole moments of ?-(n-alkyldimethylsilyl)propionic acids
  作者：D. N. Andreev、G. S. Smirnova、L. L. Burshtein、T. P. Stepanova、V. P. Malinovskaya

  DOI：10.1007/bf00947552

  日期：1979.10