4-(4-methylamino-phenylazo)-benzenesulfonic acid | 5713-92-8

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 4-(4-methylamino-phenylazo)-benzenesulfonic acid
• 英文别名: 4-(4-Methylamino-phenylazo)-benzolsulfonsaeure；Monomethylorange；(Benzol-sulfonsaeure-(1))-(4 azo 4)-(N-methyl-anilin)；4'-Methylamino-azobenzol-sulfonsaeure-(4)；4-(Methylamino)-azobenzol-4'-sulfonsaeure；Benzenesulfonic acid, 4-[2-[4-(methylamino)phenyl]diazenyl]-；4-[[4-(methylamino)phenyl]diazenyl]benzenesulfonic acid
• CAS: 5713-92-8
• 化学式: C₁₃H₁₃N₃O₃S
• 分子量: 291.331
• InChiKey: ZAFYLUMZTQWWOU-UHFFFAOYSA-N

物化性质

• 密度：
  1.35±0.1 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.4
• 重原子数：
  20
• 可旋转键数：
  4
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.08
• 拓扑面积：
  99.5
• 氢给体数：
  2
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 4-(4-methylamino-phenylazo)-benzenesulfonic acid 在 乙醚 作用下， 生成 4-(4-methylamino-phenylazo)-benzenesulfonic acid methyl ester
  参考文献：
  名称：

  Hantzsch, Chemische Berichte, 1929, vol. 62, p. 967,968

  摘要：

  DOI：
• 作为产物：
  描述：

  methyl orange 以 水 为溶剂， 生成 4-(4-methylamino-phenylazo)-benzenesulfonic acid 、 对氨基偶氮苯基-4-磺酸
  参考文献：
  名称：

  The mechanism of sonophotocatalytic degradation of methyl orange and its products in aqueous solutions

  摘要：

  In this study, it was found that a hybrid technique, sonophotocatalysis, is able to degrade a parent organic pollutant (methyl orange) as well as its by-products. The analysis of products formed during the whole degradation has demonstrated that the pH or the selection of oxidation process (sonolysis/photocatalysis/sonophotocatalysis) is able to control the degradation pathway. It was shown in the by-products analysis that the solution pH can alter the amount of each product generated during the sonophotocatalytic degradation. It was revealed that the different degradation rates of methyl orange and its products result from the solution pH and the nature of the organic products. Furthermore, a comparison of the data obtained from the oxidation processes on the degradation of the reaction intermediates identified the advantages of the combined system. It is concluded that sonophotocatalysis is capable of yielding a more complete and faster mineralization of organic pollutants than the individual processes. However, as in the degradation of the parent compound, the overall mineralization is lower than an additive effect (negative synergistic effect). (C) 2011 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.ultsonch.2011.03.017

文献信息

• 10.1021/jal090832
  作者：Clark, Joanna H.、Dyer, Matthew S.、Palgrave, Robert G.、Ireland, Christopher P.、Darwent, James R.、Claridge, John B.、Rosseinsky, Matthew J.

  DOI：10.1021/jal090832

  日期：——
• Bernthsen; Goske, Chemische Berichte, 1887, vol. 20, p. 933
  作者：Bernthsen、Goske

  DOI：——

  日期：——