1-(trimethylsilyl)-1-propynehexacarbonyldicobalt | 38599-39-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 1-(trimethylsilyl)-1-propynehexacarbonyldicobalt
• 英文别名: 1-(trimethylsilyl)-1-propyne, dicobalt-hexacarbonyl complex；Carbon monoxide;cobalt;trimethyl(prop-1-ynyl)silane
• CAS: 38599-39-2
• 化学式: C₁₂H₁₂Co₂O₆Si
• 分子量: 398.296
• InChiKey: COBUBNDBYWEVCZ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  1.66
• 重原子数：
  21
• 可旋转键数：
  1
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.33
• 拓扑面积：
  6
• 氢给体数：
  0
• 氢受体数：
  6

反应信息

• 作为反应物：
  描述：

  亚甲基环丙烷 、 1-(trimethylsilyl)-1-propynehexacarbonyldicobalt 生成 7-methyl-6-trimethylsilylspiro[2.4]hept-6-en-5-one
  参考文献：
  名称：

  SMIT, W. A.;KIREEV, S. L.;NEFEDOV, O. M.;TARASOV, V. A., TETRAHEDRON LETT., 30,(1989) N0, C. 4021-4024

  摘要：

  DOI：
• 作为产物：
  描述：

  1-(三甲基硅基)丙炔 、 dicobalt octacarbonyl 以 Petroleum ether 为溶剂， 以96%的产率得到1-(trimethylsilyl)-1-propynehexacarbonyldicobalt
  参考文献：
  名称：

  Mild and efficient preparation of alkynepentacarbonyldicobalt complexes containing the chiral (R) -(+) -Glyphos ligand

  摘要：

  A range of diastereomeric alkynepentacarbonyldicobalt complexes containing the (R)-(+)-Glyphos ligand have been prepared in moderate to good yields under standard thermal conditions. Additionally, novel tertiary amine N-oxide mediated reactions have been developed which allow the synthesis of the same range of complexes at room temperature with good selectivity in consistently high yields. Optically pure (R)-(+)-Glyphos containing complexes have been obtained by preparative HPLC separation of the sets of diastereomeric compounds. Finally, the amine N-oxide techniques allow the rapid and clean preparation of alkynepentacarbonyltriphenylphosphinedicobalt complexes in good to high yields at room temperature.

  DOI：

  10.1016/s0022-328x(96)06174-8

文献信息

• Synthesis of Dicarbonyl(η⁴-tricarbonylcobaltacyclopentadiene)cobalt Complexes from Co₂(CO)₈. A General Route to Intermediates in Cobalt Carbonyl Mediated Alkyne Trimerization
  作者：R. John Baxter、Graham R. Knox、Peter L. Pauson、Mark D. Spicer

  DOI：10.1021/om980544y

  日期：1999.1.1

  cobaltacyclopentadiene complexes, derived from cobalt carbonyl and two alkyne molecules and long believed to be intermediates in cyclotrimerization as well as in the formation of the (three-alkyne-derived) “flyover” complexes, can be isolated in selected cases if the mono(alkyne)−Co2(CO)6 complexes are treated at room temperature with just 1 equiv of alkyne in the presence of trimethylamine N-oxide. The complex (PhCCHCMeCMe)Co2(CO)5

  我们已经表明，在某些情况下，可以分离出衍生自羰基钴和两个炔烃分子的钴环戊二烯络合物，人们长期以来认为它们是环三聚化以及（三炔烃衍生的）“立交”络合物形成中的中间体。在三甲胺N-氧化物存在下，仅用1当量的炔在室温下处理单（炔）-Co 2（CO）6络合物。配合物（PhC CHCMe CMe）Co 2（CO）5已通过X射线晶体学表征。
• Methylenecyclopropane in the [2+2+1]-cycloaddition reaction with dicobalt-hexacarbonyl complexes of acetylenes
  作者：S. L. Kireev、V. A. Smit、O. M. Nefedov

  DOI：10.1007/bf00957787

  日期：1989.9
• Bantel, Harald; Powell, Anne K.; Vahrenkamp, Heinrich, Chemische Berichte, 1990, vol. 123, p. 661 - 666
  作者：Bantel, Harald、Powell, Anne K.、Vahrenkamp, Heinrich

  DOI：——

  日期：——
• KIREEV, S. L.;SMIT, V. A.;NEFEDOV, O. M., IZV. AN CCCP. CEP. XIM.,(1989) N, S. 2061-2068
  作者：KIREEV, S. L.、SMIT, V. A.、NEFEDOV, O. M.

  DOI：——

  日期：——