diallyl ethyl phosphate | 2468-70-4

• 分子结构分类: 有机化合物 - 有机酸及其衍生物 - 有机磷酸及其衍生物
• 英文名称: diallyl ethyl phosphate
• 英文别名: phosphoric acid diallyl ester ethyl ester；phosphoric acid ethyl ester-diallyl ester；Phosphorsaeure-aethylester-diallylester；Phosphorsaeure-diallyl-monoaethyl-ester；Ethyl-diallyl-phosphat；Ethyl bis(prop-2-enyl) phosphate
• CAS: 2468-70-4
• 化学式: C₈H₁₅O₄P
• 分子量: 206.178
• InChiKey: IYNXSBVDHZFSBT-UHFFFAOYSA-N

物化性质

• 沸点：
  72 °C(Press: 1-2 Torr)
• 密度：
  1.062±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  1.2
• 重原子数：
  13
• 可旋转键数：
  8
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.5
• 拓扑面积：
  44.8
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  diallyl ethyl phosphate 、 三正丁基氢锡 、 双三苯基磷二氯化钯 生成 ethyl bis(tributylstannyl) phosphate
  参考文献：
  名称：

  ZHANG, H. X.;GUIBE, F.;BALAVOINE, G., TETRAHEDRON LETT., 29,(1988) N 6, 623-626

  摘要：

  DOI：
• 作为产物：
  描述：

  二氯磷酸乙酯 、 烯丙醇 生成 diallyl ethyl phosphate
  参考文献：
  名称：

  Kennedy et al., Journal of Applied Chemistry, 1958, vol. 8, p. 459,462

  摘要：

  DOI：
• 作为试剂：
  描述：

  N-叔丁氧羰基-4-哌啶酮 在 diallyl ethyl phosphate 、 palladium diacetate 、 sodium carbonate 作用下， 以 四氢呋喃 为溶剂， 反应 21.0h， 以84%的产率得到4-氧代-3,4-二氢吡啶-1(2H)-羧酸叔丁酯
  参考文献：
  名称：

  Synthesis of 5-acyl-4-methylene-1,2,3,4-tetrahydropyridines

  摘要：

  DOI：

  10.24820/ark.5550190.p011.532

文献信息

• NON-AQUEOUS ELECTROLYTE FOR LITHIUM-ION BATTERY AND LITHIUM-ION BATTERY
  申请人：Shenzhen Capchem Technology Co., Ltd.

  公开号：EP3547433A1

  公开（公告）日：2019-10-02

  A non-aqueous electrolyte for a lithium-ion battery and a lithium-ion battery. The non-aqueous electrolyte comprises unsaturated phosphate compounds and unsaturated cyclic carboxylic acid anhydride compounds. The unsaturated phosphate compounds have the structure illustrated in structural formula 4; structural formula 4: R13, R11, and R12 are independently selected from hydrocarbon groups having 1-5 carbon atoms respectively, and at least one of R13, R11, and R12 is an unsaturated hydrocarbon group containing double bonds or triple bonds; the unsaturated cyclic carboxylic acid anhydride compounds have the structure illustrated in structural formula 5; structural formula 5: R14 is independently selected from vinylidene having 2-4 carbon atoms or fluoro-substituted vinylidene. By means of the synergistic effect of two compounds, the non-aqueous electrolyte has excellent high-temperature cycling performance and storage performance, and also has lower impedance and good low-temperature performance.

  一种用于锂离子电池的非水电解质和一种锂离子电池。该非水电解质包括不饱和磷酸盐化合物和不饱和环羧酸酐化合物。不饱和磷酸盐化合物具有结构式4所示的结构；结构式4：R13、R11和R12分别独立地选自具有1-5个碳原子的烃基，且R13、R11和R12中至少有一个是含有双键或三键的不饱和烃基；不饱和环状羧酸酐化合物具有结构式5所示的结构；结构式5：R14独立地选自具有2-4个碳原子的亚乙烯基或氟取代亚乙烯基。通过两种化合物的协同作用，非水电解质具有优异的高温循环性能和储存性能，同时还具有较低的阻抗和良好的低温性能。
• NONAQUEOUS ELECTROLYTE SOLUTION AND ELECTRICITY STORAGE DEVICE USING SAME
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3780225A1

  公开（公告）日：2021-02-17

  A nonaqueous electrolytic solution including an electrolyte, a nonaqueous solvent, and a compound represented by Formula (1) below. (in Formula (1), X1 and X2 each independently represent C, S, or P; n1 and n2 each independently represent 1 when X1 and X2 represent C or P and 2 when X1 and X2 represent S; n1 represents 1 or 2; n2 represents 1 or 2; Y1 and Y2 each independently represent a hydrocarbon group that may have a substituent or an -OW group (where W represents a hydrocarbon group that may have a substituent); m1 represents 1 or 2, and m2 represents 1 or 2; and Z represents a hydrocarbon group that may have a substituent, an -SiV3 group (where V represents a hydrocarbon group that may have a substituent), an organic onium, or a metal).

  一种非水电解溶液，包括电解质、非水溶剂和下式 (1) 所代表的化合物。 式（1）中，X1 和 X2 各自独立地代表 C、S 或 P；当 X1 和 X2 代表 C 或 P 时，n1 和 n2 各自独立地代表 1，当 X1 和 X2 代表 S 时，n1 和 n2 各自独立地代表 2；n1 代表 1 或 2；n2 代表 1 或 2；Y1 和 Y2 各自独立地代表可具有取代基的烃基或 -OW 基（其中 W 代表可具有取代基的烃基）；m1 代表 1 或 2，m2 代表 1 或 2；以及 Z 代表可能具有取代基的烃基、-SiV3 基团（其中 V 代表可能具有取代基的烃基）、有机鎓基或金属）。
• NONAQUEOUS ELECTROLYTE SOLUTION AND ENERGY DEVICE USING SAME
  申请人：Mitsubishi Chemical Corporation

  公开号：EP3780227A1

  公开（公告）日：2021-02-17

  A nonaqueous electrolytic solution including a nonaqueous solvent and a compound represented by Formula (1) . (wherein, in Formula (1), R1 to R5 each independently represent a hydrogen atom or an alkyl group that has 1 to 3 carbon atoms and may have a substituent; R6 is an organic group that has 1 to 8 carbon atoms and may have a hetero atom; X is a carbon atom, a sulfur atom, or a phosphorus atom; when X is a carbon atom, 1 = 0, m = 1, and n = 1, when X is a sulfur atom, 1 = 0, m = 2, and n = 1, and when X is a phosphorus atom, 1 = 0, m = 1, and n = 2 or 1 = 1, m = 1, and n = 1; k is an integer of 2 to 4; and Y is a direct bond or a linking group that has 1 to 8 carbon atoms and may have a hetero atom, and when Y is a direct bond, the compound has an X-X bond and k = 2).

  一种非水电解溶液，包括一种非水溶剂和一种由式（1）代表的化合物。 (其中，在式(1)中，R1至R5各自独立地代表氢原子或具有1至3个碳原子并可具有取代基的烷基；R6是具有1至8个碳原子并可具有杂原子的有机基团；X是碳原子、硫原子或磷原子；当 X 为碳原子时，1＝0，m＝1，n＝1；当 X 为硫原子时，1＝0，m＝2，n＝1；当 X 为磷原子时，1＝0，m＝1，n＝2 或 1＝1，m＝1，n＝1；k 是 2 至 4 的整数；Y 是直接键或具有 1 至 8 个碳原子且可能具有杂原子的连接基团，当 Y 是直接键时，化合物具有 X-X 键且 k = 2）。
• Non-aqueous electrolyte for lithium-ion battery and lithium-ion battery
  申请人：SHENZHEN CAPCHEM TECHNOLOGY CO., LTD.

  公开号：US11362370B2

  公开（公告）日：2022-06-14

  A non-aqueous electrolyte for a lithium-ion battery and a lithium-ion battery. The non-aqueous electrolyte comprises unsaturated phosphate compounds and unsaturated cyclic carboxylic acid anhydride compounds. The unsaturated phosphate compounds have the structure illustrated in structural formula 4; structural formula 4: R13, R11, and R12 are independently selected from hydrocarbon groups having 1-5 carbon atoms respectively, and at least one of R13, R11, and R12 is an unsaturated hydrocarbon group containing double bonds or triple bonds; the unsaturated cyclic carboxylic acid anhydride compounds have the structure illustrated in structural formula 5; structural formula 5: R14 is independently selected from vinylidene having 2-4 carbon atoms or fluoro-substituted vinylidene. By means of the synergistic effect of two compounds, the non-aqueous electrolyte has excellent high-temperature cycling performance and storage performance, and also has lower impedance and good low-temperature performance.

  一种用于锂离子电池的非水性电解液和一种锂离子电池。所述非水性电解液包括不饱和磷酸化合物和不饱和环状羧酸酐化合物。所述不饱和磷酸化合物具有结构式4所示的结构；结构式4：R13、R11和R12分别独立地选自具有1-5个碳原子的烃基，且R13、R11和R12中至少有一个为含有双键或三键的不饱和烃基；所述不饱和环状羧酸酐化合物具有结构式5所示的结构；结构式5：R14独立地选自具有2-4个碳原子的乙烯基或氟代乙烯基。通过两种化合物的协同效应，所述非水性电解液具有优异的高温循环性能和储存性能，同时具有较低的阻抗和良好的低温性能。
• REACTIONS OF DIALKYL PHOSPHITES. SYNTHESIS OF DIALKYL CHLOROPHOSPHATES, TETRAALKYL PYROPHOSPHATES, AND MIXED ORTHOPHOSPHATE ESTERS¹
  作者：GEORGE M. STEINBERG

  DOI：10.1021/jo01149a031

  日期：1950.5