tricyclopentylgallium | 149063-84-3

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机过渡后金属化合物
• 英文名称: tricyclopentylgallium
• 英文别名: Tricyclopentylgallane
• CAS: 149063-84-3
• 化学式: C₁₅H₂₇Ga
• 分子量: 277.102
• InChiKey: WIVUTHPSYQKERJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.31
• 重原子数：
  16
• 可旋转键数：
  3
• 环数：
  3.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  8-羟基喹啉 、 tricyclopentylgallium 以 正己烷 、 甲苯 为溶剂， 以91%的产率得到bis{dicyclopentyl(quinolin-8-olato)gallium}
  参考文献：
  名称：

  Synthesis and crystal structure of a quinolinolato-complex of dicyclopentylgallim

  摘要：

  Tricyclopentylgallium reacts with 8-hydroxyquinoline in 1:1 ratio to yield quantitatively bis[dicyclo-pentyl(quinolin-8-olato)gallium] which has been characterized by elemental analysis, IR, H-1 NMR and mass spectrometry. X-Ray diffraction analysis indicated that the compound belongs to the triclinic system, space group P1BAR, with a = 10.591(4), b = 12.065(4), c = 13.941(4) angstrom, alpha = 81.92(2), beta = 87.83(3), gamma = 82.55(3)-degrees, Z = 2 (dimers), R = 0.0608 (R' = 0.0871 ). The molecule contains an oxygen-bridged coplanar Ga2O2 four-membered ring.

  DOI：

  10.1039/dt9930000807
• 作为产物：
  描述：

  氯化镓 、 环戊基溴化镁 以 乙醚 为溶剂， 以92.4%的产率得到tricyclopentylgallium
  参考文献：
  名称：

  Synthesis and crystal structure of a quinolinolato-complex of dicyclopentylgallim

  摘要：

  Tricyclopentylgallium reacts with 8-hydroxyquinoline in 1:1 ratio to yield quantitatively bis[dicyclo-pentyl(quinolin-8-olato)gallium] which has been characterized by elemental analysis, IR, H-1 NMR and mass spectrometry. X-Ray diffraction analysis indicated that the compound belongs to the triclinic system, space group P1BAR, with a = 10.591(4), b = 12.065(4), c = 13.941(4) angstrom, alpha = 81.92(2), beta = 87.83(3), gamma = 82.55(3)-degrees, Z = 2 (dimers), R = 0.0608 (R' = 0.0871 ). The molecule contains an oxygen-bridged coplanar Ga2O2 four-membered ring.

  DOI：

  10.1039/dt9930000807

文献信息

• Tetraorganogallate complexes in organic chemistry: A novel, efficient and versatile preparation of ketones from acyl chlorides
  作者：Ying Han、Lei Fang、Tao Wen-Tian、Huang Yao-Zeng

  DOI：10.1016/0040-4039(95)00057-j

  日期：1995.2

  Tetraorganogallium ate complexes, prepared in situ by addition of an organolithium reagent to a triorganogallium, reacted smoothly with acyl chlorides to yield ketones in high yields and mixed ate complexes display high chemoselectivity in the transfer of one of their ligands.

  通过将有机锂试剂添加到三有机镓中原位制备的四有机镓盐配合物与酰氯平滑反应，以高收率产生酮，并且混合盐配合物在其配体之一的转移中显示出高化学选择性。
• An unexpected reaction between 2-aryl-1-nitro-1-alkenes and trialkylgallium compounds
  作者：Ying Han、Huang Yao-Zeng、Zhou Cheng-Ming

  DOI：10.1016/0040-4039(96)00542-4

  日期：1996.5

  A novel reaction between 2-aryl-1-nitro-1-alkenes and trialkylgallium compounds via NO2/alkyl substitution is found, and a possible mechanism is propose.

  发现了2-芳基-1-硝基-1-烯烃与三烷基镓化合物之间通过NO 2 /烷基取代的新反应，并提出了可能的机理。