Iridium(3+);trichloride;hydrate;hydrochloride

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: Iridium(3+);trichloride;hydrate;hydrochloride
• 化学式: (x)ClH*(x)Cl₃Ir*(x)H₂O
• 分子量: 353.0
• InChiKey: ZRPRRAOCEABMND-UHFFFAOYSA-K

计算性质

• 辛醇/水分配系数(LogP)：
  1.66
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  1
• 氢给体数：
  2
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  Iridium(3+);trichloride;hydrate;hydrochloride 在 盐酸 作用下， 以 水 为溶剂， 生成 hydrogen hexachloro iridate(III)
  参考文献：
  名称：

  Duffour, A., Annales de Chimie et de Physique, 1913, vol. 30, p. 203

  摘要：

  DOI：
• 作为产物：
  描述：

  hydrogen hexachloro iridate(III) 以 not given 为溶剂， 生成 Iridium(3+);trichloride;hydrate;hydrochloride
  参考文献：
  名称：

  Delepine, M., Annales de Chimie (Cachan, France), 1917, vol. 7, p. 292 - 307

  摘要：

  DOI：

文献信息

• Surface Characterization of Thermally Prepared, Ti‐Supported, Ir‐Based Electrocatalysts Containing Ti and Sn
  作者：T. A. F. Lassali、L. O. S. Bulhões、L. M. C. Abeid、J. F. C. Boodts

  DOI：10.1149/1.1838017

  日期：1997.10.1

  Surface characterization of Ir-based Ti- and Sn-containing electrodes of nominal composition, Ir 0.3 Ti (0.7-x) Sn x O 2 (0 ≤ x ≤ 0.7), was performed ex situ by scanning electron microscopy and energy-dispersive x-ray and in situ by open-circuit potential measurements and cyclic voltammetry. Despite the use of SnCl 2 as precursor, energy-dispersive x-ray results showed the real composition to be very

  标称成分 Ir 0.3 Ti (0.7-x) Sn x O 2 (0 ≤ x ≤ 0.7) 的 Ir 基含 Ti 和 Sn 电极的表面表征是通过扫描电子显微镜和能量色散 x 异位进行的射线和原位通过开路电位测量和循环伏安法。尽管使用 SnCl 2 作为前体，但能量色散 X 射线结果表明，由于在电极制备过程中的煅烧步骤中 SnCl 4 挥发，实际成分与标称成分非常不同。通过可见分光光度测量证实了前体混合物中SnCl 4 的形成。用 SnO 2 取代 TiO 2 导致电化学活性表面积的显着增加，这得到扫描电子显微镜、阳极伏安电荷 qs 和双层容量 C dl 的支持，作为组成的函数。获得了介于 3600 和 5100 之间的粗糙度系数。获得了角系数接近 1 的线性 C dl 与 qs 图。
• Photophysical and Electrochemical Properties of Phenanthroline‐Based Bis‐cyclometallated Iridium Complexes in Aqueous and Organic Media
  作者：Reshmi V. Kiran、Conor F. Hogan、Bruce D. James、David J. D. Wilson

  DOI：10.1002/ejic.201100639

  日期：2011.11

  organic media. The chloride salt of the underivatized phen complex, though not as soluble as the BPS chelated complex, is sufficiently soluble (> 1 mM) for sensing and other applications in aqueous media. The electrochemical response depends markedly on the medium; all the complexes showed reversible behaviour in organic media, whereas the oxidative electrochemistry of [Ir(ppy)2BPS]– and [Ir(ppy)2phen]+

  已经在有机和水介质中研究和比较了含有菲咯啉基配体的双环金属化铱 (III) 配合物的电化学和光物理性质。合成了具有通式 [Ir(ppy)2(N∩N)]+/– 的配合物，其中 ppy 是环金属化配体，2-苯基吡啶，N∩N 表示以下基于菲咯啉的配体之一：1,10-菲咯啉 (phen)、4,7-二苯基-1,10-菲咯啉 (dpp) 和 4,7-二苯基-1,10-菲咯啉二磺酸盐 (BPS)。在[Ir(ppy)2(BPS)]-的情况下，与仅溶于有机介质的dpp配合物相比，位于BPS苯环上的SO3-基团显着增加了配合物的水溶性。未衍生化的苯酚复合物的氯化物盐，虽然不如 BPS 螯合复合物可溶，可充分溶解 (> 1 mM) 用于水介质中的传感和其他应用。电化学响应显着取决于介质；所有配合物在有机介质中均表现出可逆行为，而 [Ir(ppy)2BPS]– 和 [Ir(ppy)2phen]+ 的氧化电化学是不
• Accelerated Luminophore Discovery through Combinatorial Synthesis
  作者：Michael S. Lowry、William R. Hudson、Robert A. Pascal、Stefan Bernhard

  DOI：10.1021/ja047156+

  日期：2004.11.1

  A method for accelerating the discovery of ionic luminophores using combinatorial techniques is reported. The photophysical properties of the resulting transition-metal-based chromophores were compared against a series of analogous, traditionally prepared species. The strong overlap between these two sets confirms the identity of the parallel synthesis products and supports the truthfulness of the combinatorial results. Further support for the combinatorial method comes from the adherence of these complexes to the energy gap law. The relationship between the structure of a complex and its photophysical properties was also considered, and static DFT calculations were used to assess whether it is feasible to predict the luminescent behavior of novel materials.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Ir: MVol., 5.5, page 54 - 70
  作者：

  DOI：——

  日期：——
• Catalytic oxidation of 1-hexene and cyclohexene with molecular oxygen by iridium nitro complexes
  作者：P.J Baricelli、V.J Sánchez、A.J Pardey、S.A Moya

  DOI：10.1016/s1381-1169(00)00343-5

  日期：2000.12

  The oxidation of 1-hexene and cyclohexene by molecular oxygen catalyzed by the iridium complexes [Ir(CH3CN)(4)NO2](A)(2) (A=PF6 (1) or BF4 (2)) has been studied in acetonitrile under P(O-2)=20 atm, T=120 degreesC, substrate/catalyst=100, t=20 h. Both complexes are active for oxidizing 1-hexene to 1,2-epoxyhexane, 1-hexen-3-one, 2-hexenal, 1-hexen-3-ol and 2-hexen-l-ol and also oxidize cyclohexene to 2-cyclohexen-1-one, 7-oxabicyclo[4.1.0]hexane and 2-cyclohexen-l-ol. Preliminary kinetic parameters are reported for complex (1). (C) 2000 Elsevier Science B.V. All rights reserved.