1-(2-hydroxyacenaphtylen-1-yl)ethanone | 71739-33-8

• 分子结构分类: 有机化合物 - 苯类化合物 - 吖萘类
• 英文名称: 1-(2-hydroxyacenaphtylen-1-yl)ethanone
• 英文别名: 2-Hydroxy-1-acetyl-acenaphthylen；1-(2-hydroxyacenaphthylen-1-yl)ethanone
• CAS: 71739-33-8
• 化学式: C₁₄H₁₀O₂
• 分子量: 210.232
• InChiKey: IGGQVLXNUNUSFJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.17
• 重原子数：
  16.0
• 可旋转键数：
  1.0
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.07
• 拓扑面积：
  37.3
• 氢给体数：
  1.0
• 氢受体数：
  2.0

反应信息

• 作为反应物：
  描述：

  重氮甲烷 、 1-(2-hydroxyacenaphtylen-1-yl)ethanone 生成 1-(2-methoxy-acenaphthylen-1-yl)-ethanone
  参考文献：
  名称：

  A Cyclic Saturated Pentaalkoxyphosphorane. Diketols Via Oxyphosphoranes

  摘要：

  DOI：

  10.1021/ja00866a061
• 作为产物：
  描述：

  5-Acetyl-2,2,2-trimethoxy-5-methylspiro[1,3,2lambda5-dioxaphospholane-4,2'-acenaphthylene]-1'-one 以 甲醇 为溶剂， 生成 1-(2-hydroxyacenaphtylen-1-yl)ethanone
  参考文献：
  名称：

  A Cyclic Saturated Pentaalkoxyphosphorane. Diketols Via Oxyphosphoranes

  摘要：

  DOI：

  10.1021/ja00866a061

文献信息

• Electroinduced Carbene Formation in the Cathodic Reduction of 1,2-Dicarbonyl Compounds via Electron-Transfer to the Solvent
  作者：Belen Batanero、Marina Ramirez-Moreno、Fructuoso Barba

  DOI：10.1016/j.electacta.2015.03.143

  日期：2015.6

  Electrochemical reduction of 9,10-phenanthrenequinone, benzil and acenaphthenequinone in 1,1,1-trichloroethane (TCE)/TBAP under constant potential conditions provides an interesting entry to new coupling products through an electron-transfer reaction in solution to the chlorinated solvent. This electroinduced reaction points out the differences in the reaction pathway followed by these 1,2-dicarbonyl compounds depending on their geometry. The intermediates nature and their behavior, both in solution and at the electrode surface, are discussed. (C) 2015 Elsevier Ltd. All rights reserved.