Perfluoro-3-propyl-4-aza-2,4-octadiene | 133586-53-5

• 分子结构分类: 有机化合物 - 有机卤素化合物 - 亚胺酰卤
• 英文名称: Perfluoro-3-propyl-4-aza-2,4-octadiene
• CAS: 133586-53-5
• 化学式: C₁₀F₁₉N
• 分子量: 495.086
• InChiKey: FCCABBIVTFVESY-TYPSKITBSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.76
• 重原子数：
  30.0
• 可旋转键数：
  5.0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.7
• 拓扑面积：
  12.36
• 氢给体数：
  0.0
• 氢受体数：
  1.0

反应信息

• 作为反应物：
  描述：

  Perfluoro-3-propyl-4-aza-2,4-octadiene 在 cesium fluoride 作用下， 以 乙腈 为溶剂， 反应 4.0h， 以100%的产率得到Perfluoro-4-ethyl-5-aza-3,5-nonadiene
  参考文献：
  名称：

  Transfer of an organofluorine fragment from CF2=CFSi(CH3)3 and CFCl2Si(CH3)3 to unsaturated perfluorinated compounds catalyzed by cesium fluoride

  摘要：

  A study was carried out on the reaction of 1,1,2-trifluorovinylsilane and fluorodichloromethylsilane in the presence of CsF with perfluoro-2-methyl-2-pentene, perfluoro-5-aza-4-nonene, and perfluoroisobutylene. These silanes are capable of transferring a fluorine-containing fragment to unsaturated organofluorine compounds.

  DOI：

  10.1007/bf01184539
• 作为产物：
  描述：

  三甲基(1,2,2-三氟乙烯基)硅烷 、 全氟(5-氮杂-4-壬烯) 在 cesium fluoride 作用下， 以 乙腈 为溶剂， 以89%的产率得到Perfluoro-3-propyl-4-aza-2,4-octadiene
  参考文献：
  名称：

  Transfer of an organofluorine fragment from CF2=CFSi(CH3)3 and CFCl2Si(CH3)3 to unsaturated perfluorinated compounds catalyzed by cesium fluoride

  摘要：

  A study was carried out on the reaction of 1,1,2-trifluorovinylsilane and fluorodichloromethylsilane in the presence of CsF with perfluoro-2-methyl-2-pentene, perfluoro-5-aza-4-nonene, and perfluoroisobutylene. These silanes are capable of transferring a fluorine-containing fragment to unsaturated organofluorine compounds.

  DOI：

  10.1007/bf01184539

文献信息

• Transfer of an organofluorine fragment from CF2=CFSi(CH3)3 and CFCl2Si(CH3)3 to unsaturated perfluorinated compounds catalyzed by cesium fluoride
  作者：V. A. Petrov、N. V. Shevchenko、V. K. Grinevskaya、Z. N. Parnes、V. V. Bardin、G. G. Furin、L. S. German、M. E. Vol'pin

  DOI：10.1007/bf01184539

  日期：1990.12

  A study was carried out on the reaction of 1,1,2-trifluorovinylsilane and fluorodichloromethylsilane in the presence of CsF with perfluoro-2-methyl-2-pentene, perfluoro-5-aza-4-nonene, and perfluoroisobutylene. These silanes are capable of transferring a fluorine-containing fragment to unsaturated organofluorine compounds.