4,9-diallyl-2,2,7,7-tetramethyl-1,6-dioxa-4,9-diaza-2,7-disilacyclodecane-5,10-dione | 51851-82-2

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 4,9-diallyl-2,2,7,7-tetramethyl-1,6-dioxa-4,9-diaza-2,7-disilacyclodecane-5,10-dione
• 英文别名: 1,1,6,6-tetramethyl-4,9-diallyl-4,9-diaza-2,7-dioxa-1,6-disilacyclodecane-3,8-dione；4,9-diallyl-2,2,7,7-tetramethyl-[1,6,4,9,2,7]dioxadiazadisilecane-5,10-dione；4,9-Diallyl-2,2,7,7-tetramethyl-1,6-dioxa-4,9-diaza-2,7-disilacyclodecan-5,10-dion；2,2,7,7-Tetramethyl-4,9-bis(prop-2-enyl)-1,6,4,9,2,7-dioxadiazadisilecane-5,10-dione
• CAS: 51851-82-2
• 化学式: C₁₄H₂₆N₂O₄Si₂
• 分子量: 342.542
• InChiKey: XMDODEFSQAQYEH-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.74
• 重原子数：
  22
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.57
• 拓扑面积：
  59.1
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  氯甲基二甲基氯硅烷 、 trimethylsilyl trimethylsilylallylcarbamate 以 甲苯 为溶剂， 以92%的产率得到4,9-diallyl-2,2,7,7-tetramethyl-1,6-dioxa-4,9-diaza-2,7-disilacyclodecane-5,10-dione
  参考文献：
  名称：

  Sheludyakov, V. D.; Kirilina, N. I.; Kirilin, A. D., Journal of general chemistry of the USSR, 1983, vol. 53, # 2, p. 412

  摘要：

  DOI：

文献信息

• Sheludyakov,V.D. et al., Journal of general chemistry of the USSR, 1974, vol. 44, p. 1477 - 1481
  作者：Sheludyakov,V.D. et al.

  DOI：——

  日期：——
• The reaction of chloromethylsilanes with amines, hexamethyldisilazanes, and silylcarhamates
  作者：A. D. Kirilin、N. B. Sokova、E. A. Chernyshev

  DOI：10.1007/bf00703492

  日期：1994.10

  The reactions of chloromethylsilanes with amines, hexamethyldisilazane, and silylcarbamates were studied. The dependence of the composition and structure of the resulting products on the nature of the reagents used and reaction conditions was determined. A scheme for the synthesis of 4,9-diaza-2,7-dioxa-1,6-disilacyclodecane-3,8-dione derivatives was suggested.
• Sheludyakov, , V. D.; Dmitrieva, A. B.; Gusev, A. I., Journal of general chemistry of the USSR, 1984, vol. 54, # 10, p. 2056 - 2058
  作者：Sheludyakov, , V. D.、Dmitrieva, A. B.、Gusev, A. I.、Apal'kova, G. M.、Kirilin, A. D.

  DOI：——

  日期：——
• Sheludyakov, V. D.; Lebedeva, A. B.; Shukyurov, A. Kh., Journal of general chemistry of the USSR, 1986, vol. 56, # 6, p. 1155 - 1157
  作者：Sheludyakov, V. D.、Lebedeva, A. B.、Shukyurov, A. Kh.、Kirilin, A. D.

  DOI：——

  日期：——
• Mironov,V.F. et al., Journal of general chemistry of the USSR, 1973, vol. 43, p. 2557 - 2558
  作者：Mironov,V.F. et al.

  DOI：——

  日期：——