cesium tetrabromoaurate(III) | 13682-59-2

• 分子结构分类: 无机化合物 - 混合金属/非金属化合物 - 过渡金属盐
• 英文名称: cesium tetrabromoaurate(III)
• 英文别名: Caesium tetrabromoaurate；cesium;tetrabromogold(1-)
• CAS: 13682-59-2
• 化学式: AuBr₄*Cs
• 分子量: 649.488
• InChiKey: PSIMYPAZTSWWOY-UHFFFAOYSA-J

计算性质

• 辛醇/水分配系数(LogP)：
  -14.98
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  cesium tetrabromoaurate(III) 、 caesium bromide 、 金 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  Studies of mixed-valence states in three-dimensional halogen-bridged gold compounds, Cs2Au I Au III X6(X = Cl, Br or I). Part 1. Synthesis, X-ray powder diffraction, and electron spin resonance studies of CsAu0.6Br2.6

  摘要：

  A new non-stoichiometric mixed-valence compound CsAu0.6Br2.6 has been prepared, and its powder X-ray diffraction profile, ESR spectra, and electrical conductivity determined. From its empirical formula the average valence of Au is +2.67. Powder diffraction data indicate that the compound has a cubic perovskite structure [cubic lattice, space group Pm3m, a = 5.462(2) angstrom]. This means that the AuBr6 octahedra are crystallographically equivalent. ESR measurements show the existence of a +II formal oxidation state for Au. The conductivity is four orders of magnitude higher than that of the Au(I)-Au(III) mixed-valence compound Cs2Au2Br6.

  DOI：

  10.1039/dt9910003115
• 作为产物：
  描述：

  溴化金 、 caesium bromide 生成 cesium tetrabromoaurate(III)
  参考文献：
  名称：

  Wells, H. L.; Wheeler, H. L., American Journal of Science, 1892, vol. 44, p. 157 - 162

  摘要：

  DOI：

文献信息

• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Au: MVol.3, 11.2, page 751 - 762
  作者：

  DOI：——

  日期：——
• Studies of mixed-valence states in three-dimensional halogen-bridged gold compounds, Cs2Au I Au III X6, (X = Cl, Br or I). Part 2. X-Ray photoelectron spectroscopic study
  作者：Hiroshi Kitagawa、Norimichi Kojima、Tsuyoshi Nakajima

  DOI：10.1039/dt9910003121

  日期：——

  The mixed-valence states in Cs2Au(I)Au(III)X6 (X = Cl, Br or I) were systematically studied by X-ray photoelectron spectroscopy of the Au 4f region for the first time. The gold valence states in halogeno complexes of Au(I) and Au(III) were also studied. In Cs2Au2X6 the difference between the oxidation state of Au(I) and that of Au(III) decreases as the covalency of the -Au(I)-X-Au(III)-X- bonds increases in the order X = Cl < Br < I, because the charge-transfer interaction between Au(I) and Au(III) through the bridging halogen becomes stronger in this order. In the non-stoichiometric CsAu0.6Br2.6 the oxidation state of Au is considered to be almost homogeneous.
• Wells, H. L.; Wheeler, H. L., Zeitschrift fur anorganische Chemie, 1892, vol. 2, p. 304 - 310
  作者：Wells, H. L.、Wheeler, H. L.

  DOI：——

  日期：——
• Ferrari, A.; Goghi, l., Gazzetta Chimica Italiana, 1941, vol. 71, p. 440 - 446
  作者：Ferrari, A.、Goghi, l.

  DOI：——

  日期：——
• Wells, H. L.; Wheeler, H. L., American Journal of Science, 1892, vol. 44, p. 157 - 162
  作者：Wells, H. L.、Wheeler, H. L.

  DOI：——

  日期：——