2-氨基-4,6-双(乙基氨基)-1,3,5-三嗪 | 5606-16-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 三嗪类
• 中文名称: 2-氨基-4,6-双(乙基氨基)-1,3,5-三嗪
• 英文名称: N²,N⁴-diethyl-[1,3,5]triazine-2,4,6-triyltriamine
• 英文别名: N²,N⁴-Diaethyl-[1,3,5]triazin-2,4,6-triyltriamin；2-amino-4,6-bis(ethylamino)-1,3,5-triazine；1,3,5-Triazine-2,4,6-triamine, N,N'-diethyl-；2-N,4-N-diethyl-1,3,5-triazine-2,4,6-triamine
• CAS: 5606-16-6
• 化学式: C₇H₁₄N₆
• mdl: MFCD01632361
• 分子量: 182.228
• InChiKey: JGFFIQSOYIZEHY-UHFFFAOYSA-N

物化性质

• 沸点：
  392.8±25.0 °C(Predicted)
• 密度：
  1.271±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  0.9
• 重原子数：
  13
• 可旋转键数：
  4
• 环数：
  1.0
• sp3杂化的碳原子比例：
  0.571
• 拓扑面积：
  88.8
• 氢给体数：
  3
• 氢受体数：
  6

安全信息

• 海关编码：
  2933699090

反应信息

• 作为反应物：
  描述：

  2-氨基-4,6-双(乙基氨基)-1,3,5-三嗪 、 盐酸 生成 氨 、 乙胺 、 氰尿酸
  参考文献：
  名称：

  Traube; Kegel; Schulz, Angewandte Chemie, 1926, vol. 39, p. 1468

  摘要：

  DOI：
• 作为产物：
  描述：

  溴乙烷 、 alkaline earth salt of/the/ methylsulfuric acid 在 乙醇 作用下， 生成 2-氨基-4,6-双(乙基氨基)-1,3,5-三嗪
  参考文献：
  名称：

  Traube; Kegel; Schulz, Angewandte Chemie, 1926, vol. 39, p. 1468

  摘要：

  DOI：

文献信息

• Method for obtaining a functionalized triazine compound and the triazine compound obtained by said method
  申请人：Borealis Agrolinz Melamine GmbH

  公开号：EP2774922A1

  公开（公告）日：2014-09-10

  The present invention relates to a method for obtaining a triazine compound with at least one amino group comprising a an aliphatic moiety with at least two functional groups comprising the steps of a) providing at least one triazine compound of the general formulae (I) wherein - R1 and R2 mean independently from each other Q1 or a moiety of the formula R3-N-R4 or R5-N-R6 bound with its central nitrogen atom to the triazine ring of the structure of formula (I), whereat - Q1 means a linear or branched C1-C30-alkyl or a cyclic substituent in form of a C5-C20-cycloalkyl, a C5-C20-aryl, a C1-C20-alkylsubstituted C5-C20-aryl or an amide of a cyclic unsaturated carboxylic acid, whereat in each case one or multiple carbon atoms can be substituted by one or multiple oxygen atoms, sulphur atoms, substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-,-OC(O)-,-C(O)- and/or -OC(O)O-, - R3, R4, R5 and R6 mean independently from each other H, linear or branched C1-C20-alkyl, C5-C20-cyclo alkyl, C5-C20-aryl, C1-C20-alkylsubstituted C5-C20-aryl,whereat in each case one or multiple carbon atoms can be substituted by one or multiple oxygen atoms, sulphur atoms and/or substituted nitrogen atoms and/or by one or multiple groups of the type -C(O)O-, -OC(O)-, -C(O)- and/or -OC(O) O- and/or can be functionalized by one or multiple hydroxyl groups and/or mercapto groups; and b) reacting said aminotriazine of the general formulae (I) with at least one primary amine of the general formulae (II)         R7NH2 wherein R7 is a linear or branched C3-C20-alkyl, C5-C20 cycloalkyl, C5-C20 aryl substituted C3-C20-alkyl, or C5-C20-aryl substituted C5-C20-cycloalkyl, C5-C20 aryl or C1-C20 alkylsubstituted C5-C20 aryl each comprising at least two functional groups, or a mixture of primary amines of the general formulae (II), wherein the at least two functional groups are not bound to the carbon atom carrying the primary amino group -NH2, and wherein the at least two functional groups are not bound to the same carbon atom, c) wherein the reaction takes place in the presence of at least one acidic catalyst. The present invention relates also to the compounds obtained by this method and their use.

  本发明涉及一种获得至少具有一个氨基的三嗪化合物的方法，其中该氨基包含至少两个功能基团的脂肪基，包括以下步骤：a) 提供至少一个通式（I）的三嗪化合物，其中- R1和R2分别独立地表示Q1或与其中心氮原子结合的通式（I）的三嗪环的结构中的R3-N-R4或R5-N-R6基团，其中- Q1表示线性或支链C1-C30烷基或以C5-C20环烷基，C5-C20芳基，C1-C20烷基取代的C5-C20芳基的酰胺的形式的环状取代基，在每种情况下，一个或多个碳原子可以被一个或多个氧原子，硫原子，取代的氮原子和/或一个或多个-C（O）O-，-OC（O）-，-C（O）-和/或-OC（O）O-类型的基团取代，- R3，R4，R5和R6独立地表示H，线性或支链C1-C20烷基，C5-C20环烷基，C5-C20芳基，C1-C20烷基取代的C5-C20芳基，在每种情况下，一个或多个碳原子可以被一个或多个氧原子，硫原子和/或取代的氮原子和/或一个或多个-C（O）O-，-OC（O）-，-C（O）-和/或-OC（O）O-类型的基团取代，或者可以被一个或多个羟基和/或巯基官能化；并且b)将通式（I）的氨基三嗪与至少一种通式（II）的主要胺反应，其中R7是线性或支链C3-C20烷基，C5-C20环烷基，C5-C20芳基取代的C3-C20烷基，或C5-C20芳基取代的C5-C20环烷基，C5-C20芳基或C1-C20烷基取代的C5-C20芳基，每种都包含至少两个功能基团，或通式（II）的主要胺混合物，其中至少两个功能基团未结合到带有主要氨基团-NH2的碳原子上，并且至少两个功能基团未结合到同一碳原子上，c)其中反应在至少一种酸性催化剂存在下进行。本发明还涉及通过该方法获得的化合物及其用途。
• EPOXY/ACID ANHYDRIDE COMPOSITION
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0834523A1

  公开（公告）日：1998-04-08

  (Object) It is to provide an epoxy/acid anhydride composition comprising an epoxy compound and an acid anhydride serving as a curing agent wherein a substituted triazine of a specific structure is employed as a curing accelerator to thereby impart a long pot life, a high storage stability and good working characteristics to the composition and cause no defect such as bubbling or cracking in the cured resin. (Constitution of the invention) An epoxy/acid anhydride composition characterized by containing, as a curing accelerator, a substituted triazine of the formula [] (wherein X is an amino group, C1-18 monoalkylamino group, di C1-18 alkylamino group, morpholino group, piperidino group, methyl group or phenyl group; R1 and R2 independently each represent C1-12 alkyl group, C1-12 hydroxyalkyl group, C4-8 cycloalkyl group, C5-9 cycloalkylmethyl group or C5-9 methylcycloalkyl group) in an epoxy/acid anhydride composition in which an epoxy compound and an acid anhydride-curing agent are contained, and an epoxy/acid anhydride resin composition prepared by thermosetting the epoxy/acid anhydride composition.

  目的 提供一种环氧/酸酐组合物，该组合物由环氧化合物和用作固化剂的酸酐组成，其中使用了特定结构的取代三嗪作为固化促进剂，从而使该组合物具有较长的固化寿命、较高的储存稳定性和良好的工作特性，并且不会导致固化树脂出现气泡或开裂等缺陷。 (本发明的结构） 一种环氧树脂/酸酐组合物，其特征在于含有式[]的取代三嗪作为固化促进剂。 (其中 X 是氨基、C1-18 单烷基氨基、二 C1-18 烷基氨基、吗啉基、哌啶基、甲基或苯基；R1 和 R2 各自独立地代表环氧化合物和酸酐固化剂的环氧/酸酐组合物中的 C1-12 烷基、C1-12 羟基烷基、C4-8 环烷基、C5-9 环烷基甲基或 C5-9 甲基环烷基），以及通过热固化该环氧/酸酐组合物制备的环氧/酸酐树脂组合物。
• METHODS FOR MODIFYING 1,3,5-TRIAZINE DERIVATIVES
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0882720A1

  公开（公告）日：1998-12-09

  A method for modifying 1,3,5-triazine derivatives characterized by reacting a 1,3,5-triazine derivative having at least one amino or monosubstituted amino group on any of the ring carbon atoms with an alcohol by heating in the presence of a metallic catalyst and hydrogen to thereby introduce an alkyl or alkenyl group into each amino or monosubstituted amino group; another method for modifying 1,3,5-triazine derivatives characterized by reacting a 1,3,5-triazine derivative having at least one amino or monosubstituted amino group on any of the ring carbon atoms with a dihydric alcohol by heating in the presence of a metallic catalyst and hydrogen to thereby introduce a hydroxylated alkyl group into each amino or monosubstituted amino group; and 1,3,5-triazine derivatives obtained by the methods. The various modified substituted 1,3,5-triazine derivatives thus produced are generally obtained as a mixture. These derivatives can be isolated as high-purity compounds by a general separation method for organic compounds, and the compounds are usable in the various applications mentioned in the specification. According to applications (for example, use as modifier additives, in particular a flame-retardant and a plasticizer for resins), the reaction mixture can be used as it is without being separated. Many of the substituted triazine derivatives obtained have been relatively difficult to synthesize or expensive. Since many of the derivatives are interesting with respect to their physical properties, e.g., solubility in water and in various organic solvents, high-temp. stability, melting point, boiling point, and basicity, they are thought to have a wider range of applications than conventional ones.

  一种改性 1，3，5-三嗪衍生物的方法，其特征在于在金属催化剂和氢的存在下，通过加热使任一环碳原子上具有至少一个氨基或单取代氨基的 1，3，5-三嗪衍生物与醇反应，从而在每个氨基或单取代氨基中引入一个烷基或烯基；另一种改性 1,3,5-三嗪衍生物的方法，其特征在于在金属催化剂和氢气存在下，使任一环碳原子上具有至少一个氨基或单取代氨基的 1,3,5-三嗪衍生物与二元醇反应，从而在每个氨基或单取代氨基中引入羟基烷基；以及通过上述方法获得的 1,3,5-三嗪衍生物。这样制得的各种改性取代的 1,3,5-三嗪衍生物通常以混合物的形式获得。这些衍生物可作为高纯度化合物通过有机化合物的一般分离方法分离出来，这些化合物可用于说明书中提到的各种应用中。根据用途（例如用作改性添加剂，特别是阻燃剂和树脂增塑剂），反应混合物可以不经分离直接使用。所获得的许多取代三嗪衍生物都比较难以合成或价格昂贵。由于许多衍生物在物理性质（如在水和各种有机溶剂中的溶解性、高温稳定性、熔点、沸点和碱性）方面都很有趣，因此它们被认为比传统的衍生物具有更广泛的用途。
• METHOD OF ALKYLATING TRIAZINE DERIVATIVE
  申请人：NISSAN CHEMICAL INDUSTRIES, LIMITED

  公开号：EP0711760B1

  公开（公告）日：2002-05-15
• Reactive liquid polymer crosslinking agent and process for preparation
  申请人：——

  公开号：US20030168629A1

  公开（公告）日：2003-09-11

  A reactive liquid crosslinking agent for use in the preparation of polymeric substances. The crosslinking agent comprises a substituted 1,3,5 Triazine reacted with water, an acid alkyl sulfonate and/or phosphonate and a solidifying modifier containing an hydroxyl functional group. The reactive liquid polymer crosslinking agent has a solids content between 20-99% solids. The reactive liquid crosslinking agents (RLPC's) are useful as modifiers in the preparation of polymeric compounds which are suitable for one-component self-crosslinking adhesives, coatings and polymers used in optics, textiles, composites, casting and molding. RLPC systems containing from 1-30% RLPC provide fast single package thermosetting polymeric compounds with enhanced properties such as chemical, heat and abrasion resistance.