Ni3Mo | 12033-22-6

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Ni3Mo
• 英文别名: Molybdenum--nickel (1/3)；molybdenum;nickel
• CAS: 12033-22-6
• 化学式: MoNi₃
• 分子量: 272.01
• InChiKey: NNJFNUVIVKBQGW-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  4
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  镍 、 钼 生成 Ni3Mo
  参考文献：
  名称：

  Changes in electronic structure of Ni3Mo caused by modification of atomic order

  摘要：

  The electronic structure of a stoichiometric Ni3Mo alloy formed in FCC and orthorhombic structures has been investigated experimentally and theoretically. The L(alpha) X-ray emission spectra and L(2,3) and K-absorption edges, as well as the isochromat spectra, were measured and compared with calculated spectra. Modifications of the local states distribution around Ni-atoms caused by changes in the number and distance of nearest neighbour atoms have been estimated experimentally. Similar modifications were observed in the calculated L-spectra but some discrepancies in the position of p-like unoccupied slates of FCC alloys were found. Additionally, the importance of the correlation effects in resonantly excited spectra was estimated and the dependence of the probability to excite the multiple-vacancy satellites on the Ni-atom distribution in the crystal was discussed.

  DOI：

  10.1016/0921-4526(95)00452-1

文献信息

• Crystal structure and morphology control of molybdenum carbide nanomaterials synthesized from an amine–metal oxide composite
  作者：Cheng Wan、Nicole A. Knight、Brian M. Leonard

  DOI：10.1039/c3cc46551a

  日期：——

  Multiple phases of molybdenum carbide have been synthesized using a unique amine–metal oxide composite material.

  使用独特的胺-金属氧化物复合材料合成了多相钼碳化物。
• Alloying effect on K X-ray intensity ratios, K X-ray production cross-sections and radiative Auger ratios in superalloys constitute from Al, Ni and Mo elements
  作者：N. Kup Aylikci、E. Tiraşoğlu、İ.H. Karahan、V. Aylikci、M. Eskil、E. Cengiz

  DOI：10.1016/j.chemphys.2010.08.021

  日期：2010.11

  production cross-sections, Kβ/Kα, KLM/Kα and KMM/Kβ RAE intensity ratios of Ni and σKα,σKβ1,2 production cross-sections, Kβ1,3/Kα, Kβ2,4/Kα, Kβ2,4/Kβ1,3, KLM/Kα and KMM/Kβ RAE intensity ratios of Mo have been measured in pure metals and in superalloy specimens. The samples were excited by 59.5 keV γ-rays from a 241Am annular radioactive source. K X-rays emitted by samples were counted by an Ultra-LEGe detector

  在这项研究中，σ ķ α，β σKα，β生产的横截面，ķ β / ķ α，KLM / ķ α和KMM / ķ β Ni和σKα，σKβ1,2的RAE强度比生产的横截面，ķ β1 ，3 / ķ α，ķ β2,4 / ķ α，ķ β2,4 / ķ β1,3，KLM / ķ α和KMM / ķ βMo的RAE强度比已在纯金属和高温合金样品中进行了测量。样品由241 Am环形放射源的59.5 keVγ射线激发。用Ultra-LEGe检测器对样品发出的K X射线进行计数，分辨率为5.9 keV，分辨率为150 eV。研究了合金化对镍和钼的荧光参数，相结构和腐蚀行为的影响。高温合金中Ni和Mo的X射线荧光参数表明，与纯金属相比，存在显着差异。这些差异归因于超合金中价电子的重组和/或电荷转移现象。
• Changes in electronic structure of Ni3Mo caused by modification of atomic order
  作者：K Ławniczak-Jabłońska、L.-C Duda、J Guo、S.M Butorin、J Nordgren

  DOI：10.1016/0921-4526(95)00452-1

  日期：1996.1

  The electronic structure of a stoichiometric Ni3Mo alloy formed in FCC and orthorhombic structures has been investigated experimentally and theoretically. The L(alpha) X-ray emission spectra and L(2,3) and K-absorption edges, as well as the isochromat spectra, were measured and compared with calculated spectra. Modifications of the local states distribution around Ni-atoms caused by changes in the number and distance of nearest neighbour atoms have been estimated experimentally. Similar modifications were observed in the calculated L-spectra but some discrepancies in the position of p-like unoccupied slates of FCC alloys were found. Additionally, the importance of the correlation effects in resonantly excited spectra was estimated and the dependence of the probability to excite the multiple-vacancy satellites on the Ni-atom distribution in the crystal was discussed.