Trichlorsilyl-dimethylphosphin | 18090-29-4

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: Trichlorsilyl-dimethylphosphin
• 英文别名: Phosphorane, dichloro(chlorothio)dimethyl-；dimethyl(trichlorosilyl)phosphane
• CAS: 18090-29-4
• 化学式: C₂H₆Cl₃PSi
• 分子量: 195.488
• InChiKey: YBPVBFGBKZWNHG-UHFFFAOYSA-N

物化性质

• 沸点：
  75.0±9.0 °C(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  2.88
• 重原子数：
  7
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  二甲基磷化锂 在 四氯化硅 作用下， 生成 Trichlorsilyl-dimethylphosphin
  参考文献：
  名称：

  Fritz,G.; Poppenburg,G., Angewandte Chemie, 1960, vol. 72, p. 208

  摘要：

  DOI：

文献信息

• Reactions of Difluorosilylene with Amines, Phosphines and Halomethanes The First Evidence of the Insertion of Difluorosilylene into Tetrafluorosilane
  作者：Chih-Wei Chang、Chao-Shiuan Liu、Chi-Young Lee

  DOI：10.1002/jccs.199900061

  日期：1999.6

  AbstractThe reactions of SiF2/SiF4 with amines, phosphines and various halomethanes were studied. The results show that in the presence of strong Lewis base (Et3N, HNEt2, PR3, PR2Cl), SiF2 inserts initially into SiF4 to form Si2F6, which was followed by subsequent reactions leading to products containing SiF3 groups. This is the first report of the insertion of SiF2 into SiF4. When the reactants were a weaker base (such as RPCl2, CX3Br, X=F, Cl), insertion of SiF2 into P‐Cl and C‐Br bonds became predominant.
• Fritz,G.; Poppenburg,G., Angewandte Chemie, 1960, vol. 72, p. 208
  作者：Fritz,G.、Poppenburg,G.

  DOI：——

  日期：——