3-chloro-IX | 168270-66-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: 3-chloro-IX
• 英文别名: 7-chloro-4,4-dimethoxy-4-sila-1-heptene；3-chloropropyl-dimethoxy-prop-2-enylsilane
• CAS: 168270-66-4
• 化学式: C₈H₁₇ClO₂Si
• 分子量: 208.76
• InChiKey: PAYSKNSIVWULJJ-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  2.54
• 重原子数：
  12
• 可旋转键数：
  7
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  18.5
• 氢给体数：
  0
• 氢受体数：
  2

反应信息

• 作为反应物：
  描述：

  3-chloro-IX 在 四丁基氟化铵 、 硫脲 作用下， 以13%的产率得到allyldimethoxy(3-sulfanylpropyl)allylsilane
  参考文献：
  名称：

  Si-disubstituted diallylsilanes in homolytic thiylation and electrophilic fragmentation reactions

  摘要：

  Approaches to Si-disubstituted 1-thia-5-silacyclooctanes based on homolytic addition of hydrogen sulfide to diallylsilanes R2Si(CH2CH=CH2)(2) and on intramolecular cyclization of Si-disubstituted (allyl)(gamma-sulfanylpropyl)silanes have been studied. In the former case the reactivity of the silanes decreases in the order R = MeO > F > Me > Ph, whereas in the latter case the reactivity order is slightly different: Me > MeO approximate to F >> Ph. The reactions of diphenyl-and dimethyldiallylsilanes with the complex BF3 center dot 2AcOH occur in a different manner: The former involves rearrangement to form fluoro(2-methylpent-4-enyl)diphenylsilane, while the latter, elimination of the two allyl groups to fluorodimethylsilane and propene.

  DOI：

  10.1134/s1070363208090065
• 作为产物：
  描述：

  allyltrimethoxysilane 以8.0 g (81%)的产率得到3-chloro-IX
  参考文献：
  名称：

  Allylalkylsilanes and their preparation methods

  摘要：

  本发明涉及一种由通式（III）表示的烯丙基硅烷及其制备方法，通过在氢硅化催化剂（如氯铂酸、硅胶负载铂、三丁基胺和Pd、Rh、Ni金属）的存在下，将通式I表示的烯丙基硅烷与通式II表示的烯烃化合物反应制备而成。其中，X独立地表示氯或烷氧基（C1-C4），R选自Ph、CH2Cl、CnH2nCH3（n=0-15）、Si(Me)mCl3-m（m=0-3）、CF3、CH2CF3、CN、CH2CN、(CH2)2Si(Me)mCl3-m（m=0-3）、Si(Me)m(OR1)3-m（m=0-3）、(CH2)2Si(Me)m(OR1)3-m（m=0-3）（其中Me为甲基，R1为甲氧基或乙氧基基团）、Ph-CH2Cl和环己烯基团。

  公开号：

  US05420323A1

文献信息

• CN117105970
  申请人：——

  公开号：——

  公开（公告）日：——
• Allylalkylsilanes and their preparation methods
  申请人：Korea Institute of Science and Technology

  公开号：US05420323A1

  公开（公告）日：1995-05-30

  The present invention relates to allylakylsilanes represented by the general formula (III) and their preparation methods by reacting allylsilanes represented by the formula I with olefin compounds represented by the formula II in the presence of hydrosilation catalysts such as chloroplatinic acid, platinum on silica, tributyl amine and Pd, Rh, Ni metals. ##STR1## wherein X represents independently chloro or alkoxy (C.sub.1-C.sub.4) and R is selected from the group consisting of Ph, CH.sub.2 Cl, C.sub.n H.sub.2n CH.sub.3 (n=0-15), Si(Me).sub.m Cl.sub.3-m (m=0-3), CF.sub.3, CH.sub.2 CF.sub.3, CN, CH.sub.2 CN, ##STR2## CH.sub.2 Si(Me).sub.m CL.sub.3-m (m=0-3), Si(Me).sub.m (OR.sup.1).sub.3-m (m=0-3), CH.sub.2 Si(Me).sub.m (OR.sup.1).sub.3-m (m=0-3), (wherein Me is methyl and R.sup.1 is methoxy or ethoxy group), Ph-CH.sub.2 Cl, and cyclohexenyl group.

  本发明涉及一种由通式（III）表示的烯丙基硅烷及其制备方法，通过在氢硅化催化剂（如氯铂酸、硅胶负载铂、三丁基胺和Pd、Rh、Ni金属）的存在下，将通式I表示的烯丙基硅烷与通式II表示的烯烃化合物反应制备而成。其中，X独立地表示氯或烷氧基（C1-C4），R选自Ph、CH2Cl、CnH2nCH3（n=0-15）、Si(Me)mCl3-m（m=0-3）、CF3、CH2CF3、CN、CH2CN、(CH2)2Si(Me)mCl3-m（m=0-3）、Si(Me)m(OR1)3-m（m=0-3）、(CH2)2Si(Me)m(OR1)3-m（m=0-3）（其中Me为甲基，R1为甲氧基或乙氧基基团）、Ph-CH2Cl和环己烯基团。
• Si-disubstituted diallylsilanes in homolytic thiylation and electrophilic fragmentation reactions
  作者：E. N. Suslova、A. I. Albanov、B. A. Shainyan

  DOI：10.1134/s1070363208090065

  日期：2008.9

  Approaches to Si-disubstituted 1-thia-5-silacyclooctanes based on homolytic addition of hydrogen sulfide to diallylsilanes R2Si(CH2CH=CH2)(2) and on intramolecular cyclization of Si-disubstituted (allyl)(gamma-sulfanylpropyl)silanes have been studied. In the former case the reactivity of the silanes decreases in the order R = MeO > F > Me > Ph, whereas in the latter case the reactivity order is slightly different: Me > MeO approximate to F >> Ph. The reactions of diphenyl-and dimethyldiallylsilanes with the complex BF3 center dot 2AcOH occur in a different manner: The former involves rearrangement to form fluoro(2-methylpent-4-enyl)diphenylsilane, while the latter, elimination of the two allyl groups to fluorodimethylsilane and propene.