(E)-dec-5-en-5-yltriphenylsilane | 1262797-61-4

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: (E)-dec-5-en-5-yltriphenylsilane
• 英文别名: [(E)-dec-5-en-5-yl]-triphenylsilane
• CAS: 1262797-61-4
• 化学式: C₂₈H₃₄Si
• 分子量: 398.663
• InChiKey: MROJBAHTQTWKIM-XIEYBQDHSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  6.0
• 重原子数：
  29
• 可旋转键数：
  10
• 环数：
  3.0
• sp3杂化的碳原子比例：
  0.29
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  5-癸炔 、 三苯基硅烷 在 platinum on titania 作用下， 反应 1.0h， 以98%的产率得到(E)-dec-5-en-5-yltriphenylsilane
  参考文献：
  名称：

  Hydrosilylation of alkynes catalysed by platinum on titania

  摘要：

  The heterogeneous hydrosilylation of alkynes catalysed by platinum on titania is reported. A variety of hydrosilanes react with both terminal and internal alkynes to furnish the corresponding vinyl silanes in high yields and short reaction times as well as in a regio- and stereoselective manner. The catalyst can be easily recovered and reused in several consecutive cycles. (C) 2010 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jorganchem.2010.09.068

文献信息

• Hydrosilylation of alkynes catalysed by platinum on titania
  作者：Francisco Alonso、Robison Buitrago、Yanina Moglie、Javier Ruiz-Martínez、Antonio Sepúlveda-Escribano、Miguel Yus

  DOI：10.1016/j.jorganchem.2010.09.068

  日期：2011.1

  The heterogeneous hydrosilylation of alkynes catalysed by platinum on titania is reported. A variety of hydrosilanes react with both terminal and internal alkynes to furnish the corresponding vinyl silanes in high yields and short reaction times as well as in a regio- and stereoselective manner. The catalyst can be easily recovered and reused in several consecutive cycles. (C) 2010 Elsevier B.V. All rights reserved.