trichloro-hexyloxy-silane | 18151-38-7

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: trichloro-hexyloxy-silane
• 英文别名: Trichlor-hexyloxy-silan；Trichloro(hexyloxy)silane；trichloro(hexoxy)silane
• CAS: 18151-38-7
• 化学式: C₆H₁₃Cl₃OSi
• 分子量: 235.613
• InChiKey: SKWKZDURTCWZHB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.74
• 重原子数：
  11
• 可旋转键数：
  5
• 环数：
  0.0
• sp3杂化的碳原子比例：
  1.0
• 拓扑面积：
  9.2
• 氢给体数：
  0
• 氢受体数：
  1

反应信息

• 作为反应物：
  描述：

  trichloro-hexyloxy-silane 生成 dichloro-bis-hexyloxy-silane
  参考文献：
  名称：

  Wolnow, Zhurnal Obshchei Khimii, 1947, vol. 17, p. 1428,1433

  摘要：

  DOI：
• 作为产物：
  描述：

  正己醇 在 四氯化硅 作用下， 生成 trichloro-hexyloxy-silane
  参考文献：
  名称：

  Wolnow, Zhurnal Obshchei Khimii, 1947, vol. 17, p. 231

  摘要：

  DOI：

文献信息

• Molecular Manipulation of Two- and Three-Dimensional Silica Nanostructures by Alkoxysilylation of a Layered Silicate Octosilicate and Subsequent Hydrolysis of Alkoxy Groups
  作者：Dai Mochizuki、Atsushi Shimojima、Takeshi Imagawa、Kazuyuki Kuroda

  DOI：10.1021/ja042194e

  日期：2005.5.1

  A novel methodology for constructing molecularly ordered silica nanostructures with twodimensional (2-D) and three-dimensional (3-D) networks has been developed by using a stepwise process involving silylation of a layered silicate octosilicate with alkoxytrichlorosilanes [ROSiCl3, R = alkyl] and subsequent reaction within the interlayer spaces. Alkoxytrichlorosilanes react almost completely with octosilicate, bridging two closest Si-OH (or -O-) sites on the silicate layers, to form new five-membered rings. The unreacted functional groups, Si-Cl and Si-OR, are readily hydrolyzed by the posttreatment with a water/dimethyl sulfoxide (DMSO) or water/acetone mixture, leading to the formation of two types of silicate structures. The treatment with a water/DMSO mixture produced a unique crystalline 2-D silicate framework with geminal silanol groups, whereas a water/acetone mixture induced hydrolysis and subsequent condensation between adjacent layers to form a new 3-D silicate framework. The 2-D structure is retained by the presence of DMSO molecules within the swelled interlayer spaces and is transformed to a 3-D silicate upon desorption of DMSO. The structural modeling suggests that both of the 3-D silicates contain new cagelike frameworks where solvent molecules are trapped even at high temperature (up to 380 degrees C, in the case of acetone). Both 2-D and 3-D silica structures are quite different from known layered silicates and zeolite-like materials, indicating the potential of the present approach for precise design of various silicate structures at the molecular level.
• Gmelin Handbuch der Anorganischen Chemie, Gmelin Handbook: Si: MVol.C, 140, page 384 - 386
  作者：

  DOI：——

  日期：——
• Vol'nov, Yu. N., Zhurnal Obshchei Khimii, 1947, vol. 17, p. 231 - 234
  作者：Vol'nov, Yu. N.

  DOI：——

  日期：——
• Wolnow, Zhurnal Obshchei Khimii, 1947, vol. 17, p. 1428,1433
  作者：Wolnow

  DOI：——

  日期：——
• Wolnow, Zhurnal Obshchei Khimii, 1947, vol. 17, p. 231
  作者：Wolnow

  DOI：——

  日期：——