2-(2'-p-vinylbenzoylphenyl)benzoxazole | 853730-31-1

• 分子结构分类: 有机化合物 - 苯丙烷和聚酮 - 缩酚酸和缩酚酸环醚类
• 英文名称: 2-(2'-p-vinylbenzoylphenyl)benzoxazole
• 英文别名: [2-(1,3-Benzoxazol-2-yl)phenyl] 4-ethenylbenzoate；[2-(1,3-benzoxazol-2-yl)phenyl] 4-ethenylbenzoate
• CAS: 853730-31-1
• 化学式: C₂₂H₁₅NO₃
• 分子量: 341.366
• InChiKey: MAJZDAQONDPCPG-UHFFFAOYSA-N

物化性质

• 沸点：
  535.0±43.0 °C(Predicted)
• 密度：
  1.244±0.06 g/cm3(Predicted)

计算性质

• 辛醇/水分配系数(LogP)：
  5.6
• 重原子数：
  26
• 可旋转键数：
  5
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  52.3
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为产物：
  描述：

  4-乙烯基苯甲酸 在 吡啶 、 氯化亚砜 作用下， 以 氯仿 为溶剂， 反应 26.0h， 生成 2-(2'-p-vinylbenzoylphenyl)benzoxazole
  参考文献：
  名称：

  Multiresponsive Photopatterning Organic−Inorganic Polymer Hybrids Using a Caged Photoluminescence Compound

  摘要：

  The caged photoluminescence compound 2-(2'-benzoylphenyl)benzoxazole (BzPO) modified with poly(N,N-dimethylacrylamide) was synthesized. Transparent polymer hybrids with the obtained polymer were prepared by using hydrogen bond interactions between amide groups of the organic polymer and silanol groups resulting from hydrolysis of tetramethoxysilane. By UV irradiation upon the obtained polymer hybrids, the cage-released reaction of BzPO quickly took place even in a silica gel matrix, and the resulting polymer hybrids showed strong green photoluminescence deriving from a phototautomer of 2-(2'-hydroxyphenyl)benzoxazole (HPBO) dye. The preparation of "photoresist-like" photopatterning polymer hybrids could be also accomplished by using a photomask during UV irradiation. Furthermore, the photoluminescence of the polymer hybrids was reversibly quenched and emitted by the recaging of the hydroxyl group of HPBO with adsorption and desorption of water molecules. The miscibility of polymer hybrids depending on UV irradiation was evaluated by SEM and nitrogen adsorption porosimetry studies.

  DOI：

  10.1021/ma047320d

文献信息

• Multiresponsive Photopatterning Organic−Inorganic Polymer Hybrids Using a Caged Photoluminescence Compound
  作者：Tomoki Ogoshi、Junpei Miyake、Yoshiki Chujo

  DOI：10.1021/ma047320d

  日期：2005.5.1

  The caged photoluminescence compound 2-(2'-benzoylphenyl)benzoxazole (BzPO) modified with poly(N,N-dimethylacrylamide) was synthesized. Transparent polymer hybrids with the obtained polymer were prepared by using hydrogen bond interactions between amide groups of the organic polymer and silanol groups resulting from hydrolysis of tetramethoxysilane. By UV irradiation upon the obtained polymer hybrids, the cage-released reaction of BzPO quickly took place even in a silica gel matrix, and the resulting polymer hybrids showed strong green photoluminescence deriving from a phototautomer of 2-(2'-hydroxyphenyl)benzoxazole (HPBO) dye. The preparation of "photoresist-like" photopatterning polymer hybrids could be also accomplished by using a photomask during UV irradiation. Furthermore, the photoluminescence of the polymer hybrids was reversibly quenched and emitted by the recaging of the hydroxyl group of HPBO with adsorption and desorption of water molecules. The miscibility of polymer hybrids depending on UV irradiation was evaluated by SEM and nitrogen adsorption porosimetry studies.