carbon monoxide;iron;5-methylcyclohexa-1,3-diene | 60478-56-0

• 分子结构分类: 有机化合物 - 有机盐 - 有机金属盐
• 英文名称: carbon monoxide;iron;5-methylcyclohexa-1,3-diene
• CAS: 60478-56-0；12318-17-1；83603-13-8
• 化学式: C₁₀H₁₀FeO₃
• 分子量: 234.035
• InChiKey: GAEJKCMICUJGAF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  None
• 重原子数：
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• 可旋转键数：
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• 环数：
  None
• sp3杂化的碳原子比例：
  None
• 拓扑面积：
  None
• 氢给体数：
  None
• 氢受体数：
  None

反应信息

• 作为产物：
  描述：

  tricarbonyl[(1,2,3,4,5-η)-1,3-cyclohexadienyl]iron(1+) hexafluorophosphate(1-) 、 甲基锂 以87%的产率得到
  参考文献：
  名称：

  BANDARA B. M. R.; BIRCH A. J.; KHOR THONG-CHAR, TETRAHEDRON LETT., 1980, 21, NO 37, 3625-3626

  摘要：

  DOI：

文献信息

• FTIR studies of organometalcarbonyl-tagged enzymes
  作者：Christopher E. Anson、Colin S. Creaser、Orsolya Egyed、G.Richard Stephenson

  DOI：10.1016/s1386-1425(97)00080-2

  日期：1997.10

  Attachment of organometaltricarbonyl tags to enzymes is revealed by changes in the vibrational modes of the carbonyl groups. Shoulders on nu(sym)(CO) and nu(asym)(CO) bands in the FTIR spectrum of an organometallic tag derived from tricarbonyl[1-(2,3,4,5-eta)-2,4-cyclohexadien-1-yl}pyridinium]iron(1+) hexafluorophosphate(1-)were detected on binding to enzymes (alpha-chymotrypsin, ribonuclease A, alkaline phosphatase and a triacylglycerol lipase). By comparison with tagging reactions between the tricarbonyliron moiety and model compounds, the new spectral features were attributed to an iron complex covalently bonded to the NH2 groups of the amino acid residues of the enzymes. FTIR spectroscopy was used to monitor deprotonation of tagged amino groups on the enzyme surface. Interactions between the organometalcarbonyl tag and other side-chain groups of the amino acid residues were also investigated. (C) 1997 Elsevier Science B.V.