2-phenylazophenyl 3'-indolyl sulfide | 1447009-74-6

• 分子结构分类: 有机化合物 - 有机杂环化合物 - 偶氮苯
• 英文名称: 2-phenylazophenyl 3'-indolyl sulfide
• 英文别名: [2-(1H-indol-3-ylsulfanyl)phenyl]-phenyldiazene
• CAS: 1447009-74-6
• 化学式: C₂₀H₁₅N₃S
• 分子量: 329.425
• InChiKey: XZMVFKCCJGLKKG-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  5.9
• 重原子数：
  24
• 可旋转键数：
  4
• 环数：
  4.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  65.8
• 氢给体数：
  1
• 氢受体数：
  3

反应信息

• 作为产物：
  描述：

  吲哚 、 2-phenylbenzo[d][1,2,3]thiadiazol-2-ium bromide 以 水 为溶剂， 以77%的产率得到2-phenylazophenyl 3'-indolyl sulfide
  参考文献：
  名称：

  One-Pot, Catalyst-Free, Facile, and Efficient Sulfenylation of Electron-Rich Substrates with a Mild Sulfenium Carrier Azobenzene-2-sulfenyl Bromide

  摘要：

  One-pot, catalyst-free, facile, and efficient sulfenylations of resorcinol, 1,3-diaminobenzene, 2-naphthol, 2-aminonaphthalene, indole, pentane-2,4-dione, etc., in aqueous and ethanolic solution by a mild sulfenium carrier azobenzene-2-sulfenyl bromide are described. Efficient sulfenylating reagent, mild reaction conditions, and excellent yields make this method quite simple, convenient, and practical. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.

  DOI：

  10.1080/00397911.2012.733476

文献信息

• One-Pot, Catalyst-Free, Facile, and Efficient Sulfenylation of Electron-Rich Substrates with a Mild Sulfenium Carrier Azobenzene-2-sulfenyl Bromide
  作者：Nizamuddin Ahmed、Tirtha Bhattacharjee、Pranjit Barman、Saibal Kanti Bhattacharjee

  DOI：10.1080/00397911.2012.733476

  日期：2013.10.2

  One-pot, catalyst-free, facile, and efficient sulfenylations of resorcinol, 1,3-diaminobenzene, 2-naphthol, 2-aminonaphthalene, indole, pentane-2,4-dione, etc., in aqueous and ethanolic solution by a mild sulfenium carrier azobenzene-2-sulfenyl bromide are described. Efficient sulfenylating reagent, mild reaction conditions, and excellent yields make this method quite simple, convenient, and practical. Supplemental materials are available for this article. Go to the publisher's online edition of Synthetic Communications (R) to view the free supplemental file.