bis(trimethylsilylmethyl)cadmium | 63835-91-6

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: bis(trimethylsilylmethyl)cadmium
• 英文别名: Bis-trimethylsilylmethylcadmium
• CAS: 63835-91-6
• 化学式: C₈H₂₂CdSi₂
• 分子量: 286.844
• InChiKey: MICNLHFHFZHICV-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  3.39
• 重原子数：
  11
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.75
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  双(环戊二烯)钴 、 bis(trimethylsilylmethyl)cadmium 以 not given 为溶剂， 生成 {η5-C5H5(η4-C5H5CH2SiMe3)Co}
  参考文献：
  名称：

  New derivatives of (?5-cyclopentadienyl) (?4-cyclopentadiene)cobalt

  摘要：

  DOI：

  10.1007/bf00959407
• 作为产物：
  描述：

  bis(trimethylsilylmethyl)magnesium 、 cadmium(II) chloride 以 乙醚 为溶剂， 生成 bis(trimethylsilylmethyl)cadmium
  参考文献：
  名称：

  Reactions of Diorganocadmium Compounds with Other Dialkylmetal Compounds and Macrocycles:  Synthesis of Organocadmate Anions¹

  摘要：

  Combining R2Cd (R an alkyl or Ph group), the corresponding R2Mg compound, and 1,4,8,- 11-tetramethyl-1,4,8,11-tetraazatetradecane, 2,1,1-cryptand, or 2,2,1-cryptand in solution quantitatively produces R3Cd- and RMg(macrocycle)(+) ions. Solutions obtained by combining the same macrocycles with R2Cd alone or with R2Cd plus the corresponding R2Zn compound do not contain significant amounts of ions; rapid exchange of R groups in these solutions, however, may be due to formation of trace amounts of R3Cd- ions.

  DOI：

  10.1021/om001020c

文献信息

• The preparation of metal sulfides and organo-metal sulfides from metal alkyls and hydrogen sulfide
  作者：Christopher G. Bauch、Curtis E. Johnson

  DOI：10.1016/s0020-1693(00)83218-1

  日期：1989.10

  Abstract The room temperature reactions of homoleptic metal alkyl complexes with hydrogen sulfide in toluene solution have been investigated. The aluminum alkyls, AlR 3 (R = Me, Et and i-Bu), reacted with H 2 S to form air-sensitive solids which are postulated to be mixtures of Al 2 S 3 and (RAIS) n . A species of the empirical formula CH 3 GaS was produced when GaMe 3 was treated with H 2 S. Reaction

  摘要研究了均金属烷基络合物与硫化氢在甲苯溶液中的室温反应。烷基铝AlR 3（R = Me，Et和i-Bu）与H 2 S反应形成对空气敏感的固体，推测其为Al 2 S 3和（RAIS）n的混合物。当用H 2 S处理GaMe 3时，会产生一种经验式CH 3 GaS。Cd（CH 2 SiMe 3）2与H 2 S反应生成硫化镉，其保留约10 ppm的烷基。在室温下，Hg（CH 2 SiMe 3）2与H 2 S不反应。但是，在150°C下，纯净的液体反应生成立方晶状硫化汞。还描述了MgEt 2和Ti（CH 2 SiMe 3）4与H 2 S的反应。
• New derivatives of (?5-cyclopentadienyl) (?4-cyclopentadiene)cobalt
  作者：G. A. Razuvaev、V. P. Mar'in、Yu. A. Andrianov、L. I. Vyshinskaya、A. S. Smirnov

  DOI：10.1007/bf00959407

  日期：1987.2
• RAZUVAEV G. A.; MARIN V. P.; ANDRIANOV YU. A.; VYSHINSKAYA L. I.; SMIRNOV+, IZV. AN CCCP. CEP. XIM.,(1987) N 2, 462
  作者：RAZUVAEV G. A.、 MARIN V. P.、 ANDRIANOV YU. A.、 VYSHINSKAYA L. I.、 SMIRNOV+

  DOI：——

  日期：——
• Synthesis and mass spectra of derivatives of (η5-cyclopentadienyl)(η4-cyclopentadiene)cobalt
  作者：G.A. Razuvaev、V.P. Mar'in、Yu.A. Andrianov、L.I. Vyshinskaya、O.N. Druzhkov

  DOI：10.1016/0022-328x(88)80141-4

  日期：1988.6
• Reactions of Diorganocadmium Compounds with Other Dialkylmetal Compounds and Macrocycles:  Synthesis of Organocadmate Anions¹
  作者：Hui Tang、Herman G. Richey

  DOI：10.1021/om001020c

  日期：2001.4.1

  Combining R2Cd (R an alkyl or Ph group), the corresponding R2Mg compound, and 1,4,8,- 11-tetramethyl-1,4,8,11-tetraazatetradecane, 2,1,1-cryptand, or 2,2,1-cryptand in solution quantitatively produces R3Cd- and RMg(macrocycle)(+) ions. Solutions obtained by combining the same macrocycles with R2Cd alone or with R2Cd plus the corresponding R2Zn compound do not contain significant amounts of ions; rapid exchange of R groups in these solutions, however, may be due to formation of trace amounts of R3Cd- ions.