1-[Bis[5-[bis(4-tert-butylphenyl)-methoxymethyl]-2,4-dimethylphenyl]-methoxymethyl]-5-[bis(4-tert-butylphenyl)-methoxymethyl]-2,4-dimethylbenzene | 159217-58-0

• 分子结构分类: 有机化合物 - 苯类化合物 - 三苯基化合物
• 英文名称: 1-[Bis[5-[bis(4-tert-butylphenyl)-methoxymethyl]-2,4-dimethylphenyl]-methoxymethyl]-5-[bis(4-tert-butylphenyl)-methoxymethyl]-2,4-dimethylbenzene
• CAS: 159217-58-0
• 化学式: C₉₂H₁₁₄O₄
• 分子量: 1283.91
• InChiKey: NCBHYFHPEOKFEE-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  25.5
• 重原子数：
  96
• 可旋转键数：
  22
• 环数：
  9.0
• sp3杂化的碳原子比例：
  0.41
• 拓扑面积：
  36.9
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  1-[Bis[5-[bis(4-tert-butylphenyl)-methoxymethyl]-2,4-dimethylphenyl]-methoxymethyl]-5-[bis(4-tert-butylphenyl)-methoxymethyl]-2,4-dimethylbenzene 在 氘代甲醇-d 、 lithium 作用下， 生成 1-[Bis[5-[bis(4-tert-butylphenyl)-deuteriomethyl]-2,4-dimethylphenyl]-deuteriomethyl]-5-[bis(4-tert-butylphenyl)-deuteriomethyl]-2,4-dimethylbenzene
  参考文献：
  名称：

  Synthesis of Sterically Hindered 1,3-Connected Polyarylmethanes

  摘要：

  Sterically hindered 1,3-connected polyarylmethanes were prepared by repetitive additions of aryllithiums to carbonyl compounds. Synthetic routes with various degree of convergence were used. Variable temperature NMR spectroscopy, in conjunction with other techniques, was used to characterize the products.

  DOI：

  10.1021/jo00102a041
• 作为产物：
  描述：

  甲醇 、 Tris(5-(bis(4-tert-butylphenyl)(methoxy)methyl)-2,4-dimethylphenyl)methanol 在 三氟乙酸 作用下， 以 二氯甲烷 为溶剂， 反应 4.0h， 以77%的产率得到1-[Bis[5-[bis(4-tert-butylphenyl)-methoxymethyl]-2,4-dimethylphenyl]-methoxymethyl]-5-[bis(4-tert-butylphenyl)-methoxymethyl]-2,4-dimethylbenzene
  参考文献：
  名称：

  Synthesis of Sterically Hindered 1,3-Connected Polyarylmethanes

  摘要：

  Sterically hindered 1,3-connected polyarylmethanes were prepared by repetitive additions of aryllithiums to carbonyl compounds. Synthetic routes with various degree of convergence were used. Variable temperature NMR spectroscopy, in conjunction with other techniques, was used to characterize the products.

  DOI：

  10.1021/jo00102a041