dimethyldi(5-pyrimidyl)silane | 828915-32-8

• 分子结构分类: 有机化合物 - 有机金属化合物 - 有机类金属化合物
• 英文名称: dimethyldi(5-pyrimidyl)silane
• 英文别名: 5,5'-(Dimethylsilanediyl)dipyrimidine；dimethyl-di(pyrimidin-5-yl)silane
• CAS: 828915-32-8
• 化学式: C₁₀H₁₂N₄Si
• 分子量: 216.318
• InChiKey: LKITZDYLAYMEMY-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  0.09
• 重原子数：
  15
• 可旋转键数：
  2
• 环数：
  2.0
• sp3杂化的碳原子比例：
  0.2
• 拓扑面积：
  51.6
• 氢给体数：
  0
• 氢受体数：
  4

反应信息

• 作为反应物：
  描述：

  ethylenediamine palladium(II) nitrate 、 dimethyldi(5-pyrimidyl)silane 生成
  参考文献：
  名称：

  Novel group 14 elements-bridged self-assembled supramolecules from pyrimidine derivatives and palladium ions

  摘要：

  A solvent-free complex of dimethyldi(5-pyrimidyl)silane with (ethylenediamine)palladium dinitrate in ratio of 1:3 afforded hitherto unknown three-dimensional, silicon-bridged, self-assembled, cage-like supramolecule via dative: bonding to the transition metal centers. The structure of the supramolecule was fully identified by spectroscopic methods and X-ray diffraction analysis. A germanium analogue was also prepared in the same way. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.inoche.2004.07.004

文献信息

• Novel group 14 elements-bridged self-assembled supramolecules from pyrimidine derivatives and palladium ions
  作者：Yoshiyuki Miura、Masato Nanjo、Kunio Mochida、Takeaki Iwamoto、Mitsuo Kira

  DOI：10.1016/j.inoche.2004.07.004

  日期：2004.9

  A solvent-free complex of dimethyldi(5-pyrimidyl)silane with (ethylenediamine)palladium dinitrate in ratio of 1:3 afforded hitherto unknown three-dimensional, silicon-bridged, self-assembled, cage-like supramolecule via dative: bonding to the transition metal centers. The structure of the supramolecule was fully identified by spectroscopic methods and X-ray diffraction analysis. A germanium analogue was also prepared in the same way. (C) 2004 Elsevier B.V. All rights reserved.