Osmium--ruthenium (1/1) | 64418-20-8

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Osmium--ruthenium (1/1)
• 英文别名: osmium;ruthenium
• CAS: 64418-20-8
• 化学式: Os₀Ru₀
• 分子量: 145.635
• InChiKey: GIDFDWJDIHKDMB-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  以 neat (no solvent) 为溶剂， 生成 Osmium--ruthenium (1/1)
  参考文献：
  名称：

  Double complex salts with [Ru(NH3)5Cl]2+ cation and [OsCl6]2− anion: Synthesis and properties. Crystal structure of [Ru(NH3)5Cl]2[OsCl6]Cl2

  摘要：

  Double complex salts [Ru(NH3)(5)Cl][OsCl6] and [Ru(NH3)(5)Cl](2)[OsCl6]Cl-2 were prepared and characterized. An X-ray diffraction study showed that [Ru(NH3)(5)Cl][OsCl6] is isostructural to the previously synthesized [Rh(NH3)(5)Cl][OsCl6]. The structure of [Ru(NH3)(5)Cl](2)[OsCl6]Cl-2 was solved by X-ray diffraction (a = 11.1849(8) angstrom, b = 7.9528(6) angstrom, c = 13.4122(9) angstrom; beta = 99.765(2)degrees; V = 1175.75 angstrom(3); space group C2/m; Z = 2). Thermolysis of the compounds under hydrogen and helium was studied. According to X-ray diffraction, nanosized metallic powders of the corresponding alloys are formed as the final products of thermolysis. The compositions of the obtained solid solutions are consistent with the phase diagram of the Ru-Os system.

  DOI：

  10.1134/s0036023610090032

文献信息

• Double complex salts with [Ru(NH3)5Cl]2+ cation and [OsCl6]2− anion: Synthesis and properties. Crystal structure of [Ru(NH3)5Cl]2[OsCl6]Cl2
  作者：I. V. Korol’kov、S. A. Martynova、K. V. Yusenko、S. V. Korenev

  DOI：10.1134/s0036023610090032

  日期：2010.9

  Double complex salts [Ru(NH3)(5)Cl][OsCl6] and [Ru(NH3)(5)Cl](2)[OsCl6]Cl-2 were prepared and characterized. An X-ray diffraction study showed that [Ru(NH3)(5)Cl][OsCl6] is isostructural to the previously synthesized [Rh(NH3)(5)Cl][OsCl6]. The structure of [Ru(NH3)(5)Cl](2)[OsCl6]Cl-2 was solved by X-ray diffraction (a = 11.1849(8) angstrom, b = 7.9528(6) angstrom, c = 13.4122(9) angstrom; beta = 99.765(2)degrees; V = 1175.75 angstrom(3); space group C2/m; Z = 2). Thermolysis of the compounds under hydrogen and helium was studied. According to X-ray diffraction, nanosized metallic powders of the corresponding alloys are formed as the final products of thermolysis. The compositions of the obtained solid solutions are consistent with the phase diagram of the Ru-Os system.