Hafnium;nickel | 12055-22-0

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Hafnium;nickel
• 英文别名: hafnium;nickel
• CAS: 12055-22-0
• 化学式: HfNi₅
• 分子量: 471.94
• InChiKey: SCXWRGOHKWMOBI-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.02
• 重原子数：
  6
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  镍 、 铪 以 melt 为溶剂， 生成 Hafnium;nickel
  参考文献：
  名称：

  Perturbed angular correlation studies of 181Ta hyperfine interactions in Hf–Ni and Zr–Ni compounds

  摘要：

  The hyperfine interaction experienced by Ta-181 nuclei in the intermetallic compounds ZrNi5, HfNi5, and Hf2Ni7 has been investigated by perturbed angular correlation (PAC) spectroscopy. At temperatures T >= 15 K the Ta-181 angular correlation of appropriately annealed ZrNi5 and HfNi5 is unperturbed, indicating the absence of a magnetic hyperfine interaction. This observation rules out the possibility of spontaneous magnetic order of ZrNi5 and HfNi5 recently proposed in the literature. The temperature dependence of the electric quadrupole interaction of Ta-181 in Hf2Ni7 suggests the existence of a reversible phase transformation at T >= 500 K. (C) 2009 Elsevier B. V. All rights reserved.

  DOI：

  10.1016/j.jmmm.2009.12.037

文献信息

• Perturbed angular correlation studies of 181Ta hyperfine interactions in Hf–Ni and Zr–Ni compounds
  作者：P.R.J. Silva、H. Saitovitch、J.T. Cavalcante、M. Forker

  DOI：10.1016/j.jmmm.2009.12.037

  日期：2010.7

  The hyperfine interaction experienced by Ta-181 nuclei in the intermetallic compounds ZrNi5, HfNi5, and Hf2Ni7 has been investigated by perturbed angular correlation (PAC) spectroscopy. At temperatures T >= 15 K the Ta-181 angular correlation of appropriately annealed ZrNi5 and HfNi5 is unperturbed, indicating the absence of a magnetic hyperfine interaction. This observation rules out the possibility of spontaneous magnetic order of ZrNi5 and HfNi5 recently proposed in the literature. The temperature dependence of the electric quadrupole interaction of Ta-181 in Hf2Ni7 suggests the existence of a reversible phase transformation at T >= 500 K. (C) 2009 Elsevier B. V. All rights reserved.