niobium-zirconium | 12059-59-5

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: niobium-zirconium
• 英文别名: zirconium-niobium；Niobium--zirconium (1/1)；niobium;zirconium
• CAS: 12059-59-5
• 化学式: NbZr
• 分子量: 184.13
• InChiKey: GFUGMBIZUXZOAF-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  2
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为反应物：
  描述：

  niobium-zirconium 、 锌 以 neat (no solvent) 为溶剂， 生成
  参考文献：
  名称：

  NMR Studies on Microscopic Magnetic Properties of Zr_1-xNb_xZn₂ System

  摘要：

  DOI：

  10.1143/jpsj.47.1458
• 作为产物：
  描述：

  锆 、 铌 以 neat (no solvent) 为溶剂， 生成 niobium-zirconium
  参考文献：
  名称：

  等原子 ZrNb 合金在压力下的超导转变温度为 56.4GPa

  摘要：

  摘要 等原子 ZrNb 合金的超导转变温度随压力测量到 56.4 GPa。发现 T c ( P ) 依赖性在 42 GPa 附近达到最大值，并且在 5-10 GPa 的压力范围内具有异常行为，最小值很浅。T c (P) 的这种行为类似于早先在纯金属 Nb 上观察到的行为。与最近模型计算的比较表明，纯 Nb 和 ZrNb 合金中 T c ( P ) 行为的特征具有相同的性质，并且是由声子光谱中的高压异常引起的。

  DOI：

  10.1016/j.physc.2005.12.065

文献信息

• Superconducting transition temperature of the equiatomic ZrNb alloy at pressures to 56.4GPa
  作者：I.O. Bashkin、V.G. Tissen、M.V. Nefedova、E.G. Ponyatovsky

  DOI：10.1016/j.physc.2005.12.065

  日期：2006.2

  Abstract The superconducting transition temperature of the equiatomic ZrNb alloy is measured in dependence on pressure to 56.4 GPa. The T c ( P ) dependence is found to achieve a maximum around 42 GPa and to have an anomalous behavior with a shallow minimum in the pressure range 5–10 GPa. This behavior of T c ( P ) is similar to that earlier observed on pure metal Nb. A comparison with recent model

  摘要 等原子 ZrNb 合金的超导转变温度随压力测量到 56.4 GPa。发现 T c ( P ) 依赖性在 42 GPa 附近达到最大值，并且在 5-10 GPa 的压力范围内具有异常行为，最小值很浅。T c (P) 的这种行为类似于早先在纯金属 Nb 上观察到的行为。与最近模型计算的比较表明，纯 Nb 和 ZrNb 合金中 T c ( P ) 行为的特征具有相同的性质，并且是由声子光谱中的高压异常引起的。
• High-strength Zr-Nb-(Cu,Ni,Al) composites with enhanced plasticity
  作者：J. Das、W. Löser、U. Kühn、J. Eckert、S. K. Roy、L. Schultz

  DOI：10.1063/1.1587254

  日期：2003.6.30

  Zr73.5Nb9Cu7Ni1Al9.5 and Zr66.4Nb6.4Cu10.5Ni8.7Al8.0 composites of bcc β-Zr(Nb) dendrites embedded in a nanocrystalline matrix were prepared by slow cooling from melt. The increase of Nb content from 6.4 to 9 at. % slightly reduces the strength, but considerably improves the plastic elongation under uniaxial compressive loading from ep=0.6% to 14.8%. The interaction of strain with dendrites and the

  Zr73.5Nb9Cu7Ni1Al9.5 和 Zr66.4Nb6.4Cu10.5Ni8.7Al8.0 复合物的 bcc β-Zr(Nb) 枝晶嵌入纳米晶基体中，通过熔体缓慢冷却制备。Nb 含量从 6.4 at 增加到 9 at。% 略微降低了强度，但显着提高了单轴压缩载荷下的塑性伸长率，从 ep=0.6% 到 14.8%。应变与枝晶和纳米晶基体的相互作用被认为是机械性能改善的根源。
• Hopping and tunnelling of D trapped by substitutional Zr in Nb single crystals
  作者：G. Cannelli、R. Cantelli、F. Cordero、F. Trequattrini、H. Schultz

  DOI：10.1016/0925-8388(95)01798-4

  日期：1995.12

  The hopping and tunnelling of deuterium trapped by a Zr substitutional atom in Nb have been investigated by elastic energy loss measurements. A Nb0.995Zr0.0045Dx single crystal was excited in its c' and c(44) modes at frequencies between 6.3 and 130 kHz, from 1 to 300 K. The results are compared with previous experiments on the same sample doped with H and on Nb1-yTiy(H,D)(x). The main peak around 150 K due to hopping of D around Zr is accompanied by secondary peaks at lower temperature, like in the alloys previously investigated. This indicates that D las well as H) has two distinct types of occupation around the Zr atom. The most striking feature is the isotope dependence of a narrow peak at 2 K due to H (D) tunnelling. The intensity of the peak with D is more than one order of magnitude higher than that with H. An explanation of this fact is proposed, which only requires the reduction of the tunnelling matrix element when passing from H to D, Tunnelling within both two or four equivalent sites near the Zr atom is considered.
• Effect of Zr on growth kinetics, microstructure and microtexture of Nb3Sn by bronze technique
  作者：Dheeraj Sharma、Dova Kalyan、Surendra Kumar Makineni、Sangeeta Santra

  DOI：10.1016/j.jallcom.2022.168140

  日期：2023.2
• NMR Studies on Microscopic Magnetic Properties of Zr_1-<i>x</i>Nb_<i>x</i>Zn₂ System
  作者：Masaaki Kontani、Etsuji Kato、Yoshika Masuda

  DOI：10.1143/jpsj.47.1458

  日期：1979.11