Palladium--titanium (2/1) | 12333-98-1

• 分子结构分类: 无机化合物 - 均相金属化合物 - 均相过渡金属化合物
• 英文名称: Palladium--titanium (2/1)
• 英文别名: palladium;titanium
• CAS: 12333-98-1
• 化学式: Pd₂Ti
• 分子量: 260.72
• InChiKey: LGGRUEJPHPYGLN-UHFFFAOYSA-N

计算性质

• 辛醇/水分配系数(LogP)：
  -0.01
• 重原子数：
  3
• 可旋转键数：
  0
• 环数：
  0.0
• sp3杂化的碳原子比例：
  0.0
• 拓扑面积：
  0
• 氢给体数：
  0
• 氢受体数：
  0

反应信息

• 作为产物：
  描述：

  钯 、 四氢化物钛 以 melt 为溶剂， 生成 Palladium--titanium (2/1)
  参考文献：
  名称：

  The TiPd2 compound studied by PAC with and probes

  摘要：

  The intermetallic compound TiPd2 has been investigated with the perturbed angular correlation technique using radioactive Hf-181/Ta-181 and In-111/Cd-111 probes. The measurements confirmed an orthorhombic distortion of the C11(b) structure in the temperature range from 24 to 1023 K. However. the temperature dependence of the Cd-111 quadrupole parameters demonstrated that above 650 K the indium ions reach the lattice site of high symmetry characterized by an axially symmetric electric field gradient (EFG). The situation for the Hf-181/Ta-181 probes is more complex: we observed two electric field gradients, whose fractions interchange near 700 K, possibly due to Hf-181 probes switching their positions but still occupying a low-symmetry site. (C) 2004 Elsevier B.V. All rights reserved.

  DOI：

  10.1016/j.jallcom.2004.04.121

文献信息

• The TiPd2 compound studied by PAC with and probes
  作者：P. Wodniecki、B. Wodniecka、A. Kulińska、M. Uhrmacher、K.P. Lieb

  DOI：10.1016/j.jallcom.2004.04.121

  日期：2004.12

  The intermetallic compound TiPd2 has been investigated with the perturbed angular correlation technique using radioactive Hf-181/Ta-181 and In-111/Cd-111 probes. The measurements confirmed an orthorhombic distortion of the C11(b) structure in the temperature range from 24 to 1023 K. However. the temperature dependence of the Cd-111 quadrupole parameters demonstrated that above 650 K the indium ions reach the lattice site of high symmetry characterized by an axially symmetric electric field gradient (EFG). The situation for the Hf-181/Ta-181 probes is more complex: we observed two electric field gradients, whose fractions interchange near 700 K, possibly due to Hf-181 probes switching their positions but still occupying a low-symmetry site. (C) 2004 Elsevier B.V. All rights reserved.